1. Introduction
For centuries, metal casting has been a cornerstone of industrial manufacturing, supplying essential components to sectors as diverse as automotive, aerospace, energy, and construction [
1,
2]. At the heart of this tradition lie SC and IC, two widely employed methods that collectively account for a significant proportion of global metal part production. Yet, while these foundry techniques have continually evolved to enhance product quality and operational efficiency, their environmental impact remains a pressing concern in the modern era. Traditional foundries are energy-intensive operations. The processes of melting metals, preparing moulds, post-processing castings, and managing waste streams demand large quantities of fossil fuel-derived electricity and heat [
3]. Globally, the foundry sector has been identified as a major contributor to greenhouse gas (GHG) emissions, not only through direct energy use but also by virtue of upstream activities such as extraction, refining, and transportation of raw materials [
4]. In countries heavily reliant on coal-based energy grids and carbon-intensive logistics, the footprint of casting operations becomes even more pronounced. Apart from emissions, the environmental challenges encompass significant generation of solid waste (spent foundry sand, slag, refractory materials), emissions of particulate matter and volatile organic compounds, and extensive water use for cooling and cleaning [
5]. These environmental externalities place traditional foundries at the forefront of regulatory scrutiny and transformation, as both policymakers and customers increasingly demand cleaner, greener industrial practices [
6].
Considering accelerating climate change and mounting societal pressures, industry has embarked on an unprecedented sustainability journey. In alignment with the Paris Agreement and various national pledges, manufacturers are setting ambitious “net-zero” targets and commitments to reduce or offset their total GHG emissions such that they no longer contribute to atmospheric carbon increases [
7,
8]. These net-zero goals have catalysed a paradigm shift, reframing manufacturing not just as an economic engine but as a critical participant in planetary stewardship [
9]. For foundries and casting operations, the path to net zero introduces both challenges and opportunities. Decarbonising legacy processes often demands innovative approaches that rethink material flows, energy sources, and production methods at the system level. Achieving NZEs requires a holistic reconsideration of every process stage, from raw material extraction and part fabrication to downstream logistics and end-of-life recovery [
10]. Technologies that can demonstrably lower environmental challenges while maintaining productivity are now seen as strategic imperatives in forging a more sustainable industrial future.
In the drive for net-zero manufacturing, robust and credible measurement of environmental impacts is essential. LCA has therefore emerged as a promising method for quantifying the environmental burdens of products and processes [
11]. Unlike conventional energy audits or simple carbon accounting, LCA encompasses a wide array of environmental indicators, including GHG emissions, energy consumption, water usage, air and water pollution, and resource depletion, systematically mapped across every process boundary. Within the context of casting, LCA enables manufacturers, researchers, and policymakers to pinpoint “hot spots” of environmental impact, evaluate the trade-offs between different process choices, and benchmark innovations against established baselines [
12].
To address the intertwined challenges of cost, complexity, and environmental impact in casting, advanced hybrid manufacturing approaches are rapidly gaining traction [
13]. In particular, the integration of AM techniques with traditional casting methods, leading to concepts such as AM-SC and AM-IC, offers unprecedented opportunities for process improvement and emission mitigation. AM, often referred to as 3D printing, enables the precise, digitally driven fabrication of complex geometries directly from CAD models, typically by successively layering materials. When synergised with casting, AM can be employed to produce optimised patterns, moulds, and cores, components that profoundly influence casting quality, efficiency, and material use. AM-SC involves the creation of sand moulds or cores using AM technologies (such as binder jetting or selective laser sintering), replacing or augmenting conventional patternmaking and mould assembly [
14,
15]. This allows intricate internal channels, reduced waste, faster prototyping, and enhanced near-net-shape manufacturing. AM-IC, on the other hand, leverages AM to fabricate wax or polymer patterns for investment casting shells. These patterns may incorporate designs not feasible through traditional subtractive tooling, and the process potentially minimises pattern waste and shortens lead times. Both hybrid approaches hold promise for improving product performance and manufacturing sustainability, yet their comparative environmental profiles remain ambiguous, especially as AM itself can be energy- and material-intensive [
16].
Existing studies have explored the environmental impacts of traditional and advanced manufacturing routes, with many studies focusing either on classical casting or standalone AM processes [
17,
18]. Recent works have highlighted the potential for energy and material savings in AM-assisted casting, as well as qualitative benefits such as shorter supply chains and lower transportation emissions. There is a notable lack of systematic, side-by-side comparisons between AM-SC and AM-IC from an environmental sustainability perspective. Most of the existing studies consider only technical performance, unit costs, or isolated emissions factors, often under disparate operational assumptions or differing system boundaries [
5,
19]. As such, manufacturers and decisionmakers currently lack clear, evidence-backed guidelines to select the most environmentally sustainable hybrid approach for specific applications. Much of the LCA work conducted to date has not harmonised input datasets, functional units, or allocation procedures, undermining cross-study comparability. Therefore, there is a critical need for a robust, transparent, and directly comparative “gate-to-gate” LCA analysis that accounts for identical process scopes, material flows, and realistic production scenarios [
20,
21].
