Recent Advances in Catalyst Design and Process Intensification for Ethanol Steam Reforming

Producing hydrogen from ethanol steam reforming (ESR) is a carbon-neutral and environment-friendly method, which has been expected to reduce the excessive emission of environmental pollution and over-exploitation of fossil resources. Currently, great advances have been made on heterogeneous catalysts, but an in-depth and more comprehensive understanding to further promote this reaction process is still required. Herein, the thermodynamic and kinetic analyses of ESR are firstly highlighted. Then, various reaction pathways of ESR are discussed in detail, respectively combined with experimental studies and density functional theory calculations. On this basis, the key factors affecting the catalytic performance over non-noble and noble metal catalysts are summarized, such as alloying, optimization of the preparation methods, promoter addition and support modification. In addition, the process intensification technologies, including catalytic membrane reactors, adsorption-enhanced reforming and microchannel reactors, are analyzed regarding breaking the thermodynamic limitations and improving the heat and mass transfer efficiency. Finally, the challenges and potential strategies of ESR in the research of dynamic reaction mechanisms, regulation of catalyst stability and integration of intensification technologies are summarized.