3.1. Emissions from All Garages
Figure 3 shows the average PM
2.5 and PM
10 averages distributed monthly. Seasonal trends suggest that the highest particulate concentrations were reported during the summer months. Both PM
2.5 and PM
10 concentrations increase steadily starting from February (winter), with the most significant jump occurring between May and June. In June, average PM
2.5 concentrations reach a high of 21.73 µg/m
3 and 37.46 µg/m
3 for PM
10. These PM
2.5 concentrations are higher than the primary annual EPA National Ambient Air Quality Standard (NAAQS) of 9.0 μg/m
3 and the secondary standard of 15.0 μg/m
3, but less than the 24 h limit of 35.0 μg/m
3.
Table 2 shows the annual PM
2.5 concentrations at the three garages, together with the concentrations observed at the Taft station during the same time as the garage measurements. Emissions at the garages are higher than those from the ambient levels. The PM
2.5 levels when walking in the Campus Green garage were the highest, which is consistent with [
16], while PM
2.5 exposure when walking in other garages was close to those at the gates. All values are slightly higher than the NAAQS annual standard of 9.0 μg/m
3.
Figure 4 shows PM
2.5 concentrations by garages and sensor locations. Campus Green ground level measurements show high variability with concentrations ranging from 1.80 µg/m
3 to 28.59 µg/m
3 with a median of 9.72 µg/m
3. Underground gate concentrations are lower with less variation, with a similar median of 9.63 µg/m
3. Walking measurements show a broader spread of concentrations representing the dataset’s highest median and maximum concentrations. The mean walking concentration is 14.34 µg/m
3 for Campus Green, 10.33 µg/m
3 for CCM, and 10.90 µg/m
3 for Washington Park. Both underground and walking measurements for CCM show lower overall concentrations and less variability, with medians from 7 to 9 µg/m
3. However, outliers are more frequent within the CCM dataset than in the other two garages. Washington Park underground measurements show slightly higher concentrations than walking measurements.
Table 3 shows the seasonal trends of PM
2.5 concentrations in the three garages in comparison with those from the Taft site in means and standard deviations. The highest concentrations were observed during the summer for all three garages and Taft, while the traffic volumes tend to be the lowest due to the break. This seasonal trend is consistent with a previous study at the Taft site [
23] and is likely due to both meteorological factors and the hot soak of vehicles parked in garages. Campus Green has the highest values in the fall, spring, and summer among the three garages. This is likely due to the much higher traffic volumes. The underground garages (CCM and the Washington Park) did not lead to higher emissions, which can be due to the much smaller sizes or the exhaust fans. The lowest concentrations were observed in Winter in Campus Green and in Spring in CCM, Washington Park, and Taft.
Data variations, as indicated by the standard deviation, are the highest during the summer. The variations are generally higher in garage emissions than in the ambient, which may be due to less stability of the sensors.
These findings are largely consistent with the results reported by Gonzales et al., 2022, where PM
2.5 emissions in garages were higher than those observed from ambient monitoring stations, suggesting that garages can be local air quality hotspots for higher exposures [
24].
Figure S1 presents a box plot of the seasonal PM
10 trends of the three garages in comparison with those from the Taft site. Consistent with that of PM
2.5, the highest coarse particle level also occurred in the summer, with higher values in the garages. However, the ambient PM
10 levels are higher in fall and winter.
Table 4 summarizes the days with the highest PM
2.5 emissions at each garage, and all occurred in the summertime. All except one are much higher than the ambient values, while traffic volume was lower than the median. The PM
2.5 concentration observed on 17 July 2023 in CCM is likely due to the impact of the Canadian wildfires, which occurred from May through July of 2023, where smoke was dispersed by the North American trough and severely impacted PM concentrations [
15]. Time series of PM
2.5 and CO
2 levels of these three garages are shown in
Figures S2–S4, which suggest that these two components are generally not correlated. In addition, an average PM
2.5 concentration of 10.33 µg/m
3 was observed on 14 April 2025, one of the highest in spring, during the new control console installation at the CCM garage.
Table 5 summarizes PM
2.5/PM
10 ratios between the garage and Taft site by season. All the ratios (at all seasons) are greater than 0.5, which is an indication that fine particles are major contributors to PM emissions. The ratios are higher at garage sites than in the ambient conditions, since traffic emissions contribute more fine particles at garage sites. Consistent with another study [
25], the ratio was the lowest during winter, which may be related to humidity.
CO
2 levels in the three garages are shown in
Table 6. Although the seasonal mean CO
2 concentrations are higher than that of ambient (400 ppm levels), they are much less than the ASHRAE guideline of 1000 ppm [
26]. Higher standard deviations during the summer months indicate more CO
2 fluctuation compared to other seasons.
CO2 levels in Campus Green are relatively consistent with the least variations, which is largely due to the natural ventilation. Washington Park in the spring showed the highest average CO2 emissions. The highest emission day was on 16 March 2024, with an average CO2 level of 909.4 ppm. The highest CO2 emissions in CCM were also in spring. The highest emission day was on 5 June 2024, with an hourly average of 1050.2 ppm. A CO2 increase in spring and summer in the two enclosed garages is likely the result of the temperature increase. During the days when CO2 levels are close to 1000 ppm, it is desirable to start the ventilation and replenish fresh air.
