2. Calculations and Results
A complete theory of the scattering and absorption of electromagnetic radiation by a homogeneous sphere was developed by Gustav Mie [
38]. The Mie theory is an exact solution to the Maxwell Equations (1)–(4), in SI units, for the macroscopic electromagnetic field at interior points in matter and is valid for spherical particles of any size embedded in a homogeneous medium [
39,
40,
41,
42,
43],
where
E is the electric field,
B the magnetic induction, ρ
F the charge density,
JF the current density,
D the electric displacement, and
H the magnetic field defined, respectively, as
where
P is the electric polarization (average electric dipole moment per unit volume),
M the magnetization (average magnetic dipole moment per unit volume), ε
0 the permittivity, and μ
0 the permeability of the free space. Equations (1)–(6) are not sufficient in themselves; they must be supplemented with constitutive relations which are assumed to have the form
JF = σ
E,
B = μ
H,
P = ε
0χ
E with σ the conductivity, μ the permeability, and χ the electric susceptibility.
The Mie’s approach is based on the expansion of the internal and scattered fields into a set of normal modes described by vector harmonics [
39,
40,
41,
42,
43]. The quasi-static results valid for subwavelength spheres are then recovered by a power series expansion of the absorption and scattering coefficients and taking into in account only the first term. Therefore, the Mie’s theory is applicable only to spherical particles (spherical symmetry). The Mie’s theory was generalized to analytically investigate the electromagnetic radiation scattering and absorption properties by multi-layered spherical particles [
42,
43] which is the case of the interaction of spherical core–shell nanoparticles with the electromagnetic radiation.
The main parameter to characterize the scattering process of the electromagnetic radiation from a particle is the scattering cross section σ, defined as the ratio between the total radiation scattered power to the radiation intensity, σ = W/I0 being I0 (energy/(area)(time)) the intensity of a plane electromagnetic wave impinging on the spherical particle and W (energy/time) the total (i.e., integrated over all directions) power of the wave scattered by the particle. Usually, what is experimentally measured is the scattering efficiency defined as Qscatt = σ/πR2 being the scattering cross section σ normalized to the geometrical section πR2 (area of a circle of radius R) of the spherical particle of radius R. Exploiting the definition of Qscatt, a dimensionless parameter, the electromagnetic radiation scattering properties of spherical particles with different sizes can be directly compared. Qscatt can exceed 1 for a particle since in addition to scattering radiation incident on its geometrical cross section, the particle also diffracts radiation at its edges, so that it can behave as a larger particle than its geometrical cross section. In order to calculate σ for a homogeneous spherical particle, the Maxwell’s equations can be analytically solved considering a plane wave incident on the particle. Then, Qscatt can be calculated. Similarly, the Maxwell’s equations can be solved considering a layered spherical particle on which a plan electromagnetic wave is incident: if the particle is formed by N layers (from 1, the core, to N, the outmost shell), with each layer having radius Ri (R1 the radius of the core, RN the thickness of the outmost shell) and refractive index ni (n1 the refractive index of the core, nN the refractive index of the outmost shell, nb the refractive index of a matrix embedding the layered particle, n the refractive index of the medium that the wave is traveling), then the incident, scattered, and internal fields can be expanded as a superposition of vector spherical harmonics (thanks to the spherical symmetry).
