Bimetallic Gold-Silver Nanoparticles Supported on Zeolitic Imidazolate Framework-8 as Highly Active Heterogenous Catalysts for Selective Oxidation of Benzyl Alcohol into Benzaldehyde
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Chemicals
2.2. Catalyst Preparation
2.2.1. Preparation of ZIF-8
2.2.2. Preparation of Catalyst
2.3. Characterization
2.4. Catalyst Testing
3. Results and Discussion
3.1. Catalyst Synthesis and Characterization
3.2. The Selective Catalytic Oxidation of Benzyl Alcohol
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Entry | Catalyst | Solvent | T (°C) | Pressure (bar) | Conv. (%) b | S (%) c | Yield (%) d |
---|---|---|---|---|---|---|---|
1 | Au@Ag/ZIF-8 | THF | 130 | 8 | 65.7 | 53.0 | 34.8 |
2 | Au@Ag/ZIF-8 | 1,4-dioxane | 130 | 8 | 23.7 | 72.9 | 17.3 |
3 | Au@Ag/ZIF-8 | DMF | 130 | 8 | 69.1 | 2.6 | 1.8 |
4 | Au@Ag/ZIF-8 | Acetonitrile | 130 | 8 | 27.7 | 2.0 | 0.6 |
5 | Au@Ag/ZIF-8 | Toluene | 130 | 8 | 8.3 | 29.3 | 2.4 |
6 | Au@Ag/ZIF-8 | THF | 130 | 10 | 77.0 | 24.9 | 19.2 |
7 | Au@Ag/ZIF-8 | THF | 130 | 6 | 25.5 | 98.0 | 25.0 |
8 | Au@Ag/ZIF-8 | THF | 120 | 8 | 40.1 | 66.7 | 26.7 |
9 | Au@Ag/ZIF-8 | THF | 140 | 8 | 80.7 | 29.9 | 24.1 |
10 | Ag@Au/ZIF-8 | THF | 130 | 8 | 75.3 | 53.3 | 40.1 |
11 | Ag@Au/ZIF-8 | 1,4-dioxane | 130 | 8 | 52.6 | 29.5 | 15.5 |
12 | Ag@Au/ZIF-8 | DMF | 130 | 8 | 12.3 | 16.4 | 2.0 |
13 | Ag@Au/ZIF-8 | Acetonitrile | 130 | 8 | 31.5 | 1.0 | 0.3 |
14 | Ag@Au/ZIF-8 | Toluene | 130 | 8 | 1.0 | 96.5 | 1.0 |
15 | Ag@Au/ZIF-8 | THF | 130 | 10 | 80.5 | 44.2 | 35.6 |
16 | Ag@Au/ZIF-8 | THF | 130 | 6 | 34.0 | 96.5 | 32.8 |
17 | Ag@Au/ZIF-8 | THF | 120 | 8 | 69.7 | 55.6 | 38.8 |
18 | Ag@Au/ZIF-8 | THF | 140 | 8 | 80.0 | 40.2 | 32.2 |
19 | AuAg/ZIF-8 | THF | 130 | 8 | 74.0 | 35.2 | 26.0 |
20 | AuAg/ZIF-8 | 1,4-dioxane | 130 | 8 | 51.9 | 35.0 | 18.2 |
21 | AuAg/ZIF-8 | DMF | 130 | 8 | 4.9 | 81.9 | 4.0 |
22 | AuAg/ZIF-8 | Acetonitrile | 130 | 8 | 2.0 | 95.0 | 1.9 |
23 | AuAg/ZIF-8 | Toluene | 130 | 8 | 4.3 | 94.6 | 4.1 |
24 | AuAg/ZIF-8 | THF | 130 | 10 | 80.6 | 30.6 | 24.7 |
25 | AuAg/ZIF-8 | THF | 130 | 6 | 32.4 | 55.6 | 18.0 |
26 | AuAg/ZIF-8 | THF | 120 | 8 | 34.7 | 62.3 | 21.6 |
27 | AuAg/ZIF-8 | THF | 140 | 8 | 89.9 | 24.8 | 22.3 |
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Liu, L.; Zhou, X.; Yan, Y.; Zhou, J.; Zhang, W.; Tai, X. Bimetallic Gold-Silver Nanoparticles Supported on Zeolitic Imidazolate Framework-8 as Highly Active Heterogenous Catalysts for Selective Oxidation of Benzyl Alcohol into Benzaldehyde. Polymers 2018, 10, 1089. https://doi.org/10.3390/polym10101089
Liu L, Zhou X, Yan Y, Zhou J, Zhang W, Tai X. Bimetallic Gold-Silver Nanoparticles Supported on Zeolitic Imidazolate Framework-8 as Highly Active Heterogenous Catalysts for Selective Oxidation of Benzyl Alcohol into Benzaldehyde. Polymers. 2018; 10(10):1089. https://doi.org/10.3390/polym10101089
Chicago/Turabian StyleLiu, Lili, Xiaojing Zhou, Yongmei Yan, Jie Zhou, Wenping Zhang, and Xishi Tai. 2018. "Bimetallic Gold-Silver Nanoparticles Supported on Zeolitic Imidazolate Framework-8 as Highly Active Heterogenous Catalysts for Selective Oxidation of Benzyl Alcohol into Benzaldehyde" Polymers 10, no. 10: 1089. https://doi.org/10.3390/polym10101089