The primary objective of this study is to address the gap by providing a comprehensive, comparative “gate-to-gate” LCA of AM-SC and AM-IC techniques by addressing the following research questions (RQs):
RQ1. To evaluate and compare the environmental impacts of AM-SC and AM-IC through LCA to assess their alignment with net-zero manufacturing objectives.
RQ2. To assess how the integration of renewable energy sources influences the environmental performance of AM-SC and AM-IC and how it contributes to accelerating the transition toward net-zero manufacturing.
RQ3. To deliver LCA-based empirical insights that inform decision-making by policymakers and industry stakeholders in selecting environmentally sustainable casting technologies.
The aluminium alloy Al-Si5-Cu3 (LM04) was selected due to its widespread use in automotive and aerospace components requiring high thermal conductivity, excellent casting properties, and moderate strength. Typical industrial applications include engine housings, pump casings, compressor bodies, and precision tooling components. Its balanced silicon and copper composition allows reliable performance across both sand and investment casting routes, making it an ideal candidate for comparative sustainability assessment.
The remainder of this work is structured as follows: 
Section 2 presents the literature review; 
Section 3 outlines the research methodology; 
Section 4 provides the data analysis and results; 
Section 5 discusses the findings and their implications; and 
Section 6 concludes the study, outlining its limitations and suggesting directions for future research.
  3. Methodology
  3.1. Goal and Scope Definition of This Study
The present work aims to offer a comprehensive comparison of the environmental performance of the AM-SC and AM-IC processes for fabricating parts from aluminium LM04 (Al-Si5-Cu3) alloy. By systematically quantifying and comparing their key environmental impacts, this research supports data-driven, sustainable decision-making for foundries and policymakers seeking to align with net-zero manufacturing targets.
Functional unit used in this study: To ensure a fair and practical comparison, the functional unit for this analysis is set as one finished aluminium casting product, weighing 240 g, representative of industrial applications.
The functional unit of one 240 g casting was selected as it represents the average part size for small to medium production batches in Indian foundries using AM-assisted hybrid processes. Although industrial parts often range from kilograms to tons, scaling analyses in prior LCA studies suggest that environmental indicators for casting processes scale non-linearly but proportionally with part weight within the same geometry and alloy family. Therefore, the selected functional unit captures the relative environmental trends of both AM-SC and AM-IC while maintaining data reliability and experimental control.
System boundary: A gate-to-gate analysis is adopted, beginning with patternmaking (using AM for patterns in both processes), proceeding through mould or shell making, metal melting and pouring, and ending with cleaning and finishing of the cast product. This boundary focuses exclusively on the environmental impacts arising during the manufacturing phase and excludes upstream activities (raw material extraction, transportation) and downstream stages (product use, end of life). This approach enables the direct comparison of foundry-level process alternatives and emphasises the operational improvements most relevant to net-zero objectives. 
Figure 1 represents the system boundaries for both processes.
Cut-off criteria followed the ISO 14044 mass, energy, and relevance thresholds of 1%. Excluded elements include alloy production, transportation of raw materials, pattern master fabrication for IC, and end-of-life treatment of cast parts. These exclusions are documented to maintain a consistent gate-to-gate focus.
  3.2. Life Cycle Inventory (LCI) Data
The LCI involves the detailed accounting of all material and energy flows for both AM-SC and AM-IC. Inputs and outputs at each stage (patternmaking, mould/shell preparation, metal melting and pouring, post-processing) are based on a combination of primary industrial data, experimental measurement, and the validated literature. 
Table 2 and 
Table 3 represent the LCI data for both processes.
Materials Used: Patterns/cores: these include PLA filament for AM-based sand casting patterns and wax or polymer for AM-based investment casting patterns.
Mold/Shell Materials: These include silica sand and binders (for sand casting), ceramic slurries (for investment casting shells), and auxiliary materials (e.g., water, cleaning agents).
Metal: Aluminium LM04 (Al-Si5-Cu3) alloy was utilised consistently in both process routes.
Energy Consumption: This includes electricity consumed by AM pattern printing (Fused Deposition Modelling, selective laser sintering, etc.), sand or shell preparation, core baking, and post-processing. There is also energy demand for metal melting (typically electric induction or gas-fired furnaces) and for thermal operations such as dewaxing or mould firing (in AM-IC). All energy values are measured or estimated per functional unit (one part) and normalised to gate-to-gate system boundaries.
