1. Introduction
There is an increasing need for producing environmentally and economically sustainable solutions not only from governments but also from society, even more because structural materials are by weight one of the biggest contributors to greenhouse gases and freshwater consumption. Of course, there are positive aspects as well: construction and building materials can hold a high content of liquid and solid wastes, particularly concrete [
1], asphalt pavement [
2], geopolymers [
3], phosphates [
4], and soil [
5,
6,
7].
In some countries, there is still no specific use for some solid wastes, which is why managing to incorporate these wastes into construction materials is a great advance in achieving adequate sustainable waste management [
8].
In Colombia, companies are being forced to go green with multiple regulations and tax exemptions. Conasfaltos is a large infrastructure company producing around four tons/day of residual aggregate powder, currently disposed of in a landfill, and now being one of the leaders in the sector in transitioning to a circular economy. On the other hand, there are foundry companies that produce about one ton/day of sand waste, used for iron smelting. In addition, Colombia has very important mines of kaolin, producing large amounts of metakaolin, which is widely used in the construction industry in many applications, such as supplementary cementitious material. This is because metakaolin has greater pozzolanic activity due to its highly reactive amorphous phase, which occurs after the calcination of kaolinite [
9,
10,
11,
12].
Pozzolans usually react with portlandite to form more stable compounds, which can limit the amount of calcium and alkalis [
13]. The higher the pozzolan content, the lower the final portlandite concentration. Special care must be taken when dosing pozzolans such as ashes since high doses can produce other durability issues [
14], although it has been found that with the use of pozzolans, concrete can have greater durability [
15,
16]. These pozzolans have also been studied via artificial networks in alternative materials such as geopolymers [
17]. Some authors have used concrete demolition and the recycling of rubble in combination with additions of natural pozzolans to mitigate environmental side effects [
18]. Volcanic pozzolans and rice husk have also been studied due to their high silica contents [
19,
20], whereas lamp glass waste has been used to evaluate reactivity by replacing fine aggregates instead of cement [
21,
22]. The classification of pozzolans according to Colombian Technical Standard 3493 is as follows: Class N: natural, calcined, or raw pozzolans such as some diatomaceous soils, flint and opaque shales, tuffs and volcanic ash, or pumice stone [
23]. Class F: fly ash produced in the burning of anthracitic or bituminous coal. This class of fly ash has pozzolanic properties [
23]. Class C: fly ash produced from lignite or sub-bituminous coal, which having pozzolanic properties, possesses cementing properties. Some class C ashes have lime contents greater than 10% [
23].
On the other hand, foundry sand is a high-quality silica sand, a solid waste by-product of the smelting production of ferrous and non-ferrous metals, therefore typically containing several hazardous metals. Raw sand (base sand) is usually of higher quality than natural sand used in construction. Foundry sand consists of 85–95% high-quality silica sand, 7–10% bentonite or kaolinite clay, 2–5% water, and approximately 5% charcoal [
24,
25,
26]. In the smelting process, the molding sand is recycled and reused several times and is degraded to the point where the old sand is removed from the cycle as a by-product, new sand is introduced, and the cycle starts over. The smelting of foundry sand results in large volumes that cannot be stored. Since foundry sand is basically a fine aggregate, it can be used in many ways [
27].
In Colombia, the aggregates that are used in the production of hydraulic concrete are exploited mainly in mountainous areas. As these sites have difficult geography, heavy machinery must be used, which generates more expenses but is also a source of employment for local people [
28].
Differently, metakaolin (MK) [
29] is a thermally activated alumina–silicate, obtained by calcining kaolin clay in a temperature range of 650 to 800 °C. Due to its high pozzolanic properties, the use of MK as an addition to concrete has attracted high interest in recent years. An important difference between MK and other supplementary cementitious materials is that MK is a primary product, whereas others are by-products. Therefore, MK can be produced in a controlled process to achieve desired properties. The use of MK improves the compressive strength of concrete, especially during the first stages of hydration. The increase in concrete strength with MK is because MK particles fill the space between cement particles and accelerate cement hydration and pozzolanic reaction. However, after 14 days, the contribution that MK makes to the strength of concrete is reduced [
29]. The concrete consumption is quite large elsewhere. It has been estimated that cement consumption worldwide was approximately 3309 million metric tons in 2018 [
30,
31]. In Colombia, from January to May of 2019, ready-mix concrete production reached a volume of 2.83 million cubic meters [
32]. Thus, with the use of the solid wastes selected in this research, the impact on cement consumption can be very significant. There are several research gaps in the use of these wastes, the main one being the combination of them now with the shortage of raw materials and useful wastes for concrete. This research aims to make these solutions sustainable not only ecologically but economically as well. Additionally, few of the studies have real applications and are mostly at a laboratory scale, and do not involve large companies in the construction sector.
