Hot-Pressed Multicomponent Recycled Textile Polymer Blends Reinforced with Ground GFRP from Wind Turbine Blades: Microstructure–Property Relationships
Abstract
1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Composite Preparation
2.3. Microstructural Characterization
2.4. Sample Preparation
- (a)
- drying of the matrix regranulate,
- (b)
- preparation of mixtures with the required GFRP reinforcement content,
- (c)
- hot pressing in a heated mold,
- (d)
- cooling and demolding of the plates.
2.5. Mechanical and Structural Testing of Samples
2.6. Static Bending Strength Test
2.7. Charpy Impact Test
2.8. FTIR Analysis of Composite Samples
3. Results and Discussion
3.1. Chemical Composition Analysis and Microstructural Characterisation of the Plates