Primary Data: This includes site visits, batch-wise recording of raw material and energy use, and production logs from Indian foundries (see 
Appendix A).
Secondary/Literature Data: This includes established LCI datasets from GaBi 9.2.1, international benchmarking, and previous validated studies.
Inventory data were measured directly from North Indian foundries; all flows were cross-validated per ISO LCA protocols for temporal and regional representativeness. Where regional data were lacking, documented global proxies were used, as detailed in 
Appendix A.
The modelling employed GaBi 9.2.1 with the following plan names: Electricity Mix India 2023 for grid power, Electricity Mix Wind, and Electricity Mix Solar for renewables. All electricity-dependent processes, printing, shell drying, burnout, melting, and finishing, were uniformly switched to the renewable mix during analysis to ensure scenario consistency.
  3.3. Impact Assessment
Environmental performance was assessed using the CML 2001 impact assessment method, widely recognised for its relevance in manufacturing LCA studies. This approach enables the characterisation of environmental challenges across a comprehensive set of categories, ensuring consistency with the ISO 14040 and 14044 standards. The environmental impact factors considered in this study are outlined in 
Table 4.
Each category captures distinct environmental pressures, from carbon footprint to toxicity and local ecosystem impacts, providing a robust basis for comparative analysis. All calculations and scenario modelling were performed using GaBi 9.2.1 software, which provides extensive, up-to-date LCI datasets and validated algorithms for impact assessment. This ensures methodological transparency and repeatability.
  5. Discussion and Implications
This work was designed to analyse the environmental sustainability of two hybrid manufacturing processes (AM-SC and AM-IC) for aluminium LM04 alloy, using a gate-to-gate LCA approach. Through a systematic analysis of process-level emissions, resource consumption, and the influence of various energy sources, the study aimed to offer a data-driven perspective on the contribution of these technologies to the broader vision of net-zero manufacturing. 
Section 5 is structured around the three primary RQs and shows how the study findings align with NZE objectives across the globe.
RQ1. To evaluate and compare the environmental impacts of AM-SC and AM-IC through LCA to assess their alignment with net-zero manufacturing objectives.
The comparative LCA of AM-SC and AM-IC for Al-Si5-Cu3, conducted under real-world manufacturing conditions and India’s grid electricity mix, decisively reveals that AM-SC holds a clear advantage across most environmental impact categories. AM-SC achieves a substantial 31.57% lower GWP, demonstrating its superior efficiency in minimising GHG emissions, a core metric for net-zero alignment. A similar trend extends to AP and EP, where AM-SC records 19.28% and 21.15% lower impacts, respectively, compared to AM-IC. The benefits are even greater in ecotoxicity-related categories: TETP and MAETP are reduced by 90.5% and 75.73%, respectively, with AM-SC. These substantial reductions can be attributed to fewer harmful emissions from sand and binder use, lower pattern material losses, and more straightforward process flows. Interestingly, HTP emerges as an exception, where AM-IC performs marginally better, likely due to reduced direct contact with sand-related compounds and potentially lower hazardous emissions during shell burnout. Despite this, the overall environmental balance woven by AM-SC aligns more closely with net-zero objectives, as it consistently delivers lower environmental emissions in categories most relevant to climate action and sustainable resource management. This comprehensive advantage not only positions AM-SC as an environmentally preferable pathway for aluminium casting but also strengthens the business and regulatory case for its broader adoption in decarbonising foundry sectors.
It is acknowledged that environmental impact factors scale non-linearly with the mass of the part due to process energy intensity, melt yield, and furnace efficiency. The 240 g part provides a conservative baseline to evaluate process-level efficiency differences rather than product-scale impacts. Future studies could extend this assessment to multiple mass ranges to establish a generalised scaling function for hybrid AM-assisted casting.
RQ2. To assess how the integration of renewable energy sources influences the environmental performance of AM-SC and AM-IC and how it contributes to accelerating the transition toward net-zero manufacturing.
The analysis of renewable energy scenarios marks an inflexion point in the environmental narrative of both casting routes. Substituting conventional grid electricity with renewables (such as wind, solar, hydro, or biomass) radically transforms the sustainability profile of both AM-SC and AM-IC. The most significant improvement is observed in GWP, where the use of wind energy results in an impressive 98.3% reduction compared to the baseline scenario using grid electricity. This decarbonisation trend extends across all other impact categories, AP, EP, and many ecotoxicity measures, showing substantial declines with the adoption of renewable energy. The environmental gap between AM-SC and AM-IC narrows; however, AM-SC consistently retains its performance advantage, even under renewable energy scenarios. These outcomes deliver a two-fold insight: First, achieving net-zero manufacturing is most effectively driven by the widespread integration of renewable energy, which can transform both conventional and hybrid casting processes into environmentally sustainable options. Second, process-level optimisation, such as selecting AM-SC over AM-IC, provides notable emission reductions on its own, which are significantly amplified when combined with renewable energy sources. The combined effect redefines what is achievable for industrial foundries. Incremental process improvements and systemic energy transitions must operate in tandem to unlock full progress toward decarbonisation and sustainable growth.
