Highly Efficient and Selective Oxidation of Benzyl Alcohol by WO42− Catalyst Immobilized by a Phosphonium-Containing Porous Aromatic Framework
Abstract
:1. Introduction
2. Results
2.1. Structural Characterization
2.2. Catalytic Performance
3. Materials and Methods
3.1. Synthesis of tris(4-bromobiphenyl)phosphine
3.2. Synthesis of PAF-181
3.3. Synthesis of WO4@PAF-181
3.4. Catalytic Reaction
3.5. Leaching Experiment
3.6. Loop Test
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | Acid | Temperature (°C) | T (h) | Yield (%) b |
---|---|---|---|---|---|
1 | WO4@PAF-181 | None | 110 | 24 | 13 |
2 | WO4@PAF-181 | Tartaric acid | 110 | 7 | 69 |
3 | WO4@PAF-181 | TsOH | 110 | 7 | 73 |
4 c | WO4@PAF-181 | NaHSO4 | 110 | 7 | 53 |
5 | None | NaHSO4 | 110 | 7 | 26 |
6 | PAF-181 | NaHSO4 | 110 | 7 | 10 |
7 | I@PAF-181 | NaHSO4 | 110 | 7 | 16 |
8 | Na2WO4 | NaHSO4 | 110 | 7 | 77 |
9 d | WO4@PAF-181 | NaHSO4 | 110 | 7 | 0 |
10 e | WO4@PAF-181 | NaHSO4 | 110 | 7 | 96 |
11 | WO4@PAF-181 | NaHSO4 | 110 | 7 | 99 |
12 | WO4@PAF-181 | NaHSO4 | 60 | 7 | 81 |
13 | WO4@PAF-181 | NaHSO4 | r.t. | 7 | 58 |
Entry | Substrates | Products | Yield (%) b |
---|---|---|---|
1 | 95 | ||
2 | 94 | ||
3 | 93 | ||
4 | 95 | ||
5 | 96 | ||
6 | 92 | ||
7 | 91 | ||
8 | 91 | ||
9 | 90 | ||
10 | 91 | ||
11 | 89 | ||
12 | 93 | ||
13 | 92 | ||
14 | 89 | ||
15 | 91 |
Entry | Catalysts | Oxidant | Solvent | Yield (%) | Ref. |
---|---|---|---|---|---|
1 | WO4@PAF-181 | H2O2 | H2O | 99 | this work |
2 | I@PAF-181 | H2O2 | H2O | 16 | |
3 | PAF-181 | H2O2 | H2O | 10 | |
4 | Na2WO4 | H2O2 | H2O | 77 | |
5 | HPW/MCM-48 | H2O2 | H2O | 66 | [49] |
6 | Au/PDVB-VI-n | O2 | H2O | 80 | [1] |
7 | Au1–xAgx | O2 | H2O | 67 | [50] |
8 | Au/Al2O3 | O2 | EtOH | 81 | [51] |
9 | Au101/AC | O2 | EtOH | 76 | [52] |
10 | p-Co3O4 | O2 | CH3CN | 30 | [53] |
11 | Fe3O4@SiO2-Schiff base-Co(II) | O2 | CH3CN | 91 | [54] |
12 | Holey HEO | O2 | - | 16 | [55] |
13 | RPB-O3 | O3 | ethyl acetate | 94 | [56] |
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You, B.; Cheng, Z.; Tian, Y.; Wang, S.; Wang, B. Highly Efficient and Selective Oxidation of Benzyl Alcohol by WO42− Catalyst Immobilized by a Phosphonium-Containing Porous Aromatic Framework. Catalysts 2023, 13, 1309. https://doi.org/10.3390/catal13091309
You B, Cheng Z, Tian Y, Wang S, Wang B. Highly Efficient and Selective Oxidation of Benzyl Alcohol by WO42− Catalyst Immobilized by a Phosphonium-Containing Porous Aromatic Framework. Catalysts. 2023; 13(9):1309. https://doi.org/10.3390/catal13091309
Chicago/Turabian StyleYou, Bingxin, Zeliang Cheng, Yuyang Tian, Shaolei Wang, and Baolin Wang. 2023. "Highly Efficient and Selective Oxidation of Benzyl Alcohol by WO42− Catalyst Immobilized by a Phosphonium-Containing Porous Aromatic Framework" Catalysts 13, no. 9: 1309. https://doi.org/10.3390/catal13091309