Next Article in Journal
Bandgap and Carrier Dynamic Controls in CsPbBr3 Nanocrystals Encapsulated in Polydimethylsiloxane
Next Article in Special Issue
A Theoretical Investigation about Photoswitching of Azobenzene Adsorbed on Ag Nanoparticles
Previous Article in Journal
Near-Infrared Spectroscopy Study of Serpentine Minerals and Assignment of the OH Group
Previous Article in Special Issue
Research on Shock Acceleration Limit of an Ultra-Stable Optical Cavity for Space Applications Based on the Finite Element Methodology
 
 
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Review

Advances of Yb:CALGO Laser Crystals

by 1,2, 1,2, 1,2, 1,2,* and 3,*
1
Key Laboratory of Photonic Control Technology, Tsinghua University, Ministry of Education, Beijing 100084, China
2
State Key Laboratory of Precision Measurement Technology and Instruments, Department of Precision Instrument, Tsinghua University, Beijing 100084, China
3
Optoelectronics Research Centre, University of Southampton, Southampton SO17 1BJ, UK
*
Authors to whom correspondence should be addressed.
Crystals 2021, 11(9), 1131; https://doi.org/10.3390/cryst11091131
Received: 1 September 2021 / Revised: 14 September 2021 / Accepted: 15 September 2021 / Published: 17 September 2021
(This article belongs to the Special Issue Advanced Laser Technology and Applications)

Abstract

:
Yb:CaGdAlO4, or Yb:CALGO, a new laser crystal, has been attracting increasing attention recently in a myriad of laser technologies. This crystal features salient thermal, spectroscopic and mechanical properties, which enable highly efficient and safe generation of continuous-wave radiations and ultrafast pulses with ever short durations. More specifically, its remarkable thermal-optic property and its high conversion efficiency allow high-power operation. Its high nonlinear coefficient facilitates study of optimized mode locking lasers. Besides, its ultrabroad and flat-top emission band benefits the generation of complex structured light with outstanding tunability. In this paper, we review the recent advances in the study of Yb:CALGO, covering its physical properties as well as its growing applications in various fields and prospect for future development.

1. Introduction

Laser technologies have been booming with important breakthroughs in both theoretical and experimental aspects [1,2,3,4], propelling the advances of diverse fields including ultrafast optoelectronics [5,6], laser fabrication [7,8] and laser therapy [9,10]. The gain medium is the kernel of a laser, which fundamentally determines the output characteristics including pulse energy, power and output spectrum. In solid-state lasers, the gain media are crystals or glasses doped with various metal ions, among which there are many famous ones, such as Nd:YAG [11,12,13], Cr:YAG [14,15], Nd:YVO4 [16,17], to name a few. To meet the ever-increasing demands for superior laser performance, the quest for new gain media never wanes. One of them, Yb:CaGdAlO4 [18], abbreviated as Yb:CALGO (or Yb:CGA), has enjoyed a great success with remarkable results in high efficiency lasers, low quantum defect lasers, broad wavelength-tunability lasers, narrow pulse width lasers, high peak power lasers, structured beam lasers, etc.
The reason why Yb:CALGO stands out can be attributed to its unique composition. The energy transition of the ytterbium ion (Yb3+) occurs at 2F5/2 2F7/2. This neat energy-level scheme avoids the emergence of parasitic excited state absorption and up-conversion processes, thus giving low heat load and high quantum efficiency [19,20]. Meanwhile, the absorption spectra of Yb-doped media peak at ~979 nm, which can be well pumped by commercially available InGaAs laser diode (one condition that can never be ignored for favorable lasers) [21]. Hence, many nontrivial experimental results of Yb-doped lasers came out over the past decades [22,23,24,25]. Notwithstanding the foregoing, researchers found that the quantum defect near zero regarding Yb3+ ions can differ significantly from host to host [26]. Additionally, tetragonal rare-earth calcium aluminate CaGdAlO4/CALGO is a noteworthy member because of its disordered structure [27]. So, intuitively, the combination of Yb3+ ions and CALGO may be of great promise. Indeed, in 2005, Petit et al. first reported the result of laser emission using Yb:CALGO and developed its crystal growth, thermal, optical and laser properties [18]. Except for the obtained 40% slope efficiency, 3.5% quantum defect and ~600 mW output at 1016 nm when using ~1.8 W pump and a 2 at. % Yb:CALGO sample, its broad and smooth emission spectrum with a peculiarly flat plateau between 990 nm and 1050 nm and the advantages of easily growing, cutting and polishing enlighten its future and lead to soaring research attention on itself over the past 15 years.
In this work, we review the recent advances in study of Yb:CALGO. We first introduce the important physical properties of Yb:CALGO, which are fundamental to understand various applications of the gain medium. Then, we discuss the recent advances in different laser schemes. Results are analyzed and compared, covering high efficiency lasers, low quantum defect lasers, broad wavelength-tunability lasers, narrow pulse width lasers, high peak power lasers and structured beam lasers. In the last chapter, we prospect for more potential applications of Yb:CALGO, especially in both ultrafast photonics and generation of versatile high-tunability structured light.

2. Properties

In this chapter, we summarize fundamental properties of Yb:CALGO, from the synthesis method, atomic structure to physical parameters. We also highlight the outstanding physical properties by comparison with other common Yb-doped crystals.

2.1. Crystal Preparation and Structure

The Yb:CALGO crystal is typically grown by the Czochralski (CZ) technique [18,28]. In brief, Yb2O3, CaCO3, Gd2O3 and Al2O3 powders are mixed at stoichiometric portions as raw materials ingredients based on the formula of CaGd0.92Yb0.08AlO4 (ratio of ref. [28]). Then, they are turned into pieces under high pressure (around 300 MPa). In quick succession, those pieces are charged and sintered, and the reaction (CaCO3 + 0.04 Yb2O3 + 0.46 Gd2O3 + 0.5 Al2O3 = CaGd0.92Yb0.08AlO4 + CO2 ) happens under high temperature (1200 °C, for example). With a CALGO single crystal as the seed, the crystal can be pulled out of the melt properly as shown in the lower right of Figure 1a [29]. Note that it can look colorless or gradually changed from different manufacturers.
To further comprehend macroscopic properties of Yb:CALGO, one needs to go deeper about the microscopic structure of this anisotropic crystal shown in Figure 1a. The rare-earth calcium aluminate CaLnAlO4 where Ln = Y, La … Gd … Lu, is a member of ABCD4 compounds with K2NiF4 structure, where A = Ca, Sr or Ba, B = Gd or some other rare-earth metals and C = Al, Ga or some transition metals. It has space group I4/mmm (D4h17) and belongs to the tetragonal system. In a K2NiF4-type structure, the small Al atoms are in slightly distorted octahedral sites, which are stacked in layers perpendicular to the c-direction. The large divalent Ca and trivalent Gd ions occupy the same sites statistically with a nine-fold coordination [30]. Note that the difference between the atom radius values of Ca2+ and Gd3+ is pretty trivial (1.18   Å and 1.11   Å , respectively). Thus, a disordered occupation of their sites can be anticipated [31]. They have distorted C4v symmetry [20] and quite high mechanical strength (Mohs hardness 6) [32]. Then, the dopant impurities Yb3+ are expected to substitute for both the Ca2+ and Gd3+ sites. In fact, this kind of substitution effect is utilized prevailingly to broaden the width of gain spectrum in laser science, considering that a normal rare-earth ion’s gain spectral bandwidth is limited to several nanometers and its absorption cross-section is quite low [21]. For instance, in Yb:CaF2, a media that is often used in broadly tunable, high-power and short pulse laser regimes [33], trivalent Yb ions displace divalent Ca ions, which increases the structural disorders and generates a remarkable inhomogeneous broadening of the Yb3+ emission band as a result [34,35]. It is worth adding that in CALGO, the distance between the central metal ion and its ligand ion is so small (0.19 nm in isostructural CaYAlO4) that the crystal field splitting effect is much larger than that of most oxides [36]. This advantage also contributes to the broadening phenomenon. Additionally, the great thing for Yb: CALGO is that it not only possesses the aforementioned broadening effect, but also shows excellent stability because those two substitute ions (Yb3+, 70 and Gd3+, 64) have trivial mass difference compared with Yb3+ (70) and Ca2+ (20) [37]. The lattice dimensions of Yb:CALGO are usually determined by X-ray diffraction method and the typical results carried out by Talik et al. recently are shown in Table 1 [38].

2.2. Spectroscopic Properties

For the development of lasers, it is also crucial to analyze the spectroscopic properties including absorption bands and emission bands. A narrow absorption band such as that of Nd:YAG usually demands high wavelength uniformity and precise temperature control of diode laser arrays, which poses challenges for concise system operation [48]. Luckily, the disordered structure of Yb:CALGO results in the inhomogeneous broadening effect, which brings out its intense, broad and flat bands. For familiar Yb-doped crystal Yb: YAG [49], the energy level structure is shown in Figure 1b. The transition energy between different stark sub-levels determines the corresponding photon absorption or emission wavelengths. However, for Yb:CALGO, the spectral line broadening is strengthened due to the non-equiposition exchange effect of Ca2+ ions, making the broadening of adjacent stark sub-levels exceed the energy gap. So, each sub-level does not have a certain energy value, as shown in Figure 1c. Therefore, instead of the traditional multi-peak structure, the absorption and emission spectrum structures present broad bands with main peaks shown in Figure 1d,e [50].
The Yb:CALGO crystal is optically uniaxial and the optical axis is parallel to the c-axis (c). Hence, there are two principle polarizations, when the polarization of light is parallel to the c-axis, it is π -polarization (or p-polarization, E   | |   c ), when the polarization of light is perpendicular to the c-axis, it is σ -polarization (or s-polarization, E c ). It can be clearly seen from Figure 1d that the absorption spectra are polarization-dependent and there exists an absorption peak at 979nm owning to the zero-line transition between 2F5/2 and 2F7/2 manifolds. Besides, the absorption coefficient of the π polarization is generally greater than that of the σ polarization. The specific peak absorption cross-sections are 1 × 10−20 cm2 ( σ ) and 2.7 × 10−20 cm2 ( π ) [51], while the absorption bandwidth (full width at half maximum, FWHM) is 6 nm for π polarization [20]. Note that the FWHM of 6 nm may not sound attractive enough, but actually the absorption cross-section takes considerable values in the range of 930 nm to 990 nm as shown in Figure 1d. Therefore, the absorption bands are broad enough to match with the emission wavelength of commercially InGaAs laser diodes even with a thermal shift of peak wavelength. As for the emission bands, researchers have conducted many experiments to evaluate the efficiency of this crystal. In general, the emission bands cover most of near-infrared spectral range from Figure 1e. The emission peak is around 1050 nm, the fluorescence bandwidth (FWHM) is 80 nm for σ polarization and a relatively high plateau (0.75 × 10−20 cm2) exists between 1000 nm and 1050 nm. This plateau was explained by two selective excitation experiments at the temperature of 10 K, one of which adopted pumping light of 978 nm while another relied on pumping light of 983 nm [52]. Two complementary bands were shown clearly at 10 K but were combined into one single emission band with a plateau at 300 K. In the emission wavelength range of 1000 nm to1050 nm for the σ polarization, the emission cross-section σ e m is 0.75 × 10−20 cm2 and the fluorescence lifetime τ f is 420 μs, leading to the product σ e m τ f being 315 × 10−20 μs cm2 [20].