  Implications of the Study
RQ3. To deliver LCA-based empirical insights that inform decision-making by policymakers and industry stakeholders in selecting environmentally sustainable casting technologies.
The findings of this “gate-to-gate” LCA analysis provide actionable insights for both practitioners and policymakers navigating the road to net-zero manufacturing. The data-driven evidence firmly supports the prioritisation of AM-SC, particularly for applications where large-scale manufacturing, lower complexity, or recyclability of materials is critical. The demonstrable reductions across multiple impact categories offer a compelling argument for its deployment as a low-carbon, resource-efficient alternative in both existing and new foundries. At the same time, the study underscores the necessity for site-specific process selection. Although AM-IC offers advantages in applications requiring high surface quality and complex geometries, its comparatively higher environmental impact across most categories necessitates careful consideration in relation to specific project needs and end-use demands. The adoption of renewable energy emerges as a powerful equaliser capable of reducing, or in some cases nearly eliminating, the environmental footprint of even the more impact-intensive processes. For policymakers, these insights support the development of targeted incentives, modernisation of energy infrastructure, and creation of technology roadmaps that promote both renewable energy adoption and manufacturing process optimisation. For industry stakeholders, this study offers a solid benchmarking framework and quantifiable environmental performance indicators, enabling informed decision-making and systematic tracking of progress toward India’s 2070 NZE goal. This work supports a shift away from reliance on intuition or legacy methods, toward a data-driven paradigm defined by comprehensive environmental assessment, integrated system-level thinking, and a focused commitment to achieving net-zero manufacturing.
Based on the comparative findings, practical decision guidance is proposed to support process selection under different manufacturing scenarios (refer to 
Table 7).
This guidance aligns environmental and technical criteria to assist manufacturers in selecting the most sustainable hybrid casting route.
  6. Conclusions, Limitations, and Future Work
This work presents a comparative gate-to-gate LCA of two hybrid casting techniques, AM-SC and AM-IC, using Al-Si5-Cu3 alloy under different energy scenarios. The findings clearly establish that AM-SC is more environmentally sustainable than AM-IC across most impact categories, particularly under India’s current grid mix. AM-SC demonstrates 31.57% lower GWP, 19.28% AP, and 21.15% lower EP, among other significant reductions. These results highlight AM-SC’s potential as a strategic solution for foundries aiming to decarbonise their operations.
When the processes are powered by renewable energy sources, the environmental impacts for both AM-SC and AM-IC are reduced. The GWP is reduced by over 98% with wind energy compared to the grid mix, and other impact categories, including toxicity and AP, also decrease. Even within this renewable energy context, AM-SC consistently maintains its edge in eco-efficiency. This dual insight confirms that renewable energy adoption and process-level optimisation are complementary levers in advancing toward net-zero manufacturing. This study provides a robust, empirical framework to guide industry leaders and policymakers in selecting environmentally optimal casting techniques. AM-SC proves advantageous for use cases prioritising lower emissions, recyclability, and less intricate designs, while AM-IC remains preferable for components requiring high surface finish quality or complex geometries, albeit with a higher environmental trade-off.
The robustness of this work stems from primary LCI data collection and adherence to ISO 14040/44 for methodological consistency. This ensures credibility and reproducibility. The study’s approach and findings can guide practitioners and policymakers in integrating hybrid AM-assisted processes within broader sustainability and decarbonisation strategies.
  Limitations and Future Work
The scope of the present study is limited to a detailed comparative analysis of two hybrid processes, AM-SC and AM-IC, due to resource and experimental constraints.
The present work adopted a gate-to-gate system boundary, focusing solely on the manufacturing phase of the AM-SC and AM-IC processes. This boundary was selected to maintain data accuracy and ensure comparability of primary foundry operations. It is recognised that ecotoxicity and human toxicity are significantly influenced by upstream processes such as raw material extraction and alloy production. The reported magnitudes and rankings may vary under a cradle-to-gate scope. Future research should incorporate cradle-to-gate analysis to capture the full life cycle contributions of upstream stages and validate the robustness of the comparative results. Future work, integrating circular economy models such as closed-loop recycling of patterns and materials, can help refine pathways to achieve NZEs holistically.