This approach is exploited by algorithms used in various software to carry out the calculations [
44] as, for example, Pyscatmech, Lorentz-Mie Scattering, Pyshs, Stratify, Miepython, Pymiescatt, Menp, and ScatLab. In the present work the Scatlab 1.2.111 software [
45] is used to calculate the angle-dependent intensities (I(θ)) and the scattering efficiency (Q
scatt) for the spherical core–shell particles Ag/AZO, Au/AZO, Ag/ITO, Au/ITO, Ag/PEDOT:PSS, and Au/PEDOT:PSS by changing the size of the core and of the shell and by fixing the wavelength of the incident electromagnetic wave to λ = 550 nm (the center of the visible spectrum, in view of visible light induced phenomena and visible light-based applications). ScatLab is a software developed to perform electromagnetic scattering simulations based on classical Mie theory solution. It is designed to meet windows type guidelines. The computation capabilities of Scatlab are based on the possibility to calculate scattered intensity polar diagrams for coated and uncoated spherical particles, scattered intensity versus radius graphs for homogeneous spherical particles, polarization rate versus radius graph for homogeneous spherical particles, extinction, scattering and backscattering cross section graphs, polarization rate versus damping rate graph, angle depolarization graphs, near field imaging for homogeneous spherical particles, near field average scattered intensity versus radius graphs for homogeneous spherical particles, Lorentz and Drude dielectric function implementation for refractive index calculation, and more other. As generally described above, the Scalab software is one type of calculator (based on the Mie theory), which consider an incident plane wave as represented by an infinite combination of spherical harmonics. Their amplitudes depend on the polarization and the direction of the incident wave and are given in general case by analytical formulae. The advantage of such representation is in that each such harmonics is scattered as a single spherical outgoing harmonics which amplitude depends on the particle radius and refractive indices and is prescribed by coefficient given by an analytical expression. Since each scattered harmonics propagates independently, the total scattered power is found as the sum of particular powers in all scattered harmonics. In addition, the solutions of the calculations are dependent on the specific boundary conditions under which the program operates. Generally, the following conditions are imposed: (a) interface conditions on the boundary between the spherical particle and the environment (which allow to relate the expansion coefficients of the incident, internal, and scattered fields); (b) the condition that the solution is bounded at the origin; (c) for a scattered field, the asymptotics at infinity corresponds to a diverging spherical wave. Values commonly calculated by software using Mie theory, as Scatlab, include efficiency coefficients for extinction, scattering, and absorption. The solutions solve for an infinite harmonic series, and provide as output the calculation of the scattering phase function, extinction, scattering, and absorption efficiencies. These efficiency coefficients are ratios of the cross-section of the respective process to the particle area. The dependence of the scattering cross-section on the wavelength and the contribution of specific resonances strongly depends on the particle material. For example, for a Au particle with a radius of 100 nm, the contribution of the electric dipole to scattering predominates in the optical range, while for a Si particle there are pronounced magnetic dipole and quadrupole resonances. For metal particles, the peak visible in the scattering cross-section is the localized plasmon resonance. In the limit of small particles or long wavelengths, the electric dipole contribution dominates in the scattering cross-section. Hence, the selection of the values for the real part and imaginary part of the refractive index of the material composing the particle for each analyzed wavelength is important to obtain reliable results. However, overall, the Scatlab software was widely used the calculate the optical properties of several typologies of spherical single-component or multilayered particles with excellent results since in agreement with the experimental results within the range for which the Mie theory holds and for which the experimental conditions adhere to the validity hypothesis for the theory [
43,
46,
47,
48,
49].
In particular, we exploit the Scatlab capabilities to calculate the light scattering properties of the for the spherical bimetallic core–shell nanoparticles made by Ag/AZO, Au/AZO, Ag/ITO, Au/ITO, Ag/PEDOT:PSS, and Au/PEDOT:PSS for various combinations of the core radius and shell width: hence, within the capabilities and limits of the Scatlab software, the additional scientific inside of the present work relies in the application of a freely available software to functional nanomaterials with potential interesting applications and in the setting of a general framework connecting the nanoparticles geometry to their light scattering characteristics. Therefore, our work is in the line with the computational design of the best geometries for the core–shell nanoparticles for improving the performance of solar cells devices where Ag or Au particles, in combination with TCOs, are used to enhance the light scattering efficiency.
In order to perform the calculations, the Scatlab software requires, as input parameters, values for the real part, n, and imaginary part, k, of the refractive index of the materials composing the particle and of the matrix where the particle is embedded (and corresponding to the chosen wavelength of the incident electromagnetic radiation), and values for the particle core radius R and particle shell width d. Regarding the metals here investigated, the values for n and k used for the calculations are reported in
Table 1 (for λ = 550 nm) as extracted by ref. [
50]. The core–shell particles are supposed to be placed in air so that n = 1 and k = 0 for the matrix embedding the particles.