2.3. Thermal Characteristics

In lasers, thermal regulation always plays a key role for better performance, as heavy heat loads lead to undesired thermal lensing effect and thermal stresses (even fracture of the crystal). They limit the output power scalability, affect the laser cavity stability and deteriorate output beam quality [53]. In terms of evaluating a crystal’s thermal behavior, one should never ignore thermal expansion coefficient α and thermal conductivity κ . The former describes how crystals expand or shrink under different temperatures and the latter implies how fast crystals “breathe out” the redundant heat. At the very beginning [18], researchers measured unit cell parameters of Yb:CALGO by X-ray diffraction method under temperatures ranging from 300 K to 1400 K. Based on obtained data, the exact thermal expansion coefficients were retrieved as 10.1 × 10−6 K−1 along the a-axis and 16.2 × 10−6 K−1 along the c-axis. Thermal conductivity values were determined to be as high as 6.9 W·m−1·K−1 and 6.3 W·m−1·K−1 along the a-axis and the c-axis, respectively, for a 2 at. % Yb:CALGO sample. Note that R P is a new integrated figure of merit constructed by Petit et al. to reassess Yb-doped laser materials in terms of thermo-mechanical properties and quantum defect, which is R P κ 2 / α η with η the quantum defect. Obviously, the larger κ and the smaller α and η (the larger R P ), the better crystal behaves. It turned out that the new-introduced 2 at. % Yb:CALGO ranked 1st among 15 at. % Yb:GGG, 2.7 at. % Yb:Y2O3, 5 at. % Yb:YAG, 5 at. % Yb:CaF2 and Yb:KGW. Later on, to better understand this material’s thermal advantage, researchers compared more Yb-doped laser materials’ thermal conductivities [54] and modeled to study the influence of the doping rate of Yb ions (i.e., x of CaGd1-xYbxAlO4) qualitatively and quantitatively. One of these models elaborately assumed that part of Yb ions substituted for Gd ions and the others substituted for Ca ions rather than all ions substituted for Gd ions. They also took the mass differences (MGd = 157.3 g/mol, MYb = 173 g/mol, MCa = 40.1 g/mol, ΔMGd/Yb = 16 and ΔMGd/Yb = 133) into consideration. The result fit well with experimental measurements [29].
Figure 1. (a) Eight unit cells of CaGdAlO4 (left), local surrounding of Yb3+ in CALGO structure (upper right) and appearance of Yb:CALGO (lower right). Energy band structures of (b) Yb:YAG and (c) Yb:CALGO. The absorption (d) and emission (e) cross-sections of Yb:CALGO [28]. (f) Thermal conductivity versus doping rate of Yb3+ for different Gd3+/Ca2+ occupation site [29] and thermo-optic coefficient (TOC) versus wavelength in a 5 at. % Yb:CALGO for the ordinary light and extraordinary light [37]. (a) The unit cell picture and local structure picture are redrawn based on ref. [26] and ref. [55], respectively. The Yb:CALGO boule picture is permitted for reuse by School of Crystal Materials (State Key Laboratory of Crystal Materials) of Shandong University, Group of Prof. Xutang Tao. (d,e) Reprinted with permission from ref. [28], IOP Publishing. (f) Left, reprinted with permission from ref. [29], SPIE. (f) Right, reprinted with permission from ref. [37], ©The Optical Society.
Figure 1. (a) Eight unit cells of CaGdAlO4 (left), local surrounding of Yb3+ in CALGO structure (upper right) and appearance of Yb:CALGO (lower right). Energy band structures of (b) Yb:YAG and (c) Yb:CALGO. The absorption (d) and emission (e) cross-sections of Yb:CALGO [28]. (f) Thermal conductivity versus doping rate of Yb3+ for different Gd3+/Ca2+ occupation site [29] and thermo-optic coefficient (TOC) versus wavelength in a 5 at. % Yb:CALGO for the ordinary light and extraordinary light [37]. (a) The unit cell picture and local structure picture are redrawn based on ref. [26] and ref. [55], respectively. The Yb:CALGO boule picture is permitted for reuse by School of Crystal Materials (State Key Laboratory of Crystal Materials) of Shandong University, Group of Prof. Xutang Tao. (d,e) Reprinted with permission from ref. [28], IOP Publishing. (f) Left, reprinted with permission from ref. [29], SPIE. (f) Right, reprinted with permission from ref. [37], ©The Optical Society.
Crystals 11 01131 g001
Furthermore, for the sake of optimizing laser design, one needs to explore its thermo-optic coefficients (TOCs) and thermal coefficients of the optical path (TCOP) (see Figure 1f). The former figures are evaluated by d n / d T while the latter is expressed by W = d n / d T + n 1 α , where n is the refractive index, T is the temperature and α is the thermal expansion coefficient. Considering that Yb:CALGO is uniaxial, there are two principle TOCs and TCOP values. Pavel et al. first determined these figures of merit by laser beam deviation method [37]. They modeled to evaluate experiential analytic expressions for the thermo-optic dispersion formulas: d n d T λ = A 0 + A 1 λ 2 + A 2 λ 4 + A 3 λ 6 , where d n / d T is expressed in 10−6 K−1, wavelength λ is in μm and A0–3 are the expansion coefficients. Later, they extended to investigate the dispersions of the refractive index in CALGO and CALYO laser host crystals and obtained the Sellmeier equations for the spectral range of 0.35–2.1 μm as well as group velocity dispersion being positive at ~1 μm (95 fs2/mm) and negative at ~2 μm (−40 fs2/mm) for CALGO [27]. These encouraging results are especially valuable for high power mode-locked laser designs. Basically, the thermo-optical properties determine the thermal lensing effect. So, the same group directly measured the equivalent dioptric power of thermal lensing of Ng-cut Yb:KGW and a-cut Yb:CALGO in a similar laser setup. The comparison results showed that the Yb:CALGO crystal exhibited negligible anisotropy in the thermal lensing power [56].

3. Advanced Progress

As a highly anticipated gain medium, the first milestone of laser emissions achieved 600 mW at 1050 nm and lower power at shorter wavelength [18]. After that, enduring efforts of laser specialists have been paid to achieve exceptional results based on Yb:CALGO, either in a continuous-wave (CW) scheme or pulsed scheme, some of which are even record-breaking.

3.1. Yb:CALGO in CW Lasers

Yb:CALGO in CW lasers shows its advantage in high power and high efficiency, broad wavelength and dual-wavelength tunability and, also, spatial mode tunability in structured beam lasers.

3.1.1. High Power and High Efficiency Yb:CALGO Lasers

In 2013, Calendron designed a novel laser cavity by introducing dual-crystal Yb:CALGO to reduce thermal lensing effect and successfully extracted 23 W of power at 1042 nm from 2 at. % doped crystals under CW operation [57]. Meantime, Druon et al. leveraged a high-power pumping (up to 200 W) technique as seen in Figure 2a and improved the CW output power to 43 W [58], which was a new record at that time. As high pump power (typically > 100W) leads to thermal problems, the thermal lens issue was studied in detail. It is noteworthy that they found the output could automatically stabilize from a high spatial multimode regime to a TEM00 mode, accompanied by a switch of polarization state from σ to π . They analyzed this atypical behavior and credited it to the special spectroscopic and thermal properties of Yb:CALGO. Later, Kore’s group grew the crystal with doping concentration up to 10 at. % in their lab and reached maximum CW output 3.3 W of power, 73% of slope efficiency and 65% of optical-to-optical efficiency [59]. For the sake of integration, they also designed the first femtosecond-laser-written waveguide laser in Yb:CALGO as depicted in Figure 2b, emitting CW output up to 2.4 W of power and 69% of efficiency. They recently updated the waveguide Yb:CALGO laser with 3.9 W output at a slope efficiency of 67% [60]. To better illustrate the potential of Yb:CALGO crystal, Sujith et al. directly compared the performances of CW diode-pumped Yb:CALGO and Yb:KYW lasers in a similar setup for the first time. They found that in terms of optical efficiency, the Yb:KYW laser outperformed the Yb:CALGO one in the low power regime. However, the Yb:CALGO laser indeed did a much better job on thermal behavior in the high power regime [61]. Except for those encouraging results of laser emission, researchers also conducted investigation on the intracavity loss measurement in a diode-pumped CW Yb:CALGO laser by spectroscopic gain analysis method or the Findlay–Clay analysis [62], which aided in high-efficiency and high-power laser systems.
Another interesting point to note is the parallel progress done on thin-disk (TD) lasers and microchip lasers. A TD oscillator uses a very thin crystal cooled on its back side for efficient cooling and recycling multi-pass pump configuration to obtain appreciable absorption of pump light. The advantages of this structure plus large emission bandwidth and good thermal properties of Yb:CALGO crystal enable efficiency-enhanced or power-scaled laser systems. In 2012, Ricaud’s group first created an Yb:CALGO TD laser in CW regime and obtained 29.5 W of average power, 40% of slope efficiency and 32% of optical-to-optical efficiency as shown in Figure 2c [65]. It is interesting that they discussed the main bottlenecks of this crystal, which were the difficulties to diminish scattering losses and to obtain high optical quality crystal. What follows is a thin-disk laser configuration with slope efficiency of 70%, optical-to-optical efficiency of 57% and maximum output power of 30.7 W [43]. They were the highest efficiencies achieved on this medium at that time. Years after, Pavel et al. first presented a microchip laser scheme to break the record and the slope efficiency was as high as 84% shown in Figure 2d (near the quantum-defect-limited slope efficiency) [41]. Actually, they conducted the experiments on Yb:CaLnAlO4 (Ln = Gd, Y) and the efficiency of Yb:CaYAlO4 was even higher (91%), near the upper limit indeed. They adopted a 3.4 mm-long, 8 at. %Yb:CALGO and obtained 7.79 W of output power correspondingly and compared the outputs of two crystals as well. Notably, the microchip laser scheme has been envisaged to foster miniaturization.