The main goal of this investigation is to develop mixtures of hydraulic concrete with MK and two local industrial by-products: residual aggregate powder and sand waste from the iron smelting process. Thus, the novelty is a project with a potential technical collaborative solution for several large industries: aggregates, steel making, and concrete industry. This collaborative solution is required for the industrial parks in Colombia, where companies can reduce important logistics costs with smart cooperation. Moreover, this research is applied in the large industry of Medellín, Colombia. Another important objective is to evaluate whether the by-products can be used as natural pozzolans as defined by the ASTM. It is expected that the mechanical performance and durability of concrete with these wastes can be similar or competitive to concrete with MK. The circular economy of materials [
33,
34,
35] and processes [
36,
37,
38] is very important today, and this research contributes not only to reducing pollution but also to showing other similar industries how to make an impact on these topics.
2. Experiments
Aggregates used in concrete mix designs were provided by the company Conasfaltos SAS from materials produced in Colombia. Coarse and ¾” aggregates were used in concrete. The coarse sand used was obtained by classifying river material in Medellín; its gradation is shown in
Figure 1a.
Figure 1b shows gradation of ¾” (19 mm) aggregate, obtained through primary crushing and classification processes.
Table 1 shows the physical properties of these aggregates. The cement used was type III structural cement, typically used for high early strengths; its properties are summarized in
Table 2.
The metakaolin (MK) was used as additive reference material in order to establish comparisons with the by-product’s performance in concrete; see its properties in
Table 3. Two types of materials were used as additives: residual aggregate powder (a by-product of asphalt mix production) and foundry sand. These two materials were evaluated as natural pozzolans.
Table 3 shows the characterization of the foundry sand and the by-product (residual aggregate powder-PB).
A plasticizer admixture that complies with type A and F standards [
51], for chloride-free or other materials with oxidation potential, was used to give manageability for approximately half an hour and for reducing the amount of water in the designs. Slumps of 18 cm were sought because this concrete can be pumped; the dosage was 0.7% of the weight of the cement.
The experimental design followed in this research was the categorical factor, obtained in STATGRAPHICS (see
Table 4). This method was considered because three variables were used as additives (metakaolin, residual aggregate powder-PB, and foundry sand); but the variables are independent and no combinations between them were evaluated.
Concrete mixtures were made by evaluating each variable in a wide range of percentages, from 0 to 20 wt% of the cement. In this design, each factor or variable is independent and takes equally spaced values, usually taken as 1, 2, 3, 4, and 5; which are equivalent to percentages of each variable between 0, 5, 10, 15, and 20%. For the experiments described in this investigation, the three main variables were: industrial by-product 1 (residual aggregate powder-PB), industrial by-product 2 (foundry sand), and MK. The time during which the evolution of the resistance of each sample was measured was from 3 to 270 days. The additions of by-products and MK were then evaluated in concrete with a strength of 280 kgf/cm2 (27.5 MPa), one of the most commercially used and therefore representative of the construction sector.
The design method followed in this research is based on the Vitervo O’Reilly Díaz method [
52], which takes the following steps: determination of the required strength, the maximum size of the coarse aggregate, maximum size of the sand and the fineness modulus ranges, slump determination, calculation of the water/cement ratio, the amount of cement per cubic meter, and the determination of the optimal ratio of coarse and fine aggregates.
Table 5 shows the concrete designs with residual aggregate powder-PB.
Table 6 shows the designs evaluated with MK.
Table 7 shows the designs made with foundry sand.
In total 21 cylindrical samples of 10 × 20 cm2 each were made for each concrete formulation (numbered M1 to M15), for a total of 315 concrete cylinders. For each percentage of the addition, three cylinders were tested for each age. The ages of the tests were: 3, 14, 28, 56, 90, 180, and 270 days. All cylindrical samples were kept submerged in water during the tested period. The air content for each sample and the density were measured. The compressive strength of all samples was measured in a Controls CT-1303 press. Scanning electron microscope (SEM) characterization was performed with an energy dispersive spectroscopy (SEM–EDS) type JEOL JSM-6490LV operated in a high vacuum mode, used to observe the microstructure and chemical composition of the samples. Petrography tests were also included.