NO
2 and VOC data were also measured with Flow2 sensors and are shown in
Tables S2 and S3.
Table S2 summarizes seasonal NO
2 concentrations among the three garages, with the highest NO
2 concentrations occurring in the summer and the lowest in winter for all garages, which is expected. The summer concentrations were comparable to those reported in [
24], which were 15.4 ± 3.6 ppb. NO
2 levels observed are far less than the NAAQS 1 h limit of 100 ppb. Since Flow-2 tends to underestimate NO
2 values [
27], direct comparison with FEM/FRM data should be cautioned.
Table S3 summarizes seasonal VOC concentrations among the three garages. No clear seasonal trends were observed, and the variations were high, which may be due to the emission characteristics or instability of the VOC sensor.
3.2. Emission Characteristics of Individual Garages
PM
2.5 concentrations grouped by different traffic periods at each garage are shown in
Figure 5a–c, and the averages are summarized in
Table 7. These data reflect the usage characteristics of the garages.
At Campus Green Garage (
Figure 5a), PM
2.5 concentrations during rush hours are higher than those of non-rush hours, which indicates the garage is mainly used by commuters on regular schedules. PM
2.5 concentrations at the AM rush hour had the highest mean value of 15.33 µg/m
3 and maximum concentrations reaching 30 µg/m
3, which is followed by those of the PM rush hour with a mean of 11.07 µg/m
3. PM
2.5 concentrations at non-rush hours are 51% and 35% lower than AM and PM rush hours, respectively.
During air quality sampling of the Campus Green Garage, it is frequently observed that drivers spend extended time circling in search of available parking spots. This repeated motion of cars contributed to increased vehicle idling and stop-and-go movement, which are conditions known to significantly increase pollutants such as PM, VOCs, and NOx.
In contrast, a different trend is observed at the two enclosed garages. PM2.5 concentrations at PM non-rush hours are the highest.
Figure 5b presents PM
2.5 concentrations for the CCM Garage across different traffic times of the day. PM
2.5 concentrations during the PM non-rush hour period had the highest average concentration of 13.04 µg/m
3 and the broadest range, with a maximum above 30 µg/m
3. PM
2.5 concentrations at PM rush hour display a tight spread and a mean around 7 µg/m
3, which could suggest improved ventilation or less vehicle congestion in the evening.
At the Washington Park Garage (
Figure 5c), PM non-rush hours had the highest median concentration within the data of 15.78 µg/m
3 and are tightly clustered. AM rush hour reported the second highest in concentrations with a mean of 11.51 µg/m
3 and a maximum value of 25.36 µg/m
3.
These two underground garages reported the highest emissions during the PM non-rush hour, which may be due to traffic leaving the garage ahead to avoid rush hour traffic. Different trends are shown in different garages, which warrants monitoring of each one individually. Contrary to anticipations, PM
2.5 concentrations during rush hours are not consistently higher than those during non-rush hours. This trend highlights the importance of continuous monitoring of garage emissions, rather than limiting the effort only to rush hours. PM
10 concentrations at each garage grouped by different traffic periods are shown in
Figures S5–S7, which present similar trends to those of PM
2.5.
3.3. Contributing Factors of Garage Emissions
Different regression models were used to evaluate the correlation of PM
2.5 concentrations between garages and the ambient site (Taft), as shown in
Figure 6. A positive slope indicates that as Taft PM
2.5 concentrations increase, garage PM
2.5 concentrations also increase. A strong linear correlation of R
2 = 0.6364 suggests that approximately 63.6% of the variation in garage PM
2.5 can be explained by changes in Taft PM
2.5. Additionally, a
p-value of 0.04 (less than 0.05) concludes that there is statistical significance between the garage and Taft sites. The significant relationship implies that ambient air quality is likely influencing air quality in parking garages. The strong correlation with ambient values is unique to this study, which has not been reported in other university garage emissions [
12,
14,
24]. The strong correlation with ambient air quality also suggests that control and mitigation practices can be implemented based on local air quality forecasts.
High correlations are also obtained from logarithmic and exponential regressions. However, some scatter and variability indicate that other factors, such as traffic and garage structure, may also affect pollution in garages. Similarly, a linear regression of PM
10 concentrations between garages and the ambient is also shown in
Figure S8, with a slightly lower R
2 of 0.44.
Table S4 shows hourly averaged traffic volumes from the three garages. The summer days with the highest emissions did not have higher traffic, which is also an indication that PM emissions at these garages do not correlate with traffic. The median 1 h car count was 98 vehicles for Campus Green, 67 for CCM, and 54 for Washington Park. With the exception of Campus Green, the largest garage, this volume is close to another college garage study, with a median of 71 cars per hour on weekdays [
12].
Table S4 also indicates that the traffic volume is not very different between rush hour and non-rush hours, which is likely due to the work-from-home practices post-pandemic.
The correlation between traffic volume and PM
2.5 was low, with an R
2 value of 0.09 for Campus Green, 0.21 for CCM, and 0.10 for Washington Park. This suggests that the correlation between PM
2.5 and hourly traffic volumes is not linear. One of the reasons may be the much lower average traffic volume compared with busy roads. This result is consistent with Gonzalez et al., 2022 [
24]. However, the same study found that CO and NO were strongly associated with car volume.