3.1.2. Broad Wavelength and Dual-Wavelength Tunable Yb:CALGO Laser

Thanks to the peculiar spectroscopic properties of Yb:CALGO crystal, dual- and tunable-wavelength lasers were also reported at the same time. The first laser emission of this crystal in 2005 demonstrated its potential in tunability [18]. In 2008, Boudeile et al. studied the relation between its tunability and doping concentration under CW 100 W of pump power [66]. The results showed that higher doped crystal may possess a broader emission spectrum and some other factors such as crystal length also mattered to the bandwidth. However, all emission band were quite broad and the broadest one ranged from ~1010 nm to ~1082 nm. Then, Calendron demonstrated its tunability ranging from 1018 nm to 1060 nm while the powers were beyond 15 W between 1030 nm and 1057 nm [57]. The aforementioned TD and microchip lasers were also tunable with the ranges from 1018 nm to 1052 nm [65], from 999 nm to 1089 nm (the widest) [43] and from 1057 nm to 1065 nm [41]. In addition to single-wavelength tunability, dual-wavelength Yb:CALGO lasers were presented and studied as well. A dual-wavelength oscillator can simultaneously emit two wavelengths laser output and is highly suitable for applications in THz generation [67], optical coherence tomography [68], etc. In 2018, Sujith et al. invented a discretely tunable dual-wavelength Yb:CALGO laser using a single birefringent filter (BRF) plate [69]. BRF plates can introduce wavelength-dependent periodic loss into a standard laser cavity. They not only achieved discrete frequency offset ranging from 1.3 THz to 12.5 THz by BRFs with thicknesses of 0.5, 2, 4 and 6 mm but also yielded multi-watt output power (maximum 4.1 W), which were applicable and economical to further design dual-wavelength mode-locked lasers and generate THz radiations. Recently, Reza et al. utilized a similar BRF plate (12 mm thick) to demonstrate a CW dual-wavelength Yb:CALGO laser (see Figure 2e) [64]. It is noteworthy that the wavelength spacing changed from 2.16 nm to 41.44 nm by rotating the BRF and the output power was as high as ~7.5 W for 25 W of the incident pump power. In addition, as for single-wavelength tunability, Liang’s group studied the dependence of emission wavelength on the crystal temperature [70]. They first observed that by increasing absorbed pump power, the temperature of the Yb:CALGO crystal also increased, which led to the output wavelength variation from 1051.10 nm to 1054.72 nm. In short, a Yb:CALGO laser can feature wavelength tunability in both single-wavelength and dual-wavelength operation configurations. The following sections in this review about pulsed-scheme lasers or structure-beam lasers (see below) also demonstrate this feature.

3.1.3. Mode-Tunable Structured Light Lasers with Yb:CALGO

Many laser scientists focus peculiarly on how to design a laser with higher output power or higher energy or higher repetition rate, whilst the transverse profiles of laser beams are equally meaningful since they lend support to applications in optical manipulation, next generation large-capacity communication, microscopy, measurement, etc. [71,72]. These beams are collectively known as structured beams including vortex beams [73], nondiffracting beams [74], self-accelerating beams [75], among many others. Over the past decades, there are seminal research advances in lasers that directly emit structured beams for the sake of high mode purity and power [76]. Our group first presented the experiments on Yb:CALGO structured beam lasers [77]. In a CW scheme, by controlling the dual-off-axis displacements and pump power, wavelength-tunable high order Hermite–Gaussian (HG) modes were excited at will, as illustrated in Figure 3a. The experimentally measured wavelength-tunable range was 10 nm and mode-tunable range was up to 15 modes. We also transformed the HG modes to corresponding Laguerre–Gaussian modes by a pair of cylindrical lenses and produced more valuable vortex beams carrying orbital angular momenta (OAM). Later, we reported the dual-wavelength vortex beams (1046.1 nm and 1057.2 nm) and tested the laser’s spectral stability (steadily operated for more than 3 h) as well [78]. When the cavity geometry satisfies the reentrant confinement of the coupled quantum harmonic oscillator in SU(2) Lie algebra [79], the frequency-degeneracy laser modes will be excited. Under this premise, we successfully explored vortex lattices with transverse-mode-locking states [80], periodic-trajectory-controlled and wavelength-tunable SU(2) geometric modes [81] as well as polygonal vortex beams [82]. Not long ago, a new Yb:CALGO laser scheme was proposed by inserting two cylindrical lenses into the cavity to surprisingly obtain two-dimensional tunable high order HG modes as shown in Figure 3b [83]. This is significant because the elegant scheme was able to directly control two indices of HG modes at the source and after an astigmatic converter, the LG modes were tunable likewise. With more precise adjustments on the oscillator, chirality-controllable vortex beams were also achieved. By slightly modifying the angle of the output coupler, the OAM beam with wavelength tunability could be generated directly from Yb:CALGO laser recently [84]. An alternative vortex beam generator was also demonstrated with a mirror curvature dynamically controlled Z-shaped resonator in Figure 3c [85]. Researchers also found that by rotating the Yb:CALGO crystal in the cavity, vortex arrays could be produced directly as well [86]. Another interesting structured beam is the conical refraction (CR) light, i.e., a hollow cylinder light with annular intensity profile after the beam propagates conically through a laser crystal [87]. When the light rings of the CR beam are separated by a dark ring (dubbed Poggendorff dark ring), it is considered as excellent CR beam. Reza et al. recently investigated a Yb:CALGO-based CR laser and obtained CR beam with 6.25 W output power as well as an excellent CR beam with high quality [88].

3.2. Yb:CALGO in Ultrashort Pulse Lasers

Previous endeavors care about CW laser emissions, and actually, the sought-after characteristics of Yb:CALGO including good thermal properties and broad spectrum have fueled fertile research activities on pulsed laser output, in particular, ultrashort pulses (typically a few tens of femtoseconds). Femtosecond laser sources lay the foundation for many applications such as microfabrication [5], LIDAR [89] and laser-initiated systems [90] due to its high temporal confinement of energy. The recipe of generating ultrashort pulses is to lock many longitudinal modes of a laser cavity in phase whereby these modes interfere constructively to achieve short pulses, also termed as mode-locked (ML) laser oscillators [91]. Several milestones of ML lasers were established with the emergence of various laser media: femtosecond dye laser first, titanium-doped sapphire, then, Cr4+-, Nd3+-, Cr3+- and Yb3+-doped crystals also [39]. In this regard, we review the major progress involved in the generation of ultrafast pulses initiated with Yb:CALGO.
Firstly, an inherent condition that ultrashort pulses need to satisfy is Δ t Δ ν 0.32 where Δ t and Δ ν are the FWHM time duration and spectrum of a pulse, respectively. Obviously, to achieve shorter pulses, the laser medium should allow a broader spectrum to be amplified [39]. Indeed, the emission band width (FWHM) of Yb:CALGO is as broad as 80 nm (see Section 2) and the theoretical minimum duration is approximated to be 14 fs.

3.2.1. Ultrashort Pulses with SESAM Mode Locking in Yb:CALGO Lasers

The first pulsed emission dating back to 2007 was 47 fs achieved by leveraging a semiconductor saturable-absorber mirror (SESAM) [50]. Since SESAM-based ML architecture is prevailing due to concise structure, self-starting, stable and good beam quality, we here summarize related pulsed emissions by Yb:CALGO. Soon after 2007, 40 fs pulses were enabled by a 350 mW single-mode laser pump with optimized ML performance [92]. In terms of average power, 68 fs pulses with 520 mW at a 105 MHz repetition rate were realized, updating the highest power for sub-100 fs Yb-bulk lasers [52]. This record was soon broken by Alessandro et al. by generating 95 fs pulses with average power 12.5 W at an 80 MHz repetition rate [93]. They set up a standard Z-cavity and a 4 mm long, 2 at. % doped Yb:CALGO crystal was used. Note that 12.5 W may not be the upper limit because the available pump power for them was only up to 62.5 W. Except for tunable CW output, pulsed emissions by Yb:CALGO are adjustable in wavelength too. Aforementioned, 40 fs pulses were tunable across 20 nm [92] and a similar scheme could emit sub-100 fs pulses covering a 38 nm wide wavelength range between 1034 nm and 1072 nm [94]. It is interesting for Yb:CALGO because it also enlightened researchers to investigate the tunable performance output by Yb:CaYAlO4, another new laser crystal similar to Yb:CALGO, which achieves broad tunability of 40 nm and pulse width as short as 43 fs [95].
Soliton ML scheme is interesting since it keeps pulses away from pulse broadening [96], a deleterious effect that may cause signal crosstalk. This ML scheme happens when self-phase modulation (SPM) cancels group delay dispersion. Phillips et al. tested the soliton ML output of Yb:CALGO through cascaded quadratic nonlinearities [97]. Additionally, an intracavity LBO crystal offered large and negative SPM leading to pulses of 114 fs at 1050 nm with a repetition rate of 113 MHz. Later on, they adopted a two-dimensionally patterned quasi-phase-matching (QPM) grating to better regulate the intracavity solitons and theoretically explained the new approach for pulse formation and stabilization [98]. Another milestone was established by them in terms of pulses with high repetition rate [99], as shown in Figure 4a, which could be helpful in spectroscopy and ultra-high-speed optical communications. In 2014, Alexander et al. realized a gigahertz (109 Hz) Yb:CALGO laser, reaching 1.8 GHz and 59.4 fs without resort to external pulse compression indeed [100]. Mayer et al. addressed several considerable issues of ML lasers, which were, respectively, the strict need for single mode pump, low output power, Q-switching instabilities and bulky cavity geometries [99]. The recipe was the aforementioned intracavity multi-functional two-dimensionally patterned QPM device, which shaped the pulses in time, minimized the intracavity loss and acted as a dynamic self-defocusing lens to protect the cavity elements simultaneously. The encouraging pulses with 166 fs of duration, 1.2 W of average output power and 10.6 GHz of repetition rate greatly demonstrated the potential of Yb:CALGO. Very recently, they adopted the similar scheme to investigate how intracavity dispersion, pump and cavity design could affect ML performance [101]. By pumping with a higher brightness source and designing new dispersion-optimized dichroic output-coupling cavity mirrors, 108 fs pulses at 10.4 GHz with an 11.6 nm-wide optical spectrum and average output power of 812 mW were demonstrated. The pulses were further used to verify coherent octave-spanning supercontinuum generation in a silicon nitride waveguide. Another common technique to obtain high repetition rate pulses with an easy set-up is called harmonic mode locking [102]. In 2017, a SESAM ML Yb:CALGO oscillator with harmonic repetition rate operation up to the third order (282 MHz) was realized [103]. Very soon, another Yb:CALGO laser with a harmonic repetition rate up to the 300th order was achieved, leading to 22.4 GHz repetition rate in total [104]. They employed the amplified etalon effect of the laser crystal and the scheme was neat enough for sub-picosecond high repetition rate (over 10 GHz) oscillators.