The cost of the concrete was determined based on the internal production costs for the company. The cost of MK and the cost of production of the by-products were taken from the Colombian market.
3. Results and Analysis
Petrography on the aggregates for gravel fractions below ½” showed the following results: volcanic andesite (40.2%), amphibolite (21.4%), quartzite (15.2%), andesite (3.5%), microgram (7.8%), silicate andesite (3.5%), chert (1%), alternating volcanic rock (9%), sublioarenite (0.3%), and altered gaps (1.6%). Aggregates tend to be sub-granular with some sphericity. The porosity of the sample was estimated at 3.8%, and the percentages of fractures at the macroscopic and microscopic levels were estimated at 0.3%.
Figure 2a shows the EDS spectrum of the aggregates, with Si, Ca, Mg, and Fe as the main elements forming oxides.
Table 8 shows the quantification presented by the evaluated aggregate, where their components were quantified via Rietveld analysis, finding albite (46.1%), clinochlore (23.2%), muscovite (12.8%), quartz (9.9%), and amphibole (7.9%). In the spectrum, the aggregate used has silica and alkalis in its composition, containing sodium and potassium. Results of the SEM are shown in
Figure 2b, which has an average size of 3 mm. The discontinuous and rough surface of the aggregate with a non-homogeneous surface can be appreciated. The sample contains silica, aluminum, magnesium, oxygen, calcium, iron, sodium, and potassium.
Figure 3 shows the XRD for cement, where most representative peaks are analyzed and the cement composition is presented in
Table 9: quartz (28%), lime (11%), periclase (7%), tricalcium aluminate (13%), calcite (21%), and goethite (20%).
Figure 3 shows the spectrum for MK: quartz (92%) and cristobalite (8%). In
Figure 3, the spectrum of residual aggregate powder-PB is presented, and in
Table 9, the quantified composition is summarized. This contains minerals such as quartz (13%), oligoclase (23%), hornblende (19%), albite (21%), chamosite (7%), and tremolite (17%).
Figure 3 shows the spectrum of the foundry sand, and in
Table 9 the composition is summarized. This contains quartz (55%), brucite (6%), franklinite (2%), protoenstatite (7%), and kyanite (30%).
The SEM characterization for the cement is presented in
Figure 4a, showing a large number of particles of different sizes, which indicates the presence of ashes.
Figure 4b shows SEM for metakaolin, which is known to be partially crystalline [
53], revealing different particle sizes.
Figure 4c shows the results of the SEM for the residual aggregate powder, which has a cement-like structure, and clearly is not homogeneous.
Figure 4d is the SEM of the foundry sand, showing more homogeneous particle sizes with an elongated type grain [
54].
Table 10 shows the quantification of the elemental composition of each raw material, which reveals that the foundry sand and the residual aggregate powder have a high silica content, even greater than cement, whereas the metakaolin is relatively low.
All samples were prepared with a constant water to cement (w/c) ratio, but this ratio was a function of each of the additions (residual aggregate powder, foundry sand, or metakaolin). With metakaolin, the w/c ratio increased in the mixtures, because they were not sufficiently hydrated, and adding water was necessary, which did not affect the final strength. It is known that metakaolin tends to dry the mixtures, and that is why a higher w/c ratio is required in order to find the desired consistency [
55]. For the two by-products, the w/c ratio remained constant and the addition of water to the design was not necessary. In all the sample formulations (M1 to M15), the air content and the manageability of the concrete were measured, the mixing process was started, and after one hour, the property was evaluated with the settlement test [
56]. Samples were broken using a Controls CT-1303 press, following the corresponding standards [
57]. The density of each concrete produced was also measured.
Figure 5a–c shows all samples (M1 to M15) tested after 270 days of being submerged, the aggregate is covered homogeneously by the cement paste, and there is no particle detachment at the time of failure. In addition, the concrete mixtures were cohesive. On the other hand, it is evident that the failures were due to the cut type of all samples, some to a greater extent than the others.
Table 11 shows a summary of the properties evaluated for fresh concrete mixtures which contained the additions of metakaolin, residual aggregate powder-PB, and foundry sand, from M1 to M15 (experimental design). For each concrete mixture, compressive strength was tested after 270 days of being submerged in water. Density was measured on freshly prepared concrete, which is very similar for all the samples (around 2400 kg/m
3). The fresh air content was measured (between 1.2% and 2%); it was sought that the air content did not exceed 3%, since this helps to achieve more durable concrete.
