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Article

Combustion, Emission, and Knock Characteristics in a Hydrogen-Doped Premixed Ammonia Spark-Ignition Heavy-Duty Engine

College of Power and Energy Engineering, Harbin Engineering University, Harbin 150001, China
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Author to whom correspondence should be addressed.
Sustainability 2026, 18(1), 42; https://doi.org/10.3390/su18010042
Submission received: 17 November 2025 / Revised: 11 December 2025 / Accepted: 16 December 2025 / Published: 19 December 2025
(This article belongs to the Special Issue Green Shipping and Operational Strategies of Clean Energy)

Abstract

As sustainable green fuels for heavy-duty engines, using hydrogen doping with ammonia helps to mitigate greenhouse gas emissions. Based on the background of hydrogen production from ammonia reforming, the combustion and emission characteristics of hydrogen-doped ammonia engines are studied. By employing 3D-CFD numerical simulation, this study systematically explores the combined effects of the ignition timing, hydrogen energy ratio (HER), and equivalence ratio (Φ) on the premixed combustion and emission performances of ammonia–hydrogen blends. The findings indicate that at the operating conditions of HER = 4% and Φ = 1.0, the indicated mean effective pressure (IMEP) reaches its maximum at −40 °CA aTDC, with the indicated thermal efficiency (ITE) reaching 48.2%. However, to mitigate knock hazards, the ignition timing should be adjusted to −37.5 °CA aTDC. With HER increasing from 4% to 25%, the flame propagation velocity is markedly improved, and the combustion duration is notably reduced. As the equivalence ratio rises from 0.8 to 1.0, the combustion intensity is strengthened while the proportion of indicated work declines. Notably, the lean burn condition (Φ = 0.8) exhibits no knock risk and achieves the highest ITE (49.2%). In terms of emission characteristics, advanced ignition timing, higher HER, and lower equivalence ratio all promote NOX formation. In contrast, N2O emissions decrease as the combustion temperature rises and the combustion duration shortens. Unburned NH3 is mainly distributed in the low-temperature areas inside the cylinder, and its emission amount decreases with the improvement of combustion completeness.
Keywords: sustainable; heavy-duty engine; hydrogen-doped; ignition timing; hydrogen energy ratio; equivalence ratio; combustion; emission sustainable; heavy-duty engine; hydrogen-doped; ignition timing; hydrogen energy ratio; equivalence ratio; combustion; emission

Share and Cite

MDPI and ACS Style

Xiong, Q.; Han, K.; Shi, X.; Liang, D.; Li, J.; Hou, X. Combustion, Emission, and Knock Characteristics in a Hydrogen-Doped Premixed Ammonia Spark-Ignition Heavy-Duty Engine. Sustainability 2026, 18, 42. https://doi.org/10.3390/su18010042

AMA Style

Xiong Q, Han K, Shi X, Liang D, Li J, Hou X. Combustion, Emission, and Knock Characteristics in a Hydrogen-Doped Premixed Ammonia Spark-Ignition Heavy-Duty Engine. Sustainability. 2026; 18(1):42. https://doi.org/10.3390/su18010042

Chicago/Turabian Style

Xiong, Qian, Kai Han, Xinru Shi, Dezhi Liang, Juntao Li, and Xuan Hou. 2026. "Combustion, Emission, and Knock Characteristics in a Hydrogen-Doped Premixed Ammonia Spark-Ignition Heavy-Duty Engine" Sustainability 18, no. 1: 42. https://doi.org/10.3390/su18010042

APA Style

Xiong, Q., Han, K., Shi, X., Liang, D., Li, J., & Hou, X. (2026). Combustion, Emission, and Knock Characteristics in a Hydrogen-Doped Premixed Ammonia Spark-Ignition Heavy-Duty Engine. Sustainability, 18(1), 42. https://doi.org/10.3390/su18010042

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