3.2.2. Ultrashort Pulses with Kerr-Lens Mode-Locking in Yb:CALGO Lasers

A counterpart of SESAM-based ML regime is the Kerr-lens mode-locking (KLM) technique. Researchers tried to obtain short pulses with high average powers from a Yb:CALGO oscillator operating at pure KLM mode [44], as shown in Figure 4b. Pumped by a high-brightness fiber laser, 40 fs pulses with average power up to watt level were achieved and the shortest results were down to 32 fs, which was close to the theoretical limit. In terms of tunability, Gao et al. tuned the KLM-based wavelength output from 1043.5 nm to 1076 nm by tilting the end mirror of the cavity while maintaining the sub-100 fs time duration [105]. Though high repetition rate pulses are desirable in many cases, some scenarios, such as the micromachining of glasses, prefer lower repetition rates. By carefully managing the dispersion and ML process, Papadopoulos et al. filled the blank by successfully generating 93 fs pulses at 27 MHz and 170 fs pulses at 15 MHz through an extended-cavity ML Yb:CALGO laser [106]. The performances were scaled by Manjooran et al. in 2017 by creating pulses with 650 mW of average output power and 66 fs of duration at a low repetition rate of 10.2 MHz in a KLM scheme [107]. Correspondingly, the pulse energy was 64 nJ with a peak power of 0.97 MW, which was favorable in nonlinear microscopy, high harmonic generation and so on. Based on KLM, Kimura et al. recently used stimulated Raman scattering in three oscillators with different crystals (Yb:CALGO, Yb:KY(WO4)2 and Yb:Y2O3) to produce ultrashort pulses, which is a new spectral broadening method [108]. The pulse durations from the Yb:CALGO oscillator were 22 fs, which were two thirds shorter than that of unbroadened ML pulses. To overcome the spectral and power limitations of collinearly pumped ultrashort lasers, Layaye et al. designed a cross-polarized pumping regime and obtained 31 fs pulses with 389 mW of average power and 29% efficiency recently [109]. Newly, Wang et al. delivered pulses with the shortest duration (4.8 optical cycles) ever reported for a KLM Yb-bulk laser [110]. By introducing two broadband chirped mirrors and a prism pair to regulate the intracavity dispersion, as shown in Figure 4d, 17.8 fs pulses with 26 mW of average power at 95.9 MHz were triggered, indicating compelling performance brought by this special crystal. Such a few-cycle pulse is thought to only be achievable by transition-element-doped laser media (e.g., Ti:Sapphire) at ~800 nm. Now, Yb:CALGO opens a new possible platform to pursue extreme ultrashort sub-5-cycle pulses at ~1 μm.

3.2.3. Ultrashort Pulses from SESAM and Kerr-Lens Mode-Locked Yb:CALGO Lasers

When SESAM and KLM are not considered separately, some scientific problems about laser pulses may have better solutions. In 2015, an all-optical Q-switching limiter was proposed to increase the Q-switching stabilities and output power in the gigahertz regime [111]. The key was the appropriate cavity design where a negative saturable absorber induced Kerr-lens effect held the maximum influence on the SESAM. Soon, Wang et al. enabled the Yb:CALGO laser to work in the SESAM combined Kerr-lens mode locking regime and reported the output pulses with duration of 70 fs and FWHM of 19.8 nm at output power of 210 mW, while in SESAM-only regime, the pulses were with duration of 630 fs and FWHM of 2.7 nm at output power of 385 mW [112]. Moreover, their configuration allowed for the laser operation with both high output power and short pulse duration [113]. A working example is the 45 fs pulses with 1.7 MW of peak power directly from the oscillator achieved by the combined effects of Yb:CALGO crystal properties, efficient pumping and the dual action of KLM and SESAM [45], shown in Figure 4c. In their experiments, pulses could be as short as 38 fs with peak power of 187 kW.
Figure 4. Ultrashort pulse Yb:CALGO lasers by leveraging (a) SESAM mode locking [99], (b) Kerr-lens mode locking [44], (c) both SESAM and Kerr-lens mode locking [45] and (d) Kerr-lens mode locking with broadband chirped mirrors and a prism pair [110] techniques. (b) is redrawn based on ref. [44]. (c) Reprinted with permission from ref. [45], ©The Optical Society. (d) Reprinted with permission from ref. [110], ©The Optical Society.
Figure 4. Ultrashort pulse Yb:CALGO lasers by leveraging (a) SESAM mode locking [99], (b) Kerr-lens mode locking [44], (c) both SESAM and Kerr-lens mode locking [45] and (d) Kerr-lens mode locking with broadband chirped mirrors and a prism pair [110] techniques. (b) is redrawn based on ref. [44]. (c) Reprinted with permission from ref. [45], ©The Optical Society. (d) Reprinted with permission from ref. [110], ©The Optical Society.
Crystals 11 01131 g004

3.2.4. Ultrashort Pulses with Other Methods in Yb:CALGO Lasers

Different from above ML scheme, Tong et al. recently used a nonlinear mirror ML scheme to design a pulsed Yb:CALGO laser for the first time [114]. As shown in Figure 5a, they constructed the nonlinear mirror by a BBO crystal and a dichroic mirror and obtained stable picosecond (2.3 ps) solid-state 1052 nm laser with an average power of 1.78 W and repetition rate of 116 MHz.
To acquire pulses with high energy and power, an alternative technique is regenerative amplifier (RA) whereby a seeded pulse is amplified by gain crystals and then compressed by gratings. The first Yb:CALGO RA was released by Caracciolo et al., as shown in Figure 5b, with 650 mW and 92 fs seed pulses being amplified and compressed to 28 W and 217 fs pulses at 500 kHz repetition rate [115]. What follows were 1 nJ seed pulses being augmented to 3 mJ achieved by Calendron [57]. For RAs, ultrashort pulse duration generally contradicts with high power/energy. Pouysegui et al. addressed this issue through a complex amplifier scheme, and the pulses with 97 fs, up to 24 μJ, centered at 1047 nm and at 50 kHz repetition rate were reported [116]. In terms of high pulse energy and high repetition rate, Caracciolo et al. also compared the performances of Yb:CALGO- and Yb:CaF2-based RAs where both crystals admitted 1 mJ pulses with sub-400 fs at 5 kHz [51]. Then, they proposed a brand new intracavity pulse stretching design by exploiting a single grating mirror, which simplified the layout and extracted 193 fs pulses with 205 μJ at 20 kHz repetition rate [117], as shown in Figure 5c. Yb:CALGO amplifier can also be used for the generation of low noise optical frequency comb lately, showing great potential in frequency metrology and high-resolution spectroscopy [118]. Moreover, a high-power Yb:CALGO regenerative amplifier system was also demonstrated to generate pulses with 11 W average power, 50 fs pulse width, 3.7 GW peak power and 43 kHz repetition rate, all at the same time and for the first time [119]. The scheme was also the first sub-100 fs regenerative amplifier based on Yb-doped bulk medium without nonlinear spectral broadening, showing conciseness and robustness.
Figure 5. (a) Ultrashort pulses Yb:CALGO lasers with nonlinear mirror ML scheme [114]. (b) The first Yb:CALGO RA [115]. (c) A new intracavity pulse stretching design by exploiting a single grating mirror [117]. (a) Reprinted by permission from ref. [114], Springer Nature. (b,c) are redrawn based on ref. [116] and ref. [118], respectively.
Figure 5. (a) Ultrashort pulses Yb:CALGO lasers with nonlinear mirror ML scheme [114]. (b) The first Yb:CALGO RA [115]. (c) A new intracavity pulse stretching design by exploiting a single grating mirror [117]. (a) Reprinted by permission from ref. [114], Springer Nature. (b,c) are redrawn based on ref. [116] and ref. [118], respectively.
Crystals 11 01131 g005

3.2.5. Ultrashort Pulses in Thin-Disk Yb:CALGO Lasers

In concurrence with bulk schemes, there are also efforts on pulsed oscillators in special schemes. The first ML thin-disk laser was addressed in 2012 by Ricaud et al. and sub-200 fs pulses at watt level ranging from 1032 nm to 1046 nm were extracted as well as 300 fs pulses with average power of 28 W or 197 fs pulses with an average power of 20 W [120]. The promising properties of Yb:CALGO also enabled pulses with 15 nm width (FWHM) and millijoule-level energy in a similar TD regime [63]. The results were soon improved by Diebold et al. with attractive features such as 62 fs pulse width at a repetition rate of 65 MHz, average power of 5.1 W and peak power of 44 MW in a SESAM-based TD oscillator [121]. In addition, KLM-based TD laser was also demonstrated recently, with the shortest pulses of any TD oscillators [122]. The 30 fs pulses with average power 150 mW were not only well matched with that of Yb-doped bulk oscillators, but also could be shorter for the direct generation of few-cycle pulses in their regime with further optimization.

4. Conclusive Remarks

To conclude, Yb:CALGO, as a new laser crystal, possesses outstanding properties including ultrabroad and flat-top emission spectrum and large thermal conductivity as well as stable thermo-optic characteristics. Based on these advantages, Yb:CALGO has become an increasingly important candidate of laser gain media for generating versatile structured light with largely improved properties, both in CW lasers towards tunable light and in pulsed lasers towards extremely short and intense light. In the past 15 years since it was proposed, Yb:CALGO lasers have set up several records in diverse laser technologies:
(1)
Yb:CALGO produced the ultrafast lasers with highest intracavity peak power of 44 MW [121].
(2)
Yb:CALGO laser reached the highest slop efficiency as 84% (near the quantum-defect-limited slope efficiency) in a microchip laser scheme [41].
(3)
Yb:CALGO empowered a wavelength-tunable laser with a tuning range as broad as 90 nm [43].
(4)
Yb:CALGO permitted the highest peak power of 1.7 MW in a sub-50 fs diode-pumped laser oscillator [45].
(5)
Yb:CALGO could operate in a microchip laser with length of 3.4 mm and produced multi-watt emission [41].
(6)
Yb:CALGO allowed a new mode-locking regime producing 100 fs pulses at 540 MHz repetition rate with 760 mW of average output power [98].
(7)
Yb:CALGO enabled direct emission of watt-level 10-gigahertz pulses from a simple and small straight laser cavity [99].
(8)
Yb:CALGO created the shortest pulses with time duration of 17.8 fs in a Kerr-lens mode-locked architecture [110].
(9)
Yb:CALGO optical frequency comb created the narrowest free-running CEO linewidth as 1.6 kHz and a comb optical linewidth narrower than 28 kHz in 1 ms observation time at 1064 nm [118].
(10)
Yb:CALGO-based regenerative amplifier demonstrated the first sub-100 fs pulses with 11 W average power, 3.7 GW peak power and 43 kHz repetition rate without resorting to nonlinear spectral broadening [119].
We anticipate that the Yb:CALGO will rapidly create more and more amazing records of laser technology in the near future. Despite the exciting progresses and advantages discussed above, currently, Yb:CALGO also has some challenges in terms of regulating scattering losses and growing high optical quality crystal, which can sharply impair the laser performance. So, the results of experimental gain measurement were lower than expected indeed. These drawbacks may be potentially addressed by more advanced crystal growth technique.
Furthermore, structured light with the control of multiple degrees of freedom using Yb:CALGO lasers can also be a hot topic, including ultrafast temporal-tunable, spectral-tunable and spatial-tunable vortex beams, which have promised tremendous applications such as optical tweezers, large-capacity communications. On the one hand, prevailing extra-cavity modulators such as liquid crystal spatial light modulator (LCSLM) and metasurface have emerged as powerful tools in tailoring spatial profiles of structured beams. However, they suffer from low damage threshold or low mode purity and are limited to near-field application scenarios. Intra-cavity oscillations of structured light are envisaged to overcome these hurdles featuring high power/energy and high mode purity. However, scant attention is paid to constructing high-quality tunable laser source to realize them. Now, Yb:CALGO laser may stand up to be one of the perfect solution for the requirement of versatile tunable laser sources.