The ScatLab software is, now, used to perform electromagnetic scattering simulations for the spherical bimetallic core–shell nanoparticles: in particular, an electromagnetic plan wave of wavelength λ = 550 nm is supposed to impinge from 0° on the single NP which is located in the origin of a reference system. Then, the ScatLab software is used to calculate the angular-dependent intensity I(θ) of the scattered electromagnetic wave and the scattering efficiency Q
scatt. This is done for the spherical core–shell nanoparticles made by Ag/AZO, Au/AZO, Ag/ITO, Au/ITO, Ag/PEDOT:PSS, and Au/PEDOT:PSS for various combinations of the core radius R (30, 50, 70 nm) and shell width d (10, 30, 50 nm). The other input parameters are the values of n and k, as reported in Tab. 1. In each case, the results for the calculations of I(θ) are reported in polar diagrams and the results for the calculations of Q
scatt are reported in plots expressing the evolution of Q
scatt for each couple of metals when fixed R and increasing d. The results are reported in
Figure 1,
Figure 2,
Figure 3,
Figure 4,
Figure 5,
Figure 6,
Figure 7,
Figure 8,
Figure 9 and
Figure 10. In particular:
(1) Pure Ag and Au Particles
Figure 1 reports the scheme of the structure of the simulated Ag (
Figure 1a) and Au (
Figure 1b) pure spherical particle with radius R and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 1c–e the calculated polar diagrams for the intensity of the scattered light from the Ag spherical particle changing the radius R from 30 nm to 70 nm; in
Figure 1f–h the calculated polar diagrams for the intensity of the scattered light from the Au spherical particle changing the radius R from 30 nm to 70 nm; and in
Figure 1i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag (black dots) and Au (red dots) spherical particle increasing the particle radius from 30 nm to 70 nm.
For both Ag and Au particles, the scattering intensity at 180° increases, with respect to the scattering intensity at 0° (backscattered light), by increasing the radius of the particle (
Figure 1c–h) and that the scattering efficiency is higher for the Ag particles than the Au particles in all the investigated size range (
Figure 1i), whereas the scattering efficiency linearly increases with size. The increase of the scattering efficiency by increasing the size of a spherical particle is an obvious consequence of the Mie theory for which the dipole model can be used to approximate the scattering cross-sections of a particle with a diameter much smaller than the wavelength, λ, of the incident light: C
scatt = (1/6π)(2π/λ)
4|α|
2 with α the polarizability and for a spherical particle α = 3V(ε
p−ε
m/ε
p+2ε
m) and being V the volume of the particle, ε
p and ε
m the dielectric functions of the particle and of the surrounding environment, respectively. Hence, larger particles are predominantly scattering.
(2) Ag/AZO and Au/AZO:
(a) R = 30 nm:
Figure 2a,b reports the scheme of the structure of the simulated Ag/AZO (
Figure 2a) and Au/AZO (
Figure 2b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 2c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/AZO core–shell spherical particle fixing the Ag core radius R to 30 nm and increasing the AZO shell width from 10 nm to 50 nm are reported; in
Figure 2f–h the calculated polar diagrams for the intensity of the scattered light from the Au/AZO core–shell spherical particle fixing the Au core radius R to 30 nm and increasing the AZO shell width from 10 nm to 50 nm are presented; in
Figure 2i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/AZO (black dots) and Au/AZO (red dots) core–shell spherical particles fixing the core radius to R = 30 nm and increasing the AZO shell width d from 10 nm to 50 nm is shown.
Fixing R = 30 nm and d = 10 nm (
Figure 2c), we can see that the Ag/AZO system scatters light with higher intensity at 180° than at 0° and that the light scattering is, practically, confined between 210° and 150°. Correspondently, instead, the intensity of the light scattered by the Au/AZO system (
Figure 2f) is zero at 0° and maximum at 180°; however, the scattered light is confined between 270° and 90°.
For R = 30 nm and d = 30 nm and R = 30 nm and d = 50 nm, the behavior of the Ag/AZO and Au/AZO systems is similar (
Figure 2d,e,g,h), with the maximum of the intensity of the scattered light at 180°. However, in each condition, the Ag/AZO system if more efficient in scattering light at 180° than at 0°. Moreover, in any condition the scattering efficiency of the Ag/AZO system is higher than the scattering efficiency of the Au/AZO one (
Figure 2i). However, the scattering efficiency of the Au/AZO system increases by increasing the particle size, while the scattering efficiency of the Ag/AZO system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm).
