Study on the Hydration and Microstructure of B and B/Na Ion-Doped Natural Hydraulic Lime Composed with Silica Fume/Fly Ash
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation
2.3. Test Methods
3. Results
3.1. Mineral Content and Crystal Structure
3.2. Hydration Heat
3.3. Mechanical Properties
3.4. Phase Analysis of Binders
3.5. TG Analysis
3.6. Microstructure
3.7. Pore Structure
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Materials | CaO | SiO2 | Al2O3 | Fe2O3 | MgO | SO3 | Others | L.O.I |
---|---|---|---|---|---|---|---|---|
limestone | 48.33 | 3.61 | 0.81 | 0.73 | 3.00 | 0.05 | 0.38 | 43.09 |
Diatomite | 0.32 | 86.20 | 2.03 | 1.93 | 0.26 | 0.29 | 0.82 | 8.14 |
Fly ash | 2.88 | 50.54 | 26.86 | 5.95 | 0.74 | 0.52 | 5.93 | 6.59 |
Silica fume | 0.18 | 92.70 | 0.14 | 0.04 | 0.64 | 0.59 | 0.84 | 4.87 |
Sample | NHL | B1.5 | BNa1.5 | FA | SF | |
---|---|---|---|---|---|---|
Blank | NHL | 500 | ||||
F1 | 450 | 50 | ||||
F2 | 400 | 100 | ||||
S1 | 450 | 50 | ||||
S2 | 400 | 100 | ||||
B-ion doping | B1.5 | 500 | ||||
F1B1.5 | 450 | 50 | ||||
F2B1.5 | 400 | 100 | ||||
S1B1.5 | 450 | 50 | ||||
S2B1.5 | 400 | 100 | ||||
B/Na doping | BNa1.5 | 500 | ||||
F1BNa1.5 | 450 | 50 | ||||
F2BNa1.5 | 400 | 100 | ||||
S1BNa1.5 | 450 | 50 | ||||
S2BNa1.5 | 400 | 100 |
Phase | Space Group | ICSD Code | PDF Code |
---|---|---|---|
α’-C2S | Pnma | 81097 | 49-1674 |
β-C2S | P121/N1 | 963 | 33-0302 |
Portlandite | P-3M1 | 15471 | 44-1481 |
Rutile | P42/mnm | 9161 | 21-1276 |
Calcite | P3221 | 174 | 78-2315 |
Periclase | Fm-3m | 9863 | 45-0946 |
Samples | β-C2S | α’-C2S | ||||||
---|---|---|---|---|---|---|---|---|
V | a | b | c | V | a | b | c | |
NHL | 345.74 | 5.51 | 6.76 | 9.32 | ||||
B1.5 | 337.96 | 5.50 | 6.64 | 9.27 | 345.08 | 6.84 | 5.46 | 9.25 |
BNa1.5 | 345.68 | 5.51 | 6.75 | 9.31 | 344.91 | 6.85 | 5.45 | 9.24 |
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Zhang, Y.; Liu, Z.; Wang, J.; Shao, C.; Li, J.; Wang, D. Study on the Hydration and Microstructure of B and B/Na Ion-Doped Natural Hydraulic Lime Composed with Silica Fume/Fly Ash. Sustainability 2022, 14, 10484. https://doi.org/10.3390/su141710484
Zhang Y, Liu Z, Wang J, Shao C, Li J, Wang D. Study on the Hydration and Microstructure of B and B/Na Ion-Doped Natural Hydraulic Lime Composed with Silica Fume/Fly Ash. Sustainability. 2022; 14(17):10484. https://doi.org/10.3390/su141710484
Chicago/Turabian StyleZhang, Yanbo, Ze Liu, Jixiang Wang, Conghao Shao, Jiaxing Li, and Dongmin Wang. 2022. "Study on the Hydration and Microstructure of B and B/Na Ion-Doped Natural Hydraulic Lime Composed with Silica Fume/Fly Ash" Sustainability 14, no. 17: 10484. https://doi.org/10.3390/su141710484