Author Contributions

H.W. and J.P. contribute equally to this work. H.W., J.P., Y.M., Q.L. and Y.S. contributed to data analysis and writing the manuscript, and this project is supervised by Q.L. and Y.S. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by Key-Area Research and Development Program of Guangdong Province (2020B090922006); National Natural Science Foundation of China (NSFC) (61875100).

Data Availability Statement

Data underlying the results presented in this paper are not publicly available at this time but may be obtained from the authors upon reasonable request.

Acknowledgments

The authors thank Jiading Tian for useful discussions.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Hargrove, L.E.; Fork, R.L.; Pollack, M.A. Locking of He–Ne Laser Modes Induced by Synchronous Intracavity Modulation. Appl. Phys. Lett. 1964, 5, 4–5. [Google Scholar] [CrossRef]
  2. McClung, F.J.; Hellwarth, R.W. Giant Optical Pulsations from Ruby. J. Appl. Phys. 1962, 33, 828–829. [Google Scholar] [CrossRef]
  3. Strickland, D.; Mourou, G. Compression of amplified chirped optical pulses. Opt. Commun. 1985, 56, 219–221. [Google Scholar] [CrossRef]
  4. Bloembergen, N. Nonlinear Optics; World Scientific: Singapore, 1996; p. 188. [Google Scholar]
  5. Kawata, S.; Sun, H.-B.; Tanaka, T.; Takada, K. Finer features for functional microdevices. Nature 2001, 412, 697–698. [Google Scholar] [CrossRef] [PubMed]
  6. Ma, Z.C.; Zhang, Y.L.; Han, B.; Hu, X.Y.; Li, C.H.; Chen, Q.D.; Sun, H.B. Femtosecond laser programmed artificial musculoskeletal systems. Nat. Commun. 2020, 11, 4536. [Google Scholar] [CrossRef] [PubMed]
  7. Sugioka, K.; Cheng, Y. Ultrafast lasers—Reliable tools for advanced materials processing. Light Sci. Appl. 2014, 3, e149. [Google Scholar] [CrossRef]
  8. Phillips, K.C.; Gandhi, H.H.; Mazur, E.; Sundaram, S.K. Ultrafast laser processing of materials: A review. Adv. Opt. Photonics 2015, 7, 684–712. [Google Scholar] [CrossRef]
  9. Yun, S.H.; Kwok, S.J.J. Light in diagnosis, therapy and surgery. Nat. Biomed. Eng. 2017, 1, 0008. [Google Scholar] [CrossRef]
  10. Wang, Y.; Wang, S.; Zhu, Y.; Xu, H.; He, H. Molecular Response of Skin to Micromachining by Femtosecond Laser. Front. Phys. 2021, 9. [Google Scholar] [CrossRef]
  11. Tso, F.; Byer, R. Modeling and CW operation of a quasi-three-level 946 nm Nd: YAG laser. IEEE J. Quantum Electron. 1987, 23, 605–612. [Google Scholar] [CrossRef]
  12. Cante, S.; Valle, S.; Yoon, S.J.; Mackenzie, J.I. 60-W 946-nm cryogenically-cooled Nd:YAG laser. Appl. Phys. B 2019, 125, 135. [Google Scholar] [CrossRef][Green Version]
  13. Wu, W.; Li, X.; Mei, F.; Chen, D.; Yan, R. 30 mJ, 1 kHz sub-nanosecond burst-mode Nd:YAG laser MOPA system. Opt. Express 2019, 27, 36129–36136. [Google Scholar] [CrossRef]
  14. Davide Di Dio Cafiso, S.; Ugolotti, E.; Schmidt, A.; Petrov, V.; Griebner, U.; Agnesi, A.; Cho, W.B.; Jung, B.H.; Rotermund, F.; Bae, S.; et al. Sub-100-fs Cr:YAG laser mode-locked by monolayer graphene saturable absorber. Opt. Lett. 2013, 38, 1745–1747. [Google Scholar] [CrossRef]
  15. Bae Cho, W.; Schmidt, A.; Young Choi, S.; Petrov, V.; Griebner, U.; Steinmeyer, G.; Lee, S.; Yeom, D.-I.; Rotermund, F. Mode locking of a Cr:YAG laser with carbon nanotubes. Opt. Lett. 2010, 35, 2669–2671. [Google Scholar] [CrossRef][Green Version]
  16. Chen, M.; Dai, S.; Yin, H.; Zhu, S.; Li, Z.; Chen, Z. Passively Q-switched yellow laser at 589 nm by intracavity frequency-doubled c-cut composite Nd:YVO4 self-Raman laser. Opt. Laser Technol. 2021, 133, 106534. [Google Scholar] [CrossRef]
  17. Song, J.; Wang, Z.; Lv, R.; Wang, X.; Teng, H.; Zhu, J.; Wei, Z. Generation of 172 fs pulse from a Nd: YVO4 picosecond laser by using multi-pass-cell technique. Appl. Phys. B 2021, 127, 50. [Google Scholar] [CrossRef]
  18. Petit, J.; Goldner, P.; Viana, B. Laser emission with low quantum defect in Yb:CaGdAlO4. Opt. Lett. 2005, 30, 1345–1347. [Google Scholar] [CrossRef]
  19. Tan, W.D.; Tang, D.Y.; Xu, X.D.; Li, D.Z.; Zhang, J.; Xu, C.W.; Cong, Z.H.; Xu, J. Room temperature diode-pumped Yb:CaYAlO4 laser with near quantum limit slope efficiency. Laser Phys. Lett. 2011, 8, 193–196. [Google Scholar] [CrossRef]
  20. Li, D.; Xu, X.; Cheng, Y.; Cheng, S.; Zhou, D.; Wu, F.; Xia, C.; Xu, J.; Zhang, J. Crystal growth and spectroscopic properties of Yb:CaYAlO4 single crystal. J. Cryst. Growth 2010, 312, 2117–2121. [Google Scholar] [CrossRef]
  21. Kirkpatrick, S.M.; Druon, F.; Stoian, R.; Boudeile, J.; Zaouter, Y.; Hanna, M.; Balembois, F.; Georges, P.; Petit, J.; Golner, P.; et al. New Yb-doped crystals for high-power and ultrashort lasers. In Proceedings of the Femtosecond Phenomena and Nonlinear Optics III Conference, Stockholm, Sweden, 29 September 2006. [Google Scholar]
  22. Descamps, D.; Guichard, F.; Petit, S.; Beauvarlet, S.; Comby, A.; Lavenu, L.; Zaouter, Y. High-power sub-15 fs nonlinear pulse compression at 515 nm of an ultrafast Yb-doped fiber amplifier. Opt. Lett. 2021, 46, 1804–1807. [Google Scholar] [CrossRef]
  23. Phillips, J.P.; Banerjee, S.; Mason, P.; Smith, J.; Spear, J.; De Vido, M.; Ertel, K.; Butcher, T.; Quinn, G.; Clarke, D.; et al. Second and third harmonic conversion of a kilowatt average power, 100-J-level diode pumped Yb:YAG laser in large aperture LBO. Opt. Lett. 2021, 46, 1808–1811. [Google Scholar] [CrossRef]
  24. Deng, D.; Zhang, H.; Zu, J.; Chen, J. Buildup dynamics of a pulsating dissipative soliton in an all-normal-dispersion PM Yb-doped fiber laser with a NALM. Opt. Lett. 2021, 46, 1612–1615. [Google Scholar] [CrossRef]
  25. Rosello-Mecho, X.; Delgado-Pinar, M.; Barmenkov, Y.O.; Kir’yanov, A.V.; Andres, M.V. Application of WGM Resonances to the Measurement of the Temperature Increment of Ho and Ho-Yb Doped Optical Fibers Pumped at 1125 and 975 nm. Sensors 2021, 21, 2094. [Google Scholar] [CrossRef]
  26. Petit, J.; Viana, B.; Goldner, P. High thermal conductivity and low quantum defect in Yb:CaGdAlO4, a new infrared laser material for high power applications. In Proceedings of the Advanced Solid-State Photonics (TOPS), Vienna, Austria, 6–9 February 2005; p. 24. [Google Scholar]
  27. Loiko, P.; Becker, P.; Bohaty, L.; Liebald, C.; Peltz, M.; Vernay, S.; Rytz, D.; Serres, J.M.; Mateos, X.; Wang, Y.; et al. Sellmeier equations, group velocity dispersion, and thermo-optic dispersion formulas for CaLnAlO4 (Ln = Y, Gd) laser host crystals. Opt. Lett. 2017, 42, 2275–2278. [Google Scholar] [CrossRef]
  28. Di, J.Q.; Xu, X.D.; Xia, C.T.; Zheng, L.H.; Aka, G.; Yu, H.H.; Sai, Q.L.; Guo, X.Y.; Zhu, L. Crystal growth, polarized spectra, and laser performance of Yb:CaGdAlO4crystal. Laser Phys. 2016, 26, 045803. [Google Scholar] [CrossRef]
  29. Digonnet, M.J.F.; Jaffrès, A.; Ricaud, S.; Suganuma, A.; Viana, B.; Loiseau, P.; Georges, P.; Druon, F.; Jiang, S.; Dries, J.C. Yb: CALGO as material for high power ultrafast laser and focus on thermal conductivity variation. In Proceedings of the Optical Components and Materials X, San Francisco, CA, USA, 2–7 February 2013. [Google Scholar]
  30. Verdùn, H.R.; Thomas, L.M. Growth, Optical Properties, and Stimulated Emission of Nd-Doped Aluminates with the K2NiF4 Structure. In Proceedings of the Advanced Solid State Lasers, Salt Lake City, UT, USA, 5–7 March 1990; p. MT4. [Google Scholar]
  31. Petit, P.O.; Petit, J.; Goldner, P.; Viana, B. Inhomogeneous broadening of optical transitions in Yb:CaYAlO4. Opt. Mater. 2008, 30, 1093–1097. [Google Scholar] [CrossRef]
  32. Lagatskii, A.A.; Kuleshov, N.V.; Shcherbitskii, V.G.; Kleptsyn, V.F.; Mikhailov, V.P.; Ostroumov, V.G.; Huber, G. Lasing characteristics of a diode-pumped Nd3+: CaGdAlO4crystal. Quantum Electron. 1997, 27, 15–17. [Google Scholar] [CrossRef]
  33. Wentsch, K.S.; Weichelt, B.; Günster, S.; Druon, F.; Georges, P.; Ahmed, M.A.; Graf, T. Yb:CaF2 thin-disk laser. Opt. Express 2014, 22, 1524–1532. [Google Scholar] [CrossRef]