(b) R = 50 nm:
Figure 3a,b reports the scheme of the structure of the simulated Ag/AZO (
Figure 3a) and Au/AZO (
Figure 3b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 3c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/AZO core–shell spherical particle fixing the Ag core radius R to 50 nm and increasing the AZO shell width from 10 nm to 50 nm are reported; in
Figure 3f–h the calculated polar diagrams for the intensity of the scattered light from the Au/AZO core–shell spherical particle fixing the Au core radius R to 50 nm and increasing the AZO shell width from 10 nm to 50 nm are presented; in
Figure 3i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/AZO (black dots) and Au/AZO (red dots) core–shell spherical particles fixing the core radius to R = 50 nm and increasing the AZO shell width d from 10 nm to 50 nm is shown.
In this case, the polar diagrams show similar shape for the intensity of the scattered light from the Ag/AZO and Au/AZO systems apart for the condition R = 50 nm and d = 30 nm. In this last condition (
Figure 3d,g), the intensity of light scattered by the Ag/AZO system (
Figure 3d) is zero at 0° and maximum at 180°. In the same situation, the Au/AZO system (
Figure 3g) scatters light with the best efficiency at 80°; however, the intensity is not zero at 0° and the minimum intensity for the scattered light is obtained between 60° and 90° and between 270° and 300°. Moreover, in any condition, the scattering efficiency of the Ag/AZO system is higher than the scattering efficiency of the Au/AZO one (
Figure 3i). However, the scattering efficiency of the Ag/AZO system increases by increasing the particle size, while the scattering efficiency of the Au/AZO system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm).
(c) R = 70 nm:
Figure 4a, b reports the scheme of the structure of the simulated Ag/AZO (
Figure 4a) and Au/AZO (
Figure 4b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 4c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/AZO core–shell spherical particle fixing the Ag core radius R to 70 nm and increasing the AZO shell width from 10 nm to 50 nm are reported; in
Figure 4f–h the calculated polar diagrams for the intensity of the scattered light from the Au/AZO core–shell spherical particle fixing the Au core radius R to 70 nm and increasing the AZO shell width from 10 nm to 50 nm are presented; in
Figure 4i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/AZO (black dots) and Au/AZO (red dots) core–shell spherical particles fixing the core radius to R = 70 nm and increasing the AZO shell width d from 10 nm to 50 nm is shown.
In this case, the polar diagrams show similar shape for the intensity of the scattered light from the Ag/AZO and Au/AZO systems. However, a very different result is obtained in the condition R = 70 nm and d = 50 nm (
Figure 4e,h) with respect to the other conditions (R = 70 nm and d = 10 nm,
Figure 4c,f, and R = 70 nm and d = 30 nm,
Figure 4d,g). In fact, for R = 70 nm and d = 10 nm (
Figure 4c,f), R = 70 nm and d = 30 nm (
Figure 4d,g), both the Ag/AZO and Au/AZO systems scatter light more efficiently at 180° than at 0°. This is particularly true in the case R = 70 nm and d = 30 nm (
Figure 4d,g) for which the intensity of the scattered light is about zero at 0° and maximum at 180°. The opposite situation is, instead, established for R = 70 nm and d = 50 nm (
Figure 4e,h): both systems scatter light with the maximum intensity at 0° (backscattering). The intensity of the scattered light is about zero at 180° for the Au/AZO system and, even if not exactly zero, very low for the Ag/AZO system. In addition, in this case, the Ag/AZO system has the higher overall scattering efficiency in all the investigated size range (
Figure 4i). Moreover, the scattering efficiency of the Ag/AZO system increases by increasing the particle size, while the scattering efficiency of the Au/AZO system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm).2.3. Ag/ITO and Au/ITO
(3) Ag/ITO and Au/ITO:
(a) R = 30 nm:
Figure 5a, b reports the scheme of the structure of the simulated Ag/ITO (
Figure 5a) and Au/ITO (
Figure 5b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 5c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/ITO core–shell spherical particle fixing the Ag core radius R to 30 nm and increasing the ITO shell width from 10 nm to 50 nm are reported; in
Figure 5 f–h the calculated polar diagrams for the intensity of the scattered light from the Au/ITO core–shell spherical particle fixing the Au core radius R to 30 nm and increasing the ITO shell width from 10 nm to 50 nm are presented; in
Figure 5i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/ITO (black dots) and Au/ITO (red dots) core–shell spherical particles fixing the core radius to R = 30 nm and increasing the ITO shell width d from 10 nm to 50 nm is shown.
