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Polymers 2018, 10(10), 1143;

Morphologies Tuning of Polypyrrole and Thermoelectric Properties of Polypyrrole Nanowire/Graphene Composites

School of Materials Science and Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, China
CSIRO Manufacturing, Private Bag 10, Clayton South, VIC 3169, Australia
Authors to whom correspondence should be addressed.
Received: 11 August 2018 / Revised: 28 September 2018 / Accepted: 29 September 2018 / Published: 13 October 2018
(This article belongs to the Special Issue Polymers for Thermoelectric Application)
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Polypyrrole (PPy) with different morphologies (e.g., particles, nanotubes, and nanowires) were successfully prepared by adding or without adding different kinds of surfactants through a chemical oxidative polymerization method, respectively. The results show that the morphologies of PPy can be effectively controlled and have a significantly effects on their thermoelectric properties. The PPy nanowires exhibit the highest electrical conductivity and Seebeck coefficient among the various PPy morphologies, such as particles, nanotubes, and nanowires, so PPy nanowires were chosen to prepare PPy nanowire/graphene thermoelectric composites via a soft template polymerization method using cetyltrimethyl ammonium bromide as the template. Both electrical conductivity and Seebeck coefficient of the PPy nanowire/graphene composites increased as the content of graphene increases from 0 to 20 wt %, and as the measured temperature increases from 300 K to 380 K, which leds to the same trend for the power factor. A highest power factor of 1.01 μWm−1K−2 at ~380 K was obtained for the PPy nanowire/graphene composites with 20 wt % PPy nanowire, which is about 3.3 times higher than that of the pure PPy nanowire. View Full-Text
Keywords: polypyrrole nanowire; graphene; composite; thermoelectric polypyrrole nanowire; graphene; composite; thermoelectric

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Du, Y.; Niu, H.; Li, J.; Dou, Y.; Shen, S.Z.; Jia, R.; Xu, J. Morphologies Tuning of Polypyrrole and Thermoelectric Properties of Polypyrrole Nanowire/Graphene Composites. Polymers 2018, 10, 1143.

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