Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I−/I2 Ternary System
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. I3@BB(I3)3·2DMSO
3.2. Structural Comparison
3.3. Hirshfeld Surface Analysis
3.4. Raman Evidence
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References and Note
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I2 | I3− | I5− | Assignment |
---|---|---|---|
66 m | bending v2 | ||
112 vs | symmetric stretch v1 | ||
145 m | asymmetric stretch v3 | ||
170 s | symmetric stretch V-shaped | ||
192 m | Symmetric stretch v1 |
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Savastano, M.; Bazzicalupi, C.; Gellini, C.; Bianchi, A. Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I−/I2 Ternary System. Crystals 2020, 10, 387. https://doi.org/10.3390/cryst10050387
Savastano M, Bazzicalupi C, Gellini C, Bianchi A. Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I−/I2 Ternary System. Crystals. 2020; 10(5):387. https://doi.org/10.3390/cryst10050387
Chicago/Turabian StyleSavastano, Matteo, Carla Bazzicalupi, Cristina Gellini, and Antonio Bianchi. 2020. "Genesis of Complex Polyiodide Networks: Insights on the Blue Box/I−/I2 Ternary System" Crystals 10, no. 5: 387. https://doi.org/10.3390/cryst10050387