Figure 6a shows the evolution strength for samples M1 to M5 starting at day 3 up to day 270, produced with the PB residual aggregate powder. Dosages evaluated using the residual aggregate powder as a replacement help achieve the design resistance of 280 kgf/cm
2 (27.5 MPa). With the 15% addition (M4), the highest strength of 541 kgf/cm
2 (53.1 MPa) is reached, whereas with 20% (M5) the strength was 440 kg/cm
2 (43.1 MPa).
Figure 6b shows the slumps of the four samples with residual aggregate powder (M2–M5) and the standard sample (M1). This property is measured at the initial time of the test and one hour later for the five samples, measuring the workability of concrete. At the initial time, the five samples showed good manageability (zero hours). The settlements obtained were between 16 and 18 cm. These results are within the expected range for concrete that can be pumped. After an hour, workability was lost, because the slump went from between 16 and 18 cm to between 5 and 8 cm. The error is shown for each of the samples at the ages of failure, which are not pronounced, showing that the values obtained are reliable.
Figure 7a,c,e,g,i shows the initial settlements of the samples evaluated with residual aggregate powder, and the appearance of the mixtures right after production is presented.
Figure 7b,d,f,h,j shows slumps after an hour, evidencing that the mixtures lost manageability and were not workable.
Figure 8a shows the strength evolution of samples M6 to M10, produced with metakaolin, starting at day 3 and up to day 270. With 15% of metakaolin (M9), the highest strength of 609 kg/cm
2 (59.7 MPa) was reached, whereas with 20% (M10) strength begins to decrease reaching 590 kg/cm
2 (57.9 MPa). The design strength was achieved in all samples, but the highest peak was obtained with a 15% addition. The increase in concrete strength with the addition of metakaolin was largely due to the formation of an optimal microstructure within the concrete [
58].
Figure 8b shows the slumps of all four samples made with metakaolin (M7–M10) and the standard sample (M6). This property was measured at the initial time of the test and one hour later for all samples. All of them showed, at the initial time, good workability, and the slumps were between 16 and 18 cm, all within the expected range. After an hour, the workability was lost, showing results between 6 and 10 cm with acceptable error bars, suggesting a reliable material.
Figure 9a,c,e,g,i shows the initial slumps and
Figure 9b,d,f,h,j shows the slumps after an hour, clearly losing workability.
Figure 10a shows the strength evolution for samples M11 to M15, starting at day 3 and up to day 270, produced with foundry sand. With 20% of the addition (M15), the strength of 561 kgf/cm
2 (55 MPa) was achieved. The design resistance was achieved in all samples, but the highest peak was obtained with a 20% addition of the foundry sand.
Figure 10b shows slumps of the four samples made with the foundry sand (M12–M15) and the standard sample (M11). All five samples produced, at the initial time, good workability with slumps between 18 and 20 cm, all within the expected range. After an hour, the workability was lost to values between 6 and 10 cm, and the error bars suggested a very reliable material.
Figure 11a,c,e,g,i shows the initial slumps, whereas
Figure 11b,d,f,h,j shows slumps after an hour, where there is evidence that the mixtures lost workability.
Figure 12 shows the XRD for samples of standard concrete and samples including the residual aggregate powder-PB (M1–M5) after 270 days. Each peak was identified and the quantification of the crystalline phases is summarized in
Table 12. All samples have quartz and calcite, and excepting samples M5, also contain cristobalite. Other identified phases are albite and ettringite, hornblende, greenalite, cordierite, oligoclase, portlandite, ferrobustamite, anorthoclase, and annite.
Figure 13 shows XRD for samples of standard concrete and samples including metakaolin after 270 days (M6–M10). Each peak was identified, and the quantification of the crystalline phases is summarized in
Table 13. All samples contained quartz, calcite, cristobalite, and oligoclase. Other identified phases are albite, ettringite, ferrosilite, enstatite, cordierite, portlandite, chamosite, and anorthoclase.
Figure 14 shows XRD for samples of standard concrete and samples with foundry sand after 270 days (M11–M15). Each peak was identified, and the quantification of the crystalline phases is summarized in
Table 14. All samples contained quartz and calcite. Other identified phases are cristobalite, albite, ettringite, cordierite, oligoclase, portlandite, biotite, and dolomite.