In this case, the polar diagrams show similar shape for the intensity of the scattered light from the Ag/ITO and Au/ITO systems in all sizes conditions. It is interesting to note that the polar diagrams are practically identical for R = 30 nm and d = 10 nm (
Figure 5c,f) and that, in this condition, the intensity of the scattered light is about zero at 0° and maximum at 180°. In the conditions R = 30 nm and d = 30 nm (
Figure 5d,g), R = 30 nm and d = 50 nm (
Figure 5e,h), both systems scatter light in any direction, however with maximum intensity at 180° and, in general, the Ag/ITO system with higher intensity at 180° with respect to 0°. In all these cases, however, the minimum intensity for the scattered light is obtained at 90° and 270°. For both systems the scattering efficiency (
Figure 5i) increases by increasing the shell size and, in any condition, it is higher for the Ag/ITO system.
(b) R = 50 nm:
Figure 6a, b reports the scheme of the structure of the simulated Ag/ITO (
Figure 6a) and Au/ITO (
Figure 6b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 6c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/ITO core–shell spherical particle fixing the Ag core radius R to 50 nm and increasing the ITO shell width from 10 nm to 50 nm are reported; in
Figure 6f–h the calculated polar diagrams for the intensity of the scattered light from the Au/ITO core–shell spherical particle fixing the Au core radius R to 50 nm and increasing the ITO shell width from 10 nm to 50 nm are presented; in
Figure 6i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/ITO (black dots) and Au/ITO (red dots) core–shell spherical particles fixing the core radius to R = 50 nm and increasing the ITO shell width d from 10 nm to 50 nm is shown.
In addition, in this case, the polar diagrams show similar shape for the intensity of the scattered light from the Ag/ITO and Au/ITO systems in all sizes conditions, indicating a better efficiency of the Ag/ITO system in scattering light at 180° than at 0°. For example, for R = 50 nm and d = 30 nm (
Figure 6d,g), the intensity of the light scattered at 0° by the Ag/ITO system is zero while it is not zero for the Au/ITO system. Concerning the overall scattering efficiency (
Figure 6i), the scattering efficiency of the Ag/ITO system increases by increasing the particle size, while the scattering efficiency of the Au/ITO system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm).
(c) R = 70 nm:
Figure 7a, b reports the scheme of the structure of the simulated Ag/ITO (
Figure 7a) and Au/ITO (
Figure 7b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 7c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/ITO core–shell spherical particle fixing the Ag core radius R to 70 nm and increasing the ITO shell width from 10 nm to 50 nm are reported; in
Figure 7f–h the calculated polar diagrams for the intensity of the scattered light from the Au/ITO core–shell spherical particle fixing the Au core radius R to 70 nm and increasing the ITO shell width from 10 nm to 50 nm are presented; in
Figure 7i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/ITO (black dots) and Au/ITO (red dots) core–shell spherical particles fixing the core radius to R = 70 nm and increasing the ITO shell width d from 10 nm to 50 nm is shown.
In this case, for R = 70 nm and d = 10 nm (
Figure 7c,f), the behavior of the Ag/ITO and Au/ITO particles is similar in scattering light, even if the Ag/ITO one more efficient in scattering light at 180° than at 0°. In addition, for R = 70 nm and d = 30 nm (
Figure 7d,g) the behavior is similar; however, in this case, the intensity of the scattered light by the Ag/ITO particle at 0° is zero and maximum at 180° while the intensity of the scattered light by the Au/ITO particle is not zero at 0°, however low, and maximum at 180°. For R = 70 nm and d = 50 nm (
Figure 7e,h), the intensity of the scattered light by the Au/ITO particle is about zero at 180° and maximum at 0°, for the Ag/ITO particle it is maximum at 0° and significant also at 180°, and minimum at 90° and 270°. Finally, the scattering efficiency of the Ag/ITO system increases (almost linearly) by increasing the particle size, while the scattering efficiency of the Au/ITO system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm). However, the Ag/ITO systems present a scattering efficiency higher in any size condition.
(4) Ag/PEDOT:PSS and Au/PEDOT:PSS:
(a) R = 30 nm:
Figure 8a, b the scheme of the structure of the simulated Ag/PEDOT:PSS (
Figure 8a) and Au/PEDOT:PSS (
Figure 8b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 8c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/PEDOT:PSS core–shell spherical particle fixing the Ag core radius R to 30 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are reported; in
Figure 8f–h the calculated polar diagrams for the intensity of the scattered light from the Au/PEDOT:PSS core–shell spherical particle fixing the Au core radius R to 30 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are presented; in
Figure 8i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/PEDOT:PSS (black dots) and Au/PEDOT:PSS (red dots) core–shell spherical particles fixing the core radius to R = 30 nm and increasing the PEDOT:PSS shell width d from 10 nm to 50 nm is shown.
