Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN
AbstractPhotoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (CuCl2) loading was as low as 1/64 equivalent to chlorine atom in the presence of Me6-Tren under UV irradiation. The light-responsive nature of graft polymerization was confirmed by “off-on” impulsive irradiation experiments. Temporal control of the polymerization process and varied graft contents were achieved via this photoinduced Cu(II)-mediated RDRP. View Full-Text
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Hu, X.; Cui, G.; Zhu, N.; Zhai, J.; Guo, K. Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN. Polymers 2018, 10, 68.
Hu X, Cui G, Zhu N, Zhai J, Guo K. Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN. Polymers. 2018; 10(1):68.Chicago/Turabian Style
Hu, Xin; Cui, Guopeng; Zhu, Ning; Zhai, Jinglin; Guo, Kai. 2018. "Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN." Polymers 10, no. 1: 68.
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