Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Materials
3.2. Synthesis and Characterization
3.3. Conversion of Fructose
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | SBET a (m2·g−1) | Crystallite Size (nm) b | Amount Bronsted c (mmol·g−1) | Amount Lewis c (mmol·g−1) | AB/AL d |
---|---|---|---|---|---|
Ce100 | 70.6 | 10.1 | 157.5 | 120.0 | 1.3 |
Mo100 | >5.0 | 133.6 | 700.0 | 531.8 | 1.3 |
CeMo | >5.0 | 40.5 | 490.7 | 291.1 | 1.7 |
Range T (°C) | Ce100 | Mo100 | CeMo |
---|---|---|---|
100–150 | 2.3 | nd | nd |
700–850 | 2.7 | 78.2 | nd |
850–1000 | nd | 17.5 | nd |
>1000 | 2.4 | nd | 19.0 |
Code | Description |
---|---|
Ce100 | Cerium oxide(IV) (CeO2) |
Mo100 | Molybdenum oxide(VI) (MoO3) |
CeMo | Cerium molybdate (Ce2(MoO4)3) |
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Pryston, D.B.d.A.; Martins, T.V.d.S.; Vasconcelos Júnior, J.A.d.; Avelino, D.O.d.S.; Meneghetti, M.R.; Meneghetti, S.M.P. Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion. Catalysts 2023, 13, 4. https://doi.org/10.3390/catal13010004
Pryston DBdA, Martins TVdS, Vasconcelos Júnior JAd, Avelino DOdS, Meneghetti MR, Meneghetti SMP. Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion. Catalysts. 2023; 13(1):4. https://doi.org/10.3390/catal13010004
Chicago/Turabian StylePryston, Dhara Beatriz de Amorim, Thatiane Veríssimo dos Santos Martins, Jailton Alves de Vasconcelos Júnior, Débora Olimpio da Silva Avelino, Mario Roberto Meneghetti, and Simoni Margareti Plentz Meneghetti. 2023. "Investigation of CeO2, MoO3, and Ce2(MoO4)3, Synthesized by the Pechini Method, as Catalysts for Fructose Conversion" Catalysts 13, no. 1: 4. https://doi.org/10.3390/catal13010004