In this case, it is interesting to note that for R = 30 nm and d = 10 nm (
Figure 8c,f), both Ag/PEDOT:PSS and Au/PEDOT:PSS systems allow to obtain the maximum of the intensity for scattered light at 180° and the minimum at 0°; however, in this case, the Au/PEDOT:PSS system is more efficient I scattering light at 180° with respect to 0°. For R = 30 nm and d = 30 nm (
Figure 8d,g), R = 30 nm and d = 50 nm (
Figure 8e,h), the two systems scatter light similarly; however, the Ag/PEDOT:PSS system has better efficiency than the Au/PEDOT:PSS system at 180° than at 0°. The overall scattering efficiency (
Figure 8i) increases, almost linearly, for both systems, in all the investigated size range and, in any condition, the scattering efficiency for the Ag/PEDOT:PSS systems is higher.
(b) R = 50 nm:
Figure 9a,b reports the scheme of the structure of the simulated Ag/PEDOT:PSS (
Figure 9a) and Au/PEDOT:PSS (
Figure 9b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 9c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/PEDOT:PSS core–shell spherical particle fixing the Ag core radius R to 50 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are reported; in
Figure 9f–h the calculated polar diagrams for the intensity of the scattered light from the Au/PEDOT:PSS core–shell spherical particle fixing the Au core radius R to 50 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are presented; in
Figure 9i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/PEDOT:PSS (black dots) and Au/PEDOT:PSS (red dots) core–shell spherical particles fixing the core radius to R = 50 nm and increasing the PEDOT:PSS shell width d from 10 nm to 50 nm is shown.
In particular, for R = 50 nm and d = 10 nm (
Figure 9c,f), R = 50 nm and d = 50 nm (
Figure 9e,h), the polar diagrams show a similar behavior for the intensity of the light scattered by the Ag/PEDOT:PSS and Au/PEDOT:PSS particles, with the maximum intensity at 180°, the minimum at 90° and 270° and a low (even if not minimum) at 0°. More peculiar is the behavior for R = 50 nm and d = 30 nm (
Figure 9d,g): in this case, the Ag/PEDOT:PSS system presents the maximum for the intensity of the scattered light at 180°, the minimum at 90° and 270° and a significant intensity at 0°; on the other hand, the Au/PEDOT:PSS system presents the maximum of the intensity of the scattered light at 0° (backscattered light) and the minimum at 180°. The overall scattering efficiency (
Figure 9i) is about constant for the Ag/PEDOT:PSS particle for d from 10 nm to 30 nm then increases for d from 30 nm to 50 nm. Instead, it increases from d = 10 nm to d = 50 nm for the Au/PEDOT:PSS system. In any case, the scattering efficiency of the Ag/PEDOT:PSS particle is higher.
(c) R = 70 nm:
Figure 10a, b reports the scheme of the structure of the simulated Ag/PEDOT:PSS (
Figure 10a) and Au/PEDOT:PSS (
Figure 10b) core–shell spherical particle with core radius R and shell width d and electromagnetic radiation of wavelength λ = 550 nm impinging on the particle from 0°; in
Figure 10c–e the calculated polar diagrams for the intensity of the scattered light from the Ag/PEDOT:PSS core–shell spherical particle fixing the Ag core radius R to 70 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are reported; in
Figure 10f–h the calculated polar diagrams for the intensity of the scattered light from the Au/PEDOT:PSS core–shell spherical particle fixing the Au core radius R to 70 nm and increasing the PEDOT:PSS shell width from 10 nm to 50 nm are presented; in
Figure 10i the calculated scattering efficiency for the light (wavelength λ = 550 nm) scattering process of the Ag/PEDOT:PSS (black dots) and Au/PEDOT:PSS (red dots) core–shell spherical particles fixing the core radius to R = 70 nm and increasing the PEDOT:PSS shell width d from 10 nm to 50 nm is shown. In this case, the polar diagrams shows similar results for the intensity of the light scattered by the Ag/PEDOT:PSS and Au/PEDOT:PSS particles in all the size conditions. In particular: for R = 70 nm and d = 10 nm (
Figure 10c,f), both systems show the maximum intensity for the scattered light at 180°, the minimum at 90° and 270° and a significant intensity at 0°. However, the Ag/PEDOT:PSS system a more efficient in scattering light at 180° than at 0°. For R = 70 nm and d = 30 nm (
Figure 10d,g), the intensity of the scattered light at 0° is almost zero and maximum at 180°. For R = 70 nm and d = 50 nm (
Figure 10e,h), both systems show the maximum for the intensity of the scattered light at 0°, the minimum at 90° and 270° and a high intensity (even if not maximum) at 0°. Finally, the scattering efficiency of the Ag/PEDOT:PSS system increases by increasing the particle size, while the scattering efficiency of the Au/PEDOT:PSS system firstly decreases (d from 10 to 30 nm) then increases (d from 30 to 50 nm). However, the Ag/PEDOT:PSS systems present a scattering efficiency higher in any size condition.
