Enhancement of Plasticizing Effect on Bio-Based Polyurethane Acrylate Solid Polymer Electrolyte and Its Properties
Abstract
:1. Introduction
2. Experimental
2.1. Material
2.2. Preparation of PUA Oligomer
2.3. Preparation of PUA Film Electrolyte
2.4. Characterization of Solid Polymer Electrolyte
Electrochemical Study
3. Results and Discussion
4. Conclusions
Author Contributions
Acknowledgments
Conflicts of Interest
References
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EC, wt. % | Conductivity, σ (S cm−1) |
---|---|
0% | 6.40 × 10−5 |
3% | 3.51 × 10−6 |
6% | 7.05 × 10−6 |
9% | 7.86 × 10−4 |
12% | 7.59 × 10−6 |
15% | 5.95 × 10−6 |
EC Content (%) | Maximum Peak (Hz) | τ (×10−4 s) |
---|---|---|
3 | 4.04 | 0.912 |
6 | 3.56 | 2.75 |
9 | 5.02 | 0.0955 |
12 | 3.46 | 3.47 |
15 | 3.61 | 2.45 |
18 | 3.78 | 1.66 |
Composition | Decomposition Stage | Onset | Final | Temp of Max Decomposition (°C) | Weight Loss (%) | Residue (%) |
---|---|---|---|---|---|---|
Degradation Temp (°C) | ||||||
PUA 0 wt. % Li | d1 | 53.38 | 186.75 | 79.43 | 12.26 | 0 |
d2 | 199.67 | 277.18 | 253.75 | 7.43 | ||
d3 | 278.02 | 646.83 | 415.77 | 90.45 | ||
0 wt. % EC | d1 | 55.98 | 208.62 | 107.07 | 19.62 | 17.34 |
d2 | 209.87 | 371.83 | 304.55 | 44.59 | ||
d3 | 372.66 | 579.84 | 447.94 | 18.1 | ||
3 wt. % EC | d1 | 53.67 | 108.96 | 82.88 | 6.58 | 21.14 |
d2 | 112.41 | 146.72 | 129.37 | 1.99 | ||
d3 | 215.72 | 544.02 | 345.07 | 67.93 | ||
9 wt. % EC | d1 | 52.12 | 132.48 | 97.77 | 16.92 | 23.76 |
d2 | 134.24 | 233.3 | 185.55 | 9.94 | ||
d3 | 234.36 | 363.81 | 294.33 | 39.45 | ||
d4 | 368.36 | 585.98 | 424.8 | 9.57 | ||
15 wt. % EC | d1 | 54.7 | 141.67 | 97.51 | 11.03 | 18.46 |
d2 | 146.95 | 230.59 | 187.2 | 8.12 | ||
d3 | 234.49 | 368.37 | 305.06 | 42.57 | ||
d4 | 353.33 | 520.54 | 433.31 | 11.09 |
Sample | Tm1 (°C) | Tm2 (°C) | Tg (°C) |
---|---|---|---|
PUA 0 wt. % EC | 108.9 | −15.7 | |
PUA 3 wt. % EC | 88.94 | ||
PUA 9 wt. % EC | 94.74 | 156.50 | |
PUA 15 wt. % EC | 95.89 |
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Tuan. Naiwi, T.S.R.; Aung, M.M.; Ahmad, A.; Rayung, M.; Su’ait, M.S.; Yusof, N.A.; Wynn Lae, K.Z. Enhancement of Plasticizing Effect on Bio-Based Polyurethane Acrylate Solid Polymer Electrolyte and Its Properties. Polymers 2018, 10, 1142. https://doi.org/10.3390/polym10101142
Tuan. Naiwi TSR, Aung MM, Ahmad A, Rayung M, Su’ait MS, Yusof NA, Wynn Lae KZ. Enhancement of Plasticizing Effect on Bio-Based Polyurethane Acrylate Solid Polymer Electrolyte and Its Properties. Polymers. 2018; 10(10):1142. https://doi.org/10.3390/polym10101142
Chicago/Turabian StyleTuan. Naiwi, Tuan Syarifah Rossyidah, Min Min Aung, Azizan Ahmad, Marwah Rayung, Mohd Sukor Su’ait, Nor Azah Yusof, and Khine Zar Wynn Lae. 2018. "Enhancement of Plasticizing Effect on Bio-Based Polyurethane Acrylate Solid Polymer Electrolyte and Its Properties" Polymers 10, no. 10: 1142. https://doi.org/10.3390/polym10101142