  34. Petit, V.; Camy, P.; Doualan, J.L.; Portier, X.; Moncorgé, R. Spectroscopy ofYb3+:CaF2: From isolated centers to clusters. Phys. Rev. B 2008, 78, 085131. [Google Scholar] [CrossRef]
  35. Druon, F.; Ricaud, S.; Papadopoulos, D.N.; Pellegrina, A.; Camy, P.; Doualan, J.L.; Moncorgé, R.; Courjaud, A.; Mottay, E.; Georges, P. On Yb:CaF2 and Yb:SrF2: Review of spectroscopic and thermal properties and their impact on femtosecond and high power laser performance [Invited]. Opt. Mater. Express 2011, 1, 489–502. [Google Scholar] [CrossRef]
  36. Gao, Z.; Zhu, J.; Wang, J.; Wei, Z.; Xu, X.; Zheng, L.; Su, L.; Xu, J. Generation of 33  fs pulses directly from a Kerr-lens mode-locked Yb:CaYAlO_4 laser. Photonics Res. 2015, 3, 335–338. [Google Scholar] [CrossRef]
  37. Loiko, P.; Druon, F.; Georges, P.; Viana, B.; Yumashev, K. Thermo-optic characterization of Yb:CaGdAlO_4 laser crystal. Opt. Mater. Express 2014, 4, 2241–2249. [Google Scholar] [CrossRef][Green Version]
  38. Talik, E.; Kisielewski, J.; Zajdel, P.; Guzik, A.; Wierzbicka, E.; Kania, A.; Kusz, J.; Miga, S.; Szubka, M. XPS spectroscopy, structural, magnetic and dielectric investigations of CaGdAlO4 and Yb:CaGdAlO4 single crystals. Opt. Mater. 2019, 91, 355–362. [Google Scholar] [CrossRef]
  39. Druon, F.; Balembois, F.; Georges, P. New laser crystals for the generation of ultrashort pulses. C. R. Phys. 2007, 8, 153–164. [Google Scholar] [CrossRef]
  40. Pirzio, F.; Kemnitzer, M.; Guandalini, A.; Kienle, F.; Veronesi, S.; Tonelli, M.; Aus der Au, J.; Agnesi, A. Ultrafast, solid-state oscillators based on broadband, multisite Yb-doped crystals. Opt. Express 2016, 24, 11782–11792. [Google Scholar] [CrossRef]
  41. Loiko, P.; Serres, J.M.; Mateos, X.; Xu, X.; Xu, J.; Jambunathan, V.; Navratil, P.; Lucianetti, A.; Mocek, T.; Zhang, X.; et al. Microchip Yb:CaLnAlO4 lasers with up to 91% slope efficiency. Opt. Lett. 2017, 42, 2431–2434. [Google Scholar] [CrossRef]
  42. Brasselet, E.; Malinauskas, M.; Zukauskas, A.; Juodkazis, S. Photopolymerized microscopic vortex beam generators: Precise delivery of optical orbital angular momentum. Appl. Phys. Lett. 2010, 97, 211108. [Google Scholar] [CrossRef]
  43. Beil, K.; Deppe, B.; Krankel, C. Yb:CaGdAlO4 thin-disk laser with 70% slope efficiency and 90 nm wavelength tuning range. Opt. Lett. 2013, 38, 1966–1968. [Google Scholar] [CrossRef]
  44. Sevillano, P.; Georges, P.; Druon, F.; Descamps, D.; Cormier, E. 32-fs Kerr-lens mode-locked Yb:CaGdAlO4 oscillator optically pumped by a bright fiber laser. Opt. Lett. 2014, 39, 6001–6004. [Google Scholar] [CrossRef][Green Version]
  45. Manjooran, S.; Major, A. Diode-pumped 45 fs Yb:CALGO laser oscillator with 1.7 MW of peak power. Opt. Lett. 2018, 43, 2324–2327. [Google Scholar] [CrossRef][Green Version]
  46. Sroor, H.; Huang, Y.-W.; Sephton, B.; Naidoo, D.; Vallés, A.; Ginis, V.; Qiu, C.-W.; Ambrosio, A.; Capasso, F.; Forbes, A. High-purity orbital angular momentum states from a visible metasurface laser. Nat. Photonics 2020, 14, 498–503. [Google Scholar] [CrossRef]
  47. Petit, J.; Goldner, P.; Viana, B.; Didierjean, J.; Balembois, F.; Druon, F.; Georges, P. Quest of athermal solid state laser: Case of Yb:CaGdAlO4. In Proceedings of the Photonics Europe, Strasbourg, France, 3–7 April 2006. [Google Scholar]
  48. Li, D.Z.; Xu, X.D.; Cheng, S.S.; Zhou, D.H.; Wu, F.; Zhao, Z.W.; Xia, C.T.; Xu, J.; Zhang, J.; Zhu, H.M.; et al. Polarized spectral properties of Nd3+ ions in CaYAlO4 crystal. Appl. Phys. B 2010, 101, 199–205. [Google Scholar] [CrossRef]
  49. Koerner, J.; Kaluza, M.C.; Kloepfel, D.; Vorholt, C.; Kahle, M.; Liebetrau, H.; Seifert, R.; Hein, J. Measurement of temperature-dependent absorption and emission spectra of Yb:YAG, Yb:LuAG, and Yb:CaF2 between 20 °C and 200 °C and predictions on their influence on laser performance. JOSA B 2012, 29, 2493–2502. [Google Scholar] [CrossRef]
  50. Zaouter, Y.; Didierjean, J.; Balembois, F.; Leclin, G.L.; Druon, F.; Georges, P.; Petit, J.; Goldner, P.; Viana, B. 47-fs diode-pumped Yb3+:CaGdAlO4 laser. Opt. Lett. 2006, 31, 119–121. [Google Scholar] [CrossRef] [PubMed][Green Version]
  51. Caracciolo, E.; Kemnitzer, M.; Guandalini, A.; Pirzio, F.; Agnesi, A.; Aus der Au, J. High pulse energy multiwatt Yb:CaAlGdO4 and Yb:CaF2 regenerative amplifiers. Opt. Express 2014, 22, 19912–19918. [Google Scholar] [CrossRef] [PubMed]
  52. Boudeile, J.; Druon, F.; Hanna, M.; Georges, P.; Zaouter, Y.; Cormier, E.; Petit, J.; Goldner, P.; Viana, B. Continuous-wave and femtosecond laser operation of Yb:CaGdAlO4 under high-power diode pumping. Opt. Lett. 2007, 32, 1962–1964. [Google Scholar] [CrossRef][Green Version]
  53. Wang, J.; Shi, L.; Li, Y.; Jin, L.; Xu, Y.; Zhang, H.; Zou, Y.; Lan, Y.; Ma, X. Thermal management of graphene-induced high-power semiconductor laser package with bidirectional conduction structure. Opt. Laser Technol. 2021, 139, 106927. [Google Scholar] [CrossRef]
  54. Petit, J.; Viana, B.; Goldner, P.; Roger, J.-P.; Fournier, D. Thermomechanical properties of Yb3+ doped laser crystals: Experiments and modeling. J. Appl. Phys. 2010, 108, 123108. [Google Scholar] [CrossRef]
  55. Jiang, S.; Digonnet, M.J.F.; Jaffres, A.; Sharma, S.K.; Loiseau, P.; Viana, B.; Doualan, J.L.; Moncorgé, R. UV-visible luminescence properties of the broad-band Yb:CALGO laser crystal. In Proceedings of the Optical Components and Materials XII, San Francisco, CA, USA, 7–12 February 2015. [Google Scholar]
  56. Akbari, R.; Loiko, P.; Major, A.; Clarkson, W.A.; Shori, R.K. Thermal lensing in diode-pumped Yb:CALGO and Yb:KGW lasers. In Proceedings of the Solid State Lasers XXIX: Technology and Devices, San Francisco, CA, USA, 4–6 February 2020. [Google Scholar]
  57. Calendron, A.L. Dual-crystal Yb:CALGO high power laser and regenerative amplifier. Opt. Express 2013, 21, 26174–26181. [Google Scholar] [CrossRef][Green Version]
  58. Druon, F.; Olivier, M.; Jaffres, A.; Loiseau, P.; Aubry, N.; DidierJean, J.; Balembois, F.; Viana, B.; Georges, P. Magic mode switching in Yb:CaGdAlO4 laser under high pump power. Opt. Lett. 2013, 38, 4138–4141. [Google Scholar] [CrossRef][Green Version]
  59. Hasse, K.; Calmano, T.; Deppe, B.; Liebald, C.; Krankel, C. Efficient Yb3+:CaGdAlO4 bulk and femtosecond-laser-written waveguide lasers. Opt. Lett. 2015, 40, 3552–3555. [Google Scholar] [CrossRef]
  60. Hasse, K.; Kränkel, C. Yb:CALGO waveguide laser written with 1 MHz-repetition rate fs-laser. In Proceedings of the Laser Congress 2019 (ASSL, LAC, LS&C), Vienna, Austria, 29 September–3 October 2019; p. ATu1A.7. [Google Scholar]
  61. Manjooran, S.; Major, A.; Clarkson, W.A.; Shori, R.K. Comparative studies of high power diode-pumped Yb:CALGO and Yb:KYW lasers. In Proceedings of the Solid State Lasers XXVIII: Technology and Devices, San Francisco, CA, USA, 5–7 February 2019. [Google Scholar]
  62. Reza, M.A.R.; Loiko, P.; Major, A.; Clarkson, W.A.; Shori, R.K. Intracavity loss measurement in a diode-pumped Yb:CALGO laser. In Proceedings of the Solid State Lasers XXVIII: Technology and Devices, San Francisco, CA, USA, 5–7 February 2019. [Google Scholar]
  63. Clarkson, W.A.; Ricaud, S.; Jaffres, A.; Loiseau, P.; Viana, B.; Weichelt, B.; Abdou-Ahmed, M.; Voss, A.; Graf, T.; Rytz, D.; et al. Yb:CaGdAlO4 thin-disk. In Proceedings of the Solid State Lasers XXI: Technology and Devices, San Francisco, CA, USA, 22–25 January 2012. [Google Scholar]
  64. Reza, A.R.; Akbari, R.; Major, A.; Clarkson, W.A.; Shori, R.K. Dual-wavelength Yb:CALGO laser with wavelength spacing tunability. In Proceedings of the Solid State Lasers XXIX: Technology and Devices, San Francisco, CA, USA, 4–6 February 2020. [Google Scholar]
  65. Ricaud, S.; Jaffres, A.; Loiseau, P.; Viana, B.; Weichelt, B.; Abdou-Ahmed, M.; Voss, A.; Graf, T.; Rytz, D.; Delaigue, M.; et al. Yb:CaGdAlO4 thin-disk laser. Opt. Lett. 2011, 36, 4134–4136. [Google Scholar] [CrossRef][Green Version]