Figure 15a,b shows SEM results for the reference sample M1, which does not contain additives.
Figure 15a shows the aggregate covered by hydrated cement paste, which is not homogeneous, showing some areas with more pores than others [
59]. In
Figure 15b, the characteristic ettringite structures can be seen, a phase that increases cohesion in cement and occurs at late ages [
60]. The SEM results for the M2 sample, with 5% of the residual aggregate powder as addition, are presented in
Figure 15c,d.
Figure 15c shows the aggregate covered by hydrated cement paste [
59]; the structure of ettringite can be seen in a pore [
61].
Figure 15d shows the surface of the aggregate, surrounded by hydrated cement paste. The SEM results for the M3 sample, containing 10% of the residual aggregate powder, are shown in
Figure 15e,f.
Figure 16e shows hydrated cement paste [
59], and within a pore, portlandite (calcium hydroxide), which acts as an “alkaline reserve”, thus keeping the reinforced concrete protected against electrochemical corrosion [
62]. Image 15f shows a portion of the aggregate surrounded by hydrated cement paste, as well as ettringite [
61], on the surface. The SEM results for the M4 sample, containing 15% of the residual aggregate powder, are presented in
Figure 15g,h.
Figure 15g shows hydrated cement paste surrounding the aggregate, revealing some porosity in the paste.
Figure 15h shows hydrated cement paste surrounding the aggregate, with ettringite surrounded by paste [
61]. This hydrated cement phase increases the cohesion in the cement [
62].
Figure 15i,j shows the SEM results for sample M5, containing 20% of the residual aggregate powder.
Figure 15i shows hydrated cement paste surrounding the aggregate, covering it in a homogeneous way. The porosity in the paste can also be seen.
Figure 15j is a higher magnification, where hydrated cement paste is seen surrounding the aggregate and C-S-H gel is presented [
61], which is responsible for the adhesion of the paste with the aggregates [
60].
Table 15 shows the elementary quantification found by EDS mapping, performed on each sample. It was found that all samples have C, O, Mg, Al, Si, Ca, and Fe, whereas Na, K, and Mn are found in some formulations.
Figure 16a,b shows SEM images of the standard sample M1 just for comparison.
Figure 16c,d shows SEM images for sample M7, which contains 5% of the metakaolin.
Figure 16c shows hydrated cement paste surrounding the aggregate.
Figure 16d shows the structure of the metakaolin in a portion that did not react.
Figure 16e,f shows the SEM for sample M8, containing 10% of the metakaolin.
Figure 16e shows hydrated cement paste surrounding the aggregate, whereas
Figure 16f shows a higher magnification of the image, where hydrated cement paste is seen surrounding the aggregate.
Figure 16g,h shows results for sample M9, containing 15% of metakaolin, where the hydrated cement paste is surrounding the aggregate.
Figure 16h shows the image at a larger magnification, where hydrated cement paste is seen surrounding the aggregate and tobermorite gel or C-S-H [
63].
Figure 16i,j shows results for sample M10, which contained 20% of the metakaolin as an addition.
Figure 16i shows hydrated cement paste surrounding the aggregate.
Figure 16j shows the image at a higher magnification, where hydrated cement paste is seen surrounding the aggregate and tobermorite gel (C-S-H) [
61].
Table 16 shows the elementary quantification found by EDS mapping, performed on each sample. It was found that all samples have C, O, Mg, Al, Si, Ca, and Fe, whereas some samples do not have Na, K, and Ti.
Figure 17a,b shows the results of the SEM test of the standard sample M1, just for comparison.
Figure 17c,d shows results for sample M12, containing 5% of foundry sand.
Figure 17c shows hydrated cement paste surrounding the aggregate.
Figure 17d shows the hydrated cement paste surrounding the aggregate and tobermorite gel (C-S-H).
Figure 17e,f shows sample M13, with 10% of the foundry sand, showing hydrated cement paste surrounding the aggregate. Ettringite is also observed. The results for sample M14, with 15% of the foundry sand, are presented in
Figure 17g,h.
Figure 17g shows hydrated cement paste surrounding the aggregate, with some hard to see porosity.
Figure 17h shows the details of a pore, within which, ettringite, C-S-H gel (responsible for the adhesion of the paste with the aggregates), and portlandite (responsible for the protection of concrete against corrosion) are observed in this image. For sample M15, with 20% of foundry sand, SEM images are shown in
Figure 17i,j, revealing the cement paste surrounding the aggregate and tobermorite gel at two different magnifications.
