Eco-Friendly and Solvent-Less Mechanochemical Synthesis of ZrO2–MnCO3/N-Doped Graphene Nanocomposites: A Highly Efficacious Catalyst for Base-Free Aerobic Oxidation of Various Types of Alcohols
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations
2.2. Catalytic Activities
2.2.1. Impact of wt.% of NDG
2.2.2. Effects of Various Graphene Derivatives
2.2.3. Impact of Operating Temperature
2.2.4. Impact of Catalyst Dose
2.3. Reusability Tests
3. Experimental Section
3.1. Preparation of GRO and NDG
3.2. Preparation of (X%)NDG Doped MnCO3–(1%)ZrO2 Nanocomposites
3.3. Characterizations
3.4. Catalytic Investigations
3.5. Recovery Tests
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Entry | Catalyst | S. A. (m2/g) | Con. (%) | Specific Activity (mmol·g−1·h−1) | Sel. (%) |
---|---|---|---|---|---|
1 | NDG | 485.6 | 2.7 | 1.8 | >99 |
2 | MnCO3 | 70.5 | 41.6 | 27.7 | >99 |
3 | MnCO3–(1%)ZrO2 | 133.6 | 73.1 | 48.8 | >99 |
4 | (1%)NDG/MnCO3–(1%)ZrO2 | 243.7 | 100.0 | 66.7 | >99 |
5 | (1%)GRO/MnCO3–(1%)ZrO2 | 229.5 | 96.8 | 64.6 | >99 |
6 | (1%)HRG/MnCO3–(1%)ZrO2 | 211.0 | 89.3 | 59.6 | >99 |
Entry | Catalyst | Conv. (%) | Specific Activity (mmol·g−1·h−1) | Sel. (%) |
---|---|---|---|---|
1 | NDG | 2.7 | 1.8 | >99 |
2 | MnCO3–(1%)ZrO2 | 73.1 | 48.8 | >99 |
3 | (1%)NDG/MnCO3–(1%)ZrO2 | 100.0 | 66.7 | >99 |
4 | (3%)NDG/MnCO3–(1%)ZrO2 | 95.1 | 63.4 | >99 |
5 | (5%)NDG/MnCO3–(1%)ZrO2 | 84.8 | 56.6 | >99 |
6 | (7%)NDG/MnCO3–(1%)ZrO2 | 65.6 | 43.8 | >99 |
Catalyst | T. (°C) | Time (h) | Conv. (%) | Sel. (%) | Specific Activity (mmol·g−1·h−1) | Ref. |
---|---|---|---|---|---|---|
(1%)NDG/MnCO3–(1%)ZrO2 | 100 | 0.1 | 100 | >99 | 66.7 | Herein |
(1%)GRO/MnCO3–(1%)ZrO2 | 100 | 0.1 | 100 | >99 | 64.6 | [20] |
(1%)HRG/MnCO3–(1%)ZrO2 | 100 | 0.1 | 100 | >99 | 59.6 | [14] |
4%Ru (CO)/NDG | 90 | 24 | 46 | >99 | 6.4 | [38] |
MCG-700 | 100 | 8 | 89.5 | 97.3 | 4.5 | [43] |
Au–Pd/Fe–Gr | 110 | 4 | 89.1 | 87.5 | 6.7 | [42] |
Au NPs/NG | 70 | 6 | 67 | 40 | 0.4 | [44] |
MnO2/GRO | 110 | 3 | 97 | 100 | 1.6 | [45] |
Sn–W/RGO | 80 | 3 | 94.0 | 94.4 | 15.7 | [46] |
Ag NPs/GOSH | 80 | 24 | 61 | 58 | 5.1 | [47] |
Cu NPs@rGO | 80 | 16 | <99 | 98.6 | 8.3 | [48] |
Pd NPs/GRO | 110 | 6 | 36 | 34.1 | 1.0 | [49] |
1 wt.% RGO/MnCoO | 140 | 2 | 78 | 100 | 12.6 | [50] |
Au NPs/RGO | 100 | 8 | 65 | 93 | 5.4 | [41] |