  66. Boudeile, J.; Didierjean, J.; Balembois, F.; Druon, F.; Georges, P.; Petit, J.; Goldner, P.; Viana, B. High power diode pumped Yb3+:CaGdAlO4 laser. In Proceedings of the Advanced Solid-State Photonics, Nara, Japan, 27–30 January 2008; p. WE28. [Google Scholar]
  67. Scheller, M.; Yarborough, J.M.; Moloney, J.V.; Fallahi, M.; Koch, M.; Koch, S.W. Room temperature continuous wave milliwatt terahertz source. Opt. Express 2010, 18, 27112–27117. [Google Scholar] [CrossRef]
  68. Chang, S.; Mao, Y.; Flueraru, C. Dual-Source Swept-Source Optical Coherence Tomography Reconstructed on Integrated Spectrum. Int. J. Opt. 2012, 2012, 565823. [Google Scholar] [CrossRef]
  69. Manjooran, S.; Loiko, P.; Major, A. A discretely tunable dual-wavelength multi-watt Yb:CALGO laser. Appl. Phys. B 2017, 124, 13. [Google Scholar] [CrossRef]
  70. Du, X.; Guo, J.; Wang, W.; Sun, D.; Gao, Y.; Liang, X. Wavelength shift with a diode-pumped continuous-wave Yb:CALGO laser. Appl. Opt. 2020, 59, 2097–2100. [Google Scholar] [CrossRef] [PubMed]
  71. Forbes, A.; de Oliveira, M.; Dennis, M.R. Structured light. Nat. Photonics 2021, 15, 253–262. [Google Scholar] [CrossRef]
  72. Forbes, A. Structured Light from Lasers. Laser Photonics Rev. 2019, 13, 1900140. [Google Scholar] [CrossRef]
  73. Shen, Y.; Wang, X.; Xie, Z.; Min, C.; Fu, X.; Liu, Q.; Gong, M.; Yuan, X. Optical vortices 30 years on: OAM manipulation from topological charge to multiple singularities. Light Sci. Appl. 2019, 8, 90. [Google Scholar] [CrossRef][Green Version]
  74. Céspedes Vicente, O.; Caloz, C. Bessel beams: A unified and extended perspective. Optica 2021, 8, 451–457. [Google Scholar] [CrossRef]
  75. Efremidis, N.K.; Chen, Z.; Segev, M.; Christodoulides, D.N. Airy beams and accelerating waves: An overview of recent advances. Optica 2019, 6, 686. [Google Scholar] [CrossRef][Green Version]
  76. Wang, S.; Zhang, S.; Yang, H.; Xie, J.; Jiang, S.; Feng, G.; Zhou, S. Direct emission of chirality controllable femtosecond LG01 vortex beam. Appl. Phys. Lett. 2018, 112, 201110. [Google Scholar] [CrossRef]
  77. Shen, Y.; Meng, Y.; Fu, X.; Gong, M. Wavelength-tunable Hermite-Gaussian modes and an orbital-angular-momentum-tunable vortex beam in a dual-off-axis pumped Yb:CALGO laser. Opt. Lett. 2018, 43, 291–294. [Google Scholar] [CrossRef][Green Version]
  78. Shen, Y.; Meng, Y.; Fu, X.; Gong, M. Dual-wavelength vortex beam with high stability in a diode-pumped Yb:CaGdAlO4laser. Laser Phys. Lett. 2018, 15, 055803. [Google Scholar] [CrossRef][Green Version]
  79. Bužek, V.; Quang, T. Generalized coherent state for bosonic realization of SU(2)Lie algebra. J. Opt. Soc. Am. B 1989, 6, 2447–2449. [Google Scholar] [CrossRef]
  80. Shen, Y.; Wan, Z.; Fu, X.; Liu, Q.; Gong, M. Vortex lattices with transverse-mode-locking states switching in a large-aperture off-axis-pumped solid-state laser. J. Opt. Soc. Am. B 2018, 35, 2940–2944. [Google Scholar] [CrossRef]
  81. Shen, Y.; Yang, X.; Fu, X.; Gong, M. Periodic-trajectory-controlled, coherent-state-phase-switched, and wavelength-tunable SU(2) geometric modes in a frequency-degenerate resonator. Appl. Opt. 2018, 57, 9543–9549. [Google Scholar] [CrossRef] [PubMed]
  82. Shen, Y.; Wan, Z.; Meng, Y.; Fu, X.; Gong, M. Polygonal Vortex Beams. IEEE Photonics J. 2018, 10, 1–16. [Google Scholar] [CrossRef]
  83. Pan, J.; Shen, Y.; Wan, Z.; Fu, X.; Zhang, H.; Liu, Q. Index-Tunable Structured-Light Beams from a Laser with an Intracavity Astigmatic Mode Converter. Phys. Rev. Appl. 2020, 14, 044048. [Google Scholar] [CrossRef]
  84. Zhao, L.; Yuan, Y.; Tong, L.; Cai, F.; Zhang, W.; Cai, Y. Broadly tunable optical vortex beam in a diode-pumped Yb:CALGO laser. Opt. Laser Technol. 2021, 141, 107134. [Google Scholar] [CrossRef]
  85. Wang, D.; Lei, M.; Lin, S.; Zheng, Y.; Kang, S.; Huang, L. Generation of a mode-tunable optical vortex based on a mirror curvature dynamically controlled Z-shaped resonant cavity. Opt. Lett. 2021, 46, 3079–3082. [Google Scholar] [CrossRef]
  86. Yuan, Y.; Tong, L.; Cai, F.; Zhang, W.; Cai, Y.; Zhao, L. Direct generation of optical vortex arrays by rotating in an all-solid-state Yb:CALGO laser. Opt. Mater. Express 2021, 11, 1594–1602. [Google Scholar] [CrossRef]
  87. Turpin, A.; Loiko, Y.V.; Kalkandjiev, T.K.; Mompart, J. Conical refraction: Fundamentals and applications. Laser Photonics Rev. 2016, 10, 750–771. [Google Scholar] [CrossRef][Green Version]
  88. Reza, A.R.; Akbari, R.; Fedorova, K.; Sokolovskii, G.; Rafailov, E.; Major, A.; Clarkson, W.A.; Shori, R.K. Diode-pumped Yb:CALGO laser with conical refraction output. In Proceedings of the Solid State Lasers XXIX: Technology and Devices, San Francisco, CA, USA, 4–6 February 2020. [Google Scholar]
  89. Jiang, Y.; Yang, J.; Li, P.; Si, H.; Fu, X.; Liu, Q. High energy LiDAR source for long distance, high resolution range imaging. Microw. Opt. Technol. Lett. 2020, 62, 3655–3661. [Google Scholar] [CrossRef]
  90. Edwards, M.J.; Patel, P.K.; Lindl, J.D.; Atherton, L.J.; Glenzer, S.H.; Haan, S.W.; Kilkenny, J.D.; Landen, O.L.; Moses, E.I.; Nikroo, A.; et al. Progress towards ignition on the National Ignition Facility. Phys. Plasmas 2013, 20, 070501. [Google Scholar] [CrossRef]
  91. Malcolm, G.P.A.; Ferguson, A.I. Mode-locking of diode laser-pumped solid-state lasers. Opt. Quantum Electron. 1992, 24, 705–717. [Google Scholar] [CrossRef]
  92. Agnesi, A.; Greborio, A.; Pirzio, F.; Reali, G.; Aus der Au, J.; Guandalini, A. 40-fs Yb3+:CaGdAlO4 laser pumped by a single-mode 350-mW laser diode. Opt. Express 2012, 20, 10077–10082. [Google Scholar] [CrossRef][Green Version]
  93. Alessandro, G.; Annalisa, G.; Juerg Aus der, A. Sub-100 fs pulses with 12.5-W from Yb:CALGO based oscillators. In Proceedings of the SPIE, San Francisco, CA, USA, 22–25 January 2012. [Google Scholar]
  94. Agnesi, A.; Greborio, A.; Pirzio, F.; Ugolotti, E.; Reali, G.; Guandalini, A.; Aus der Au, J. Diode-pumped passively mode-locked tunable Yb:CALGO solid-state laser. J. Opt. Soc. Am. B 2013, 30, 1513–1516. [Google Scholar] [CrossRef]
  95. Pirzio, F.; Cafiso, S.D.; Kemnitzer, M.; Guandalini, A.; Kienle, F.; Veronesi, S.; Tonelli, M.; Aus der Au, J.; Agnesi, A. Sub-50-fs widely tunable Yb:CaYAlO(4) laser pumped by 400-mW single-mode fiber-coupled laser diode. Opt. Express 2015, 23, 9790–9795. [Google Scholar] [CrossRef]
  96. Mollenauer, L.F.; Stolen, R.H. The soliton laser. Opt. Lett. 1984, 9, 13–15. [Google Scholar] [CrossRef] [PubMed]
  97. Phillips, C.R.; Mayer, A.S.; Klenner, A.; Keller, U. SESAM modelocked Yb:CaGdAlO4 laser in the soliton modelocking regime with positive intracavity dispersion. Opt. Express 2014, 22, 6060–6077. [Google Scholar] [CrossRef]
  98. Phillips, C.R.; Mayer, A.S.; Klenner, A.; Keller, U. Femtosecond mode locking based on adiabatic excitation of quadratic solitons. Optica 2015, 2, 667–674. [Google Scholar] [CrossRef]
  99. Mayer, A.S.; Phillips, C.R.; Keller, U. Watt-level 10-gigahertz solid-state laser enabled by self-defocusing nonlinearities in an aperiodically poled crystal. Nat. Commun. 2017, 8, 1673. [Google Scholar] [CrossRef] [PubMed]
  100. Klenner, A.; Golling, M.; Keller, U. High peak power gigahertz Yb:CALGO laser. Opt. Express 2014, 22, 11884–11891. [Google Scholar] [CrossRef][Green Version]
  101. Kruger, L.M.; Mayer, A.S.; Okawachi, Y.; Ji, X.; Klenner, A.; Johnson, A.R.; Langrock, C.; Fejer, M.M.; Lipson, M.; Gaeta, A.L.; et al. Performance scaling of a 10-GHz solid-state laser enabling self-referenced CEO frequency detection without amplification. Opt. Express 2020, 28, 12755–12770. [Google Scholar] [CrossRef] [PubMed]
  102. Liu, X.; Pang, M. Revealing the Buildup Dynamics of Harmonic Mode-Locking States in Ultrafast Lasers. Laser Photonics Rev. 2019, 13, 1800333. [Google Scholar] [CrossRef]