Finally, the Mie’s theory, on which the present Scatlab calculations are based, is applicable only to spherical particles (spherical symmetry). Hence, the results of the present calculations are limited to such a situation; however, they could be a starting point to analyze the scattering properties of non-spherical particles. It can be observed that many natural and artificial small particles have nonspherical overall shapes or lack a spherically symmetric internal structure. It is now well recognized that the scattering properties of nonspherical particles can differ dramatically from those of “equivalent” Mie spheres. Therefore, the ability to accurately compute or measure light scattering by nonspherical particles in order to clearly understand the effects of particle nonsphericity on scattering patterns is very important [
51]. In this regard, several techniques were developed for computing electromagnetic scattering by nonspherical particles based on numerically solving Maxwell’s equations [
51,
52]. The main classes of techniques can be, roughly, classified in: (a) the separation of variables method, (b) the discrete dipole approximation (a specific approach in a more general class called the volume-integral equation method), (c) the T-matrix approach, d) the Finite Difference Time Domain method. The basic idea of the separation of variables method is to make a separation ansatz for the solution to the scalar Helmholtz equation and to obtain a set of differential equations for each component function from the scalar Helmholtz equation. From the set of solution functions to these differential equations one can construct solenoidal vector wave functions that solve the vector Helmholtz equation [
52]. The incident, scattered, and internal fields are expanded in suitable vector wave functions, and the expansion coefficients are determined by enforcing the boundary conditions on the particle surface. An important advantage of this method is its high numerical accuracy, making it a method suitable for benchmark computations [
52]. A disadvantage of this approach is that for large size parameters of the spheroid and/or large refractive indices the system of linear equations to be solved becomes large, and ill-conditioning problems may occur. In the discrete dipole approximation, the effect of the exciting field is interpreted as inducing a dipole moment in each discrete volume cell [
52]. This formalism leads to a system of linear equations that can be inverted numerically by standard techniques, such as Gaussian elimination or the conjugate gradient method. The computational complexity of the discrete dipole approximation depends on the method employed for solving the system of linear equations, and on suitable methods for reducing the large number of operations involved in calculating the matrix–vector products [
52]. An important issue for this approach is how relate the relative permittivity to the polarizability in each cell. The T-matrix approach is based on the traditional description of the scattering problem, i.e., the computation of the scattered field for a given incident field. This procedure needs to be repeated for each new angle of incidence or each new form of the incident field. However, by contrast, the T-matrix approach offers a significantly more concise description of a particle’s scattering and absorption properties [
52]. The objective in the development of the nullified method was to derive an approach suitable for numerically computing the scattered field in the exterior domain. The T-matrix is a quantity that contains (in approximate form) the full information about a particle’s optical properties at a given wavelength. It depends only on the particle’s size parameter, its shape, its refractive index, and on the particle’s orientation with respect to the coordinate system. The T matrix is independent of the incident field. The Finite Difference Time Domain method is the most direct method to solve Maxwell’s curl equations in differential form [
52]. In this method both time and space are discretized, i.e., all spatial and temporal derivatives in Maxwell’s curl equations are replaced by finite difference quotients. Thus, the essence of this algorithm is to numerically solve an initial-value problem by marching a plane wave or pulse source, which is switched on at some initial time, through discrete time steps over a 5nite discretized spatial domain that includes the particle [
52]. The main practical issue of this approach is the method of spatial discretization.