Selective Conversion of Phenol in a Subcritical Water Medium Using γ-Al2O3 Supported Ni–Co Bimetallic Catalyst
Abstract
:1. Introduction
2. Results and Discussion
2.1. Catalyst Characterization
2.2. Selection of Catalyst for the Conversion of Phenol
2.3. Selective Conversion Kinetic Behaviors of Phenol
2.4. Developing a Kinetic Model for the Conversion of Phenol
2.4.1. Model Development
2.4.2. Parameters Determination and Model Evaluation
3. Experiments
3.1. Materials
3.2. Catalyst Preparation
3.3. Catalyst Characterization
3.4. Phenol Hydrogenation
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | SBET (m2.g−1) a | VP (cm3.g−1) b | DP (nm) c |
---|---|---|---|
γ-Al2O3 | 122.75 | 0.6627 | 22.90 |
Ni/γ-Al2O3 | 109.50 | 0.5237 | 17.24 |
Ni–3Co/γ-Al2O3 | 102.48 | 0.4496 | 13.76 |
Ni–1.5Co/γ-Al2O3 | 113.18 | 0.4634 | 13.89 |
Ni–1Co/γ-Al2O3 | 107.70 | 0.4922 | 15.39 |
Ni–0.67Co/γ-Al2O3 | 105.30 | 0.5026 | 16.72 |
Ni–0.33Co/γ-Al2O3 | 101.06 | 0.5149 | 17.52 |
Co/γ-Al2O3 | 106.42 | 0.5061 | 16.28 |
Parameter | Cp0 (mol/L) | k’ | m | t0 (min) | Ea (kJ/mol) |
---|---|---|---|---|---|
Value | 0.0864 | 317.13 | 1.15 | 0 | 37.82 |
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Shi, Y.; Chen, S.; He, L.; Ning, P.; Guan, Q. Selective Conversion of Phenol in a Subcritical Water Medium Using γ-Al2O3 Supported Ni–Co Bimetallic Catalyst. Catalysts 2019, 9, 212. https://doi.org/10.3390/catal9030212
Shi Y, Chen S, He L, Ning P, Guan Q. Selective Conversion of Phenol in a Subcritical Water Medium Using γ-Al2O3 Supported Ni–Co Bimetallic Catalyst. Catalysts. 2019; 9(3):212. https://doi.org/10.3390/catal9030212
Chicago/Turabian StyleShi, Yuzhen, Shanshuai Chen, Liang He, Ping Ning, and Qingqing Guan. 2019. "Selective Conversion of Phenol in a Subcritical Water Medium Using γ-Al2O3 Supported Ni–Co Bimetallic Catalyst" Catalysts 9, no. 3: 212. https://doi.org/10.3390/catal9030212