Table 17 shows the elementary quantification found by EDS mapping performed on each sample, where all samples have C, O, Mg, Al, Si, Ca, and Fe, whereas some samples do not have Na and K.
4. Discussion
The case study described in detail in this investigation is considered very successful for several reasons. First, there is a big part of the world where the implementation of some recycling technologies is not only not possible from an economic but also from a political point of view. Therefore, the combination of complex materials in relatively simple and accessible methods is a real solution, and its impact in terms of environmental and economic solutions can be large. This, in addition to a raw materials shortage in the concrete industry, is an important area where the current research shows high potential for providing solutions by combining solid wastes.
Recycled by-products from the ceramic industry, such as those used in this research, and particularly those from the metallurgical industry, are a worldwide problem. In addition, this research gives a real solution for two very different industries: steel smelting and quarry, both generating large amounts of solid waste. The complexity of these wastes forced companies from these sectors to dispose of them in landfills or in some cases illegally dispose of them in rivers. Both are not good solutions. In addition, this research is a company–university collaboration, which has proven to be a good example for large-scale implementations in the country, not only in the field but also for promoting and motivating politicians to generate new regulations that really enable the construction industry to use these novel materials. Moreover, from the materials engineering point of view, the use of these solid wastes reduced the amount of raw cement necessary in the concrete mix, as these by-products act as natural pozzolans replacing part of the cement, therefore helping decrease the CO2 footprint.
Additionally, a comparison of concrete with a commercial metakaolin and two by-products, the residual aggregate powder and the foundry sand, showed the following important results: the standard concrete resulted in a strength of 349 kgf/cm2, corresponding to a 24% improvement with respect to the design strength of 280 kgf/cm2 (27.5 MPa). Besides, concrete with the residual aggregate powder gave a strength of 541 kgf/cm2 (53.1 MPa), which corresponds to M4 (concrete containing 15% of residual aggregate powder), corresponding to a 93% improvement with respect to the strength resistance. Furthermore, concrete with the foundry sand powder gave a strength of 561 kgf/cm2 (55 MPa), corresponding to a 100% improvement with respect to the strength resistance, which corresponds to M15 (concrete containing 20% of foundry sand). Finally, concrete with the metakaolin powder presented a strength of 609 kgf/cm2 (59.7 MPa), which corresponds to M9 (concrete containing 15% of metakaolin), corresponding to a 116% improvement with respect to the strength resistance.
These are very significant improvements that validate its use in infrastructure. This opens up research to the use of naturally occurring pozzolans, such as those with a volcanic origin, in great abundance in Central and South America [
64]. The used by-products may have hydraulic and pozzolanic reactions. The first is chemical reactions in the presence of water that allows them to harden, like what happens with Portland cement. The second is the reactions of silica oxides in the presence of calcium hydroxides (portlandite) and water to form hydrated calcium silicates [
65]. The calcium hydroxides that are one of the hydration products of Portland cement can also be produced by SCM itself by combining the CaO they contain with water [
66]. The generation of hydrated calcium silicates from the pozzolanic reaction helps to densify the microstructure of the concrete, decrease its porosity, and increase its mechanical strength.
On the other hand, for a complete pozzolanic reaction and good curing in concrete, it is necessary to have an important amount of available water in the mix [
67]. In this investigation, it was possible to maintain a good cure during the whole time of the test, since the cylinders were completely submerged, which contributed to a complete pozzolanic reaction of both the by-products and metakaolin.