  103. Bensch, H.M.; Herink, G.; Kurtz, F.; Morgner, U. Harmonically mode-locked Yb:CALGO laser oscillator. Opt. Express 2017, 25, 14164–14172. [Google Scholar] [CrossRef]
  104. Wang, S.; Wang, Y.B.; Feng, G.Y.; Zhou, S.H. Harmonically mode-locked Yb:CALGO laser pumped by a single-mode 1.2 W laser diode. Opt. Express 2018, 26, 1521–1529. [Google Scholar] [CrossRef]
  105. Gao, Z.; Zhu, J.; Wang, J.; Wang, Z.; Wei, Z.; Xu, X.; Zheng, L.; Su, L.; Xu, J. Diode-pumped Kerr-lens mode-locked Yb:CaGdAlO4laser with tunable wavelength. Laser Phys. Lett. 2016, 13, 015302. [Google Scholar] [CrossRef]
  106. Papadopoulos, D.N.; Druon, F.; Boudeile, J.; Martial, I.; Hanna, M.; Georges, P.; Petit, P.O.; Goldner, P.; Viana, B. Low-repetition-rate femtosecond operation in extended-cavity mode-locked Yb:CALGO laser. Opt. Lett. 2009, 34, 196–198. [Google Scholar] [CrossRef] [PubMed][Green Version]
  107. Shori, R.K.; Clarkson, W.A.; Major, A.; Manjooran, S. Low repetition rate operation of a femtosecond Yb:CALGO laser. In Proceedings of the Solid State Lasers XXVII: Technology and Devices, San Francisco, CA, USA, 29 January–1 February 2018. [Google Scholar]
  108. Kimura, S.; Tani, S.; Kobayashi, Y. Raman-assisted broadband mode-locked laser. Sci. Rep. 2019, 9, 3738. [Google Scholar] [CrossRef]
  109. Labaye, F.; Wittwer, V.J.; Modsching, N.; Razskazovskaya, O.; Cormier, E.; Südmeyer, T. Yb.CALGO Oscillator Generates 31-fs Pulses with 389 mW at 29% Efficiency by Cross-Polarized Optical Pumping. In Proceedings of the Conference on Lasers and Electro-Optics, Washington, DC, USA, 10–15 May 2020; p. SF2H.2. [Google Scholar]
  110. Wang, Y.; Su, X.; Xie, Y.; Gao, F.; Kumar, S.; Wang, Q.; Liu, C.; Zhang, B.; Zhang, B.; He, J. 17.8  fs broadband Kerr-lens mode-locked Yb:CALGO oscillator. Opt. Lett. 2021, 46, 1892–1895. [Google Scholar] [CrossRef]
  111. Klenner, A.; Keller, U. All-optical Q-switching limiter for high-power gigahertz modelocked diode-pumped solid-state lasers. Opt. Express 2015, 23, 8532–8544. [Google Scholar] [CrossRef] [PubMed][Green Version]
  112. Wang, Y.; Wang, S.; Feng, G.; Zhou, S. SESAM combined Kerr lens mode locked Yb:CALGO laser pumped by a 1.2 W single mode fiber coupled laser diode. Laser Phys. Lett. 2017, 14, 055003. [Google Scholar] [CrossRef]
  113. Akbari, R.; Zhao, H.; Fedorova, K.A.; Rafailov, E.U.; Major, A. Quantum-dot saturable absorber and Kerr-lens mode-locked Yb:KGW laser with >450 kW of peak power. Opt. Lett. 2016, 41, 3771–3774. [Google Scholar] [CrossRef] [PubMed]
  114. Tong, L.; Cai, F.; Xu, Q.; Ji, Y.; Liu, J.; Cai, Y.; Zhao, L. Nonlinear-mirror mode-locked 1052 nm Yb:CALGO laser. Opt. Quantum Electron. 2019, 51, 223. [Google Scholar] [CrossRef]
  115. Caracciolo, E.; Kemnitzer, M.; Guandalini, A.; Pirzio, F.; Aus der Au, J.; Agnesi, A. 28-W, 217 fs solid-state Yb:CAlGdO4 regenerative amplifiers. Opt. Lett. 2013, 38, 4131–4133. [Google Scholar] [CrossRef][Green Version]
  116. Pouysegur, J.; Delaigue, M.; Zaouter, Y.; Honninger, C.; Mottay, E.; Jaffres, A.; Loiseau, P.; Viana, B.; Georges, P.; Druon, F. Sub-100-fs Yb:CALGO nonlinear regenerative amplifier. Opt. Lett. 2013, 38, 5180–5183. [Google Scholar] [CrossRef]
  117. Caracciolo, E.; Kemnitzer, M.; Rumpel, M.; Guandalini, A.; Pirzio, F.; Kienle, F.; Graf, T.; Abdou Ahmed, M.; Aus der Au, J.; Agnesi, A. Single-grating-mirror intracavity stretcher design for chirped pulse regenerative amplification. Opt. Lett. 2015, 40, 1532–1535. [Google Scholar] [CrossRef]
  118. Molteni, L.M.; Canella, F.; Pirzio, F.; Betz, M.; Vicentini, E.; Coluccelli, N.; Piccinno, G.; Agnesi, A.; Laporta, P.; Galzerano, G. Low-noise Yb:CALGO optical frequency comb. Opt. Express 2021, 29, 19495–19505. [Google Scholar] [CrossRef]
  119. Wang, W.; Wu, H.; Liu, C.; Sun, B.; Liang, H. Multigigawatt 50fs Yb:CALGO regenerative amplifier system with 11W average power and mid-infrared generation. Photonics Res. 2021, 9, 1439–1445. [Google Scholar] [CrossRef]
  120. Ricaud, S.; Jaffres, A.; Wentsch, K.; Suganuma, A.; Viana, B.; Loiseau, P.; Weichelt, B.; Abdou-Ahmed, M.; Voss, A.; Graf, T.; et al. Femtosecond Yb:CaGdAlO4 thin-disk oscillator. Opt. Lett. 2012, 37, 3984–3986. [Google Scholar] [CrossRef] [PubMed][Green Version]
  121. Diebold, A.; Emaury, F.; Schriber, C.; Golling, M.; Saraceno, C.J.; Sudmeyer, T.; Keller, U. SESAM mode-locked Yb:CaGdAlO4 thin disk laser with 62 fs pulse generation. Opt. Lett. 2013, 38, 3842–3845. [Google Scholar] [CrossRef] [PubMed][Green Version]
  122. Modsching, N.; Paradis, C.; Labaye, F.; Gaponenko, M.; Graumann, I.J.; Diebold, A.; Emaury, F.; Wittwer, V.J.; Sudmeyer, T. Kerr lens mode-locked Yb:CALGO thin-disk laser. Opt. Lett. 2018, 43, 879–882. [Google Scholar] [CrossRef] [PubMed][Green Version]
Figure 2. (a) A high-power Yb:CALGO oscillator [58]. (b) The first fs-laser-written waveguide laser in Yb:CALGO [59]. (c) High-efficiency Yb:CALGO thin disk [63]. (d) The performance of the first Yb:CALGO microchip laser [41]. (e) Dual-wavelength [64] and (f) broad wavelength-tunable [43] lasers. (ac) are redrawn based on refs. [58,59,63], respectively. (d) Reprinted with permission from ref. [41], ©The Optical Society. (e) Reprinted with permission from ref. [64], SPIE. (f) Reprinted with permission from ref. [43], ©The Optical Society.
Figure 2. (a) A high-power Yb:CALGO oscillator [58]. (b) The first fs-laser-written waveguide laser in Yb:CALGO [59]. (c) High-efficiency Yb:CALGO thin disk [63]. (d) The performance of the first Yb:CALGO microchip laser [41]. (e) Dual-wavelength [64] and (f) broad wavelength-tunable [43] lasers. (ac) are redrawn based on refs. [58,59,63], respectively. (d) Reprinted with permission from ref. [41], ©The Optical Society. (e) Reprinted with permission from ref. [64], SPIE. (f) Reprinted with permission from ref. [43], ©The Optical Society.
Crystals 11 01131 g002
Figure 3. (a) Wavelength- and OAM-tunable Yb:CALGO laser [77]. (b) Two-dimensional tunable high order mode laser [83]. (c) Mode-tunable laser based on a mirror curvature dynamically controlled Z-shaped resonator [85]. (a) Reprinted with permission from ref. [77], ©The Optical Society. (b) Reprinted with permission from ref. [83], the American Physical Society. (c) Reprinted with permission from ref. [85], ©The Optical Society.
Figure 3. (a) Wavelength- and OAM-tunable Yb:CALGO laser [77]. (b) Two-dimensional tunable high order mode laser [83]. (c) Mode-tunable laser based on a mirror curvature dynamically controlled Z-shaped resonator [85]. (a) Reprinted with permission from ref. [77], ©The Optical Society. (b) Reprinted with permission from ref. [83], the American Physical Society. (c) Reprinted with permission from ref. [85], ©The Optical Society.
Crystals 11 01131 g003
Table 1. Chemical and physical properties of Yb:CALGO [27,38,39,40,41,42,43,44,45,46,47].
Table 1. Chemical and physical properties of Yb:CALGO [27,38,39,40,41,42,43,44,45,46,47].
Chemical PropertiesValuesPhysical PropertiesValues
Space groupI4/mmm ( D 4 h 17 )Density5.97 g/cm3
symmetryC4vMelting point1840 ℃
Lattice dimensionsa = 3.66 Å
c = 12.01 Å
Refractive indexno = 1.9331
ne = 1.9564
Lattice volume161.15 Å3Group velocity dispersion∼95 fs2/mm
Molecular weight288.31 g/molThermo-optic coefficientsdno/dT = –7.6 × 10−6 K−1
dne/dT = –8.6 × 10−6 K−1
Occupation siteGd3+/Ca2+Gain bandwidth~90 nm
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Wang, H.; Pan, J.; Meng, Y.; Liu, Q.; Shen, Y. Advances of Yb:CALGO Laser Crystals. Crystals 2021, 11, 1131. https://doi.org/10.3390/cryst11091131

AMA Style

Wang H, Pan J, Meng Y, Liu Q, Shen Y. Advances of Yb:CALGO Laser Crystals. Crystals. 2021; 11(9):1131. https://doi.org/10.3390/cryst11091131

Chicago/Turabian Style

Wang, Hao, Jing Pan, Yuan Meng, Qiang Liu, and Yijie Shen. 2021. "Advances of Yb:CALGO Laser Crystals" Crystals 11, no. 9: 1131. https://doi.org/10.3390/cryst11091131

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop