Microstructure and High-Temperature Compressive Properties of a Core-Shell Structure Dual-MAX-Phases-Reinforced TiAl Matrix Composite

As an advanced high-temperature structural material, TiAl alloy, is often used in the manufacturing of hot-end components of aviation and aerospace engines. However, it is difficult to increase the strength at high temperature, which limits its wider application. Adopting composite material technology is one of the effective ways to improve the comprehensive mechanical properties of TiAl alloy. In this work, by adding 3 wt.% SiC micro-particles to Ti-47.5Al-7Nb-0.4W-0.1B (at.%) pre-alloyed powder, a core-shell structure dual-MAX-phase high-temperature strengthened TiAl matrix composite (also known as TiAl-SiC composite) was prepared by combining powder metallurgy and hot forging. The microstructure and high-temperature compressive properties of the prepared TiAl-SiC composites were studied and compared with TiAl alloy prepared by the same process, and the microstructural characteristics of the TiAl-SiC composite and its microstructure evolution during processing were revealed. The results show that the matrix of as-sintered TiAl-SiC composites was mainly composed of γ phase and a small amount of Ti₂AlC particles, while the reinforcement phase was a dual-MAX-phase core-shell structure, which was mainly composed of core Ti₂AlC phase, shell Ti₃SiC₂ phase, and small Ti₂AlC particles distributed in the outer layer. After hot forging, the microstructure of TiAl-SiC composite became more compact, finer, and more uniform; the phase composition was almost not changed, but the content of Ti₂AlC, Ti₃SiC₂, and TiB₂ phases increased significantly; the content of C in each constituent phase decreased obviously, and a granular Si-rich phase was generated in the core of the reinforcement phase. The yield strength of the as-forged TiAl-SiC composite was significantly higher than that of the as-forged TiAl alloy at temperature higher than 859 °C. This is because the core-shell structure dual MAX phases can effectively reduce the softening rate of TiAl alloy in the range of 800–900 °C, thus playing a strengthening role and increasing the service temperature of TiAl alloy.