The use of pozzolans as a complement to Portland cement generally influences reducing the heat of hydration because it has a lower percentage of the compounds responsible for raising the temperature during the setting of the cement, which implies a less capillary formation and therefore a greater density and compactness, which is reflected in a lower need for water to cure the elements made with this type of mixture. Furthermore, these additions improve the development of resistance and the durability of mortars and concrete [
68]. The two by-products evaluated in this work are natural pozzolans (residual aggregate powder and foundry sand), and therefore gave appropriate results, far better than standard concrete, indicating that the concrete had greater compactness and density. The addition of MK to cement to generate mortars produces phase changes and microstructural transformations that affects the physical and chemical properties of the material. The OH- ions that are produced in the hydration of the cement are deposited in the pores of the concrete and when coming into contact with the amorphous silica of the pozzolans, as in the case of MK, an extra gel of hydrated calcium silicate is formed and the calcium hydroxide is reduced, giving important advantages to the mixtures, such as the increase in its mechanical strengths and the decrease in porosity, which is why it has been called a micro-filled effect. The MK reacts with the free calcium hydroxide [Ca(OH)
2] of the cement hydration process to form secondary C
2S, which subsequently forms the hydrated calcium silicate gel or tobermorite gel, the hydrated bicalcium silicoaluminate (gehlenite) and sometimes hydrogranates (hydrogarnet), which contribute to the improvement of the mechanical properties of the mixtures [
69]. The metakaolin applicability has focused on artificial pozzolan in the production of mortars and concretes. Its pozzolanic activity, especially at an early age, is comparable to or superior to silica smoke and fly ash, which are two of the most widely used pozzolans in the world. In addition, it has the great advantage of its white color which allows its use in special applications and even in the production of added white cement [
69]. In the samples analyzed with the XRD after 270 days (see
Figure 12,
Figure 13 and
Figure 14), the components were evidenced to have helped achieve high-strength concrete with acceptable amounts of cement, thus accomplishing concrete that is not expensive. This was revealed when the used by-products rose some of the compounds responsible for high strength, supported by SEM images. The solid waste materials used in this case study were residual aggregate powder and foundry sand, both classified as N-type ashes. On the other hand,
Figure 6b,
Figure 8b and
Figure 10b were made based on the settlement (slump) of the concrete, tested just after the mixing and after 1 h of making the mixtures. With these graphs, it was shown that the concretes elaborated in this investigation must be used within an hour for any application; after this time, the concretes are not pumpable.
Figure 18 shows an economic analysis of the alternatives to concrete production. This graph shows the cost of each concrete formulation evaluated with the by-products and metakaolin. The cost of concrete with metakaolin is higher than with the by-products, which confirms the importance of using wastes and materials within reach. Concrete produced using the by-products would be more competitive at a commercial level since it could be cheaper and with similar characteristics to concrete with MK. Several eco-friendly solutions have been developed and implemented in Colombia as circular economy strategies in cementitious materials [
70,
71] and other building materials [
72,
73], aiming to reduce pollution by using concrete to hold solid wastes that are unproperly treated, reused, or disposed of. This research is a contribution to improve material circularity in the region and must be expanded for a larger impact on the environment.
In this study, the test of natural pozzolans was carried out for use as a mineral additive in Portland cement concrete, ASTM C311 standard, for the three materials studied. According to the standard, to be considered as materials with pozzolanic activity, these materials must have an index greater than 75% at 28 days. For the foundry sand, a 75.5% resistant activity index was obtained, meeting the standard requirements. According to the ASTM 311 standard, the fineness of these materials must be a minimum of 34% to be considered a pozzolan, and with the foundry sand, 65.4% was obtained. In relation to the addition of 20%, the concrete design was made based on 1 m3 of concrete, and the additions were made based on the amount of cement. Thus, the additions increase the m3 of designed concrete, with a good density of 2458 kg/m3.
In this study, hydraulic concrete mixtures were designed as can be seen in
Table 5,
Table 6 and
Table 7. These designs contained: cement, water, fine sand for concrete 3/8 of an inch (maximum size 9.53 mm), ¾ inch gravel (maximum size 25.4 mm), plasticizer additive, and additions (foundry sand, residual aggregate powder-PB, or metakaolin). In
Figure 1, we see the distribution of the particle sizes of the aggregates used, coarse (crushed ¾ inch) and fine (fine sand size 3/8 in), in order to provide the concrete with strength and give structure to it. In
Figure 4, the morphology of the materials at a scale of 100 μm is evidenced, showing that the foundry sand and residual aggregate power do have a slightly larger particle size than cement and metakaolin, not to be used as fine aggregate, but as natural pozzolans. Although the specific surfaces of foundry sand and residual aggregate powder were not tested, with the measurement that was made of their fineness it can be seen that they are within the norm to be considered a natural pozzolan.
The presented results and method of this research can be fully applied to the particular mix of waste materials since they showed a strong influence on the properties of concrete. An important alteration in the waste chemistry may affect the microstructure and the corresponding properties; thus, results cannot be generalized to other wastes. This limitation is an opportunity to conduct more research depending on chemistry variation parameters which could include pH, calcium, other element variation contents, particle size distribution, and more.