Next Article in Journal
Metal-Free Organocatalysis
Previous Article in Journal
Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water
Open AccessArticle

Palladium-Catalyzed Isomerization-Coupling Reactions of Allyl Chloride with Amines to Generate Functionalized Phosphorus Derivatives

1
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China
2
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
*
Author to whom correspondence should be addressed.
These two authors contributed equally to this work.
Catalysts 2018, 8(5), 194; https://doi.org/10.3390/catal8050194
Received: 17 April 2018 / Revised: 26 April 2018 / Accepted: 27 April 2018 / Published: 5 May 2018
  |  
PDF [7282 KB, uploaded 5 May 2018]
  |  

Abstract

A Pd-catalyzed isomerization-coupling reaction of P-containing allyl chloride with amine afforded imine or enamine that was converted to various functionalized phosphorus derivatives via hydrolysis, reduction, or Stork reactions. The reaction was confirmed to proceed via an isomerization of a starting material and a coupling of the resulting vinyl chloride with amine. View Full-Text
Keywords: isomerization-coupling; allyl chloride; amines; phosphorus derivatives; Stork reactions isomerization-coupling; allyl chloride; amines; phosphorus derivatives; Stork reactions
Figures

Chart 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

Supplementary material

SciFeed

Share & Cite This Article

MDPI and ACS Style

Wen, J.-H.; Li, Q.; Nie, S.-Z.; Ye, J.-J.; Xu, Q.; Zhao, C.-Q. Palladium-Catalyzed Isomerization-Coupling Reactions of Allyl Chloride with Amines to Generate Functionalized Phosphorus Derivatives. Catalysts 2018, 8, 194.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Catalysts EISSN 2073-4344 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top