GRO/Fe3O4/HPW | 70 | 3 | 99 | 100 | 16.7 | [51] |
GO-100 | 80 | 5 | 100 | 100 | 1.1 | [52] |
S. No. | Reactant | Product | Time (min) | Conv. (%) | Sel. (%) |
---|---|---|---|---|---|
1 | 6 | 100 | >99.9 | ||
2 | 7 | 100 | >99.9 | ||
3 | 6 | 100 | >99.9 | ||
4 | 8 | 100 | >99.9 | ||
5 | 10 | 100 | >99.9 | ||
6 | 9 | 100 | >99.9 | ||
7 | 11 | 100 | >99.9 | ||
8 | 10 | 100 | >99.9 | ||
9 | 11 | 100 | >99.9 | ||
10 | 12 | 100 | >99.9 | ||
11 | 14 | 100 | >99.9 | ||
12 | 14 | 100 | >99.9 | ||
13 | 17 | 100 | >99.9 | ||
14 | 15 | 100 | >99.9 | ||
15 | 20 | 100 | >99.9 | ||
16 | 17 | 100 | >99.9 | ||
17 | 18 | 100 | >99.9 | ||
18 | 24 | 100 | >99.9 | ||
19 | 12 | 100 | >99.9 | ||
20 | 25 | 100 | >99.9 | ||
21 | 8 | 100 | >99.9 | ||
22 | 10 | 100 | >99.9 | ||
23 | 10 | 100 | >99.9 | ||
24 | 15 | 100 | >99.9 | ||
25 | 14 | 100 | >99.9 | ||
26 | 18 | 100 | >99.9 | ||
27 | 30 | 100 | >99.9 | ||
28 | 100 | 100 | >99.9 | ||
29 | 110 | 100 | >99.9 | ||
30 | 130 | 100 | >99.9 | ||
31 | 40 | 100 | >99.9 | ||
32 | 120 | 100 | >99.9 |
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Kuniyil, M.; Kumar, J.V.S.; Adil, S.F.; Assal, M.E.; Shaik, M.R.; Khan, M.; Al-Warthan, A.; Siddiqui, M.R.H.; Khan, A.; Bilal, M.; et al. Eco-Friendly and Solvent-Less Mechanochemical Synthesis of ZrO2–MnCO3/N-Doped Graphene Nanocomposites: A Highly Efficacious Catalyst for Base-Free Aerobic Oxidation of Various Types of Alcohols. Catalysts 2020, 10, 1136. https://doi.org/10.3390/catal10101136
Kuniyil M, Kumar JVS, Adil SF, Assal ME, Shaik MR, Khan M, Al-Warthan A, Siddiqui MRH, Khan A, Bilal M, et al. Eco-Friendly and Solvent-Less Mechanochemical Synthesis of ZrO2–MnCO3/N-Doped Graphene Nanocomposites: A Highly Efficacious Catalyst for Base-Free Aerobic Oxidation of Various Types of Alcohols. Catalysts. 2020; 10(10):1136. https://doi.org/10.3390/catal10101136
Chicago/Turabian StyleKuniyil, Mufsir, J. V. Shanmukha Kumar, Syed Farooq Adil, Mohamed E. Assal, Mohammed Rafi Shaik, Mujeeb Khan, Abdulrahman Al-Warthan, Mohammed Rafiq H. Siddiqui, Aslam Khan, Muhammad Bilal, and et al. 2020. "Eco-Friendly and Solvent-Less Mechanochemical Synthesis of ZrO2–MnCO3/N-Doped Graphene Nanocomposites: A Highly Efficacious Catalyst for Base-Free Aerobic Oxidation of Various Types of Alcohols" Catalysts 10, no. 10: 1136. https://doi.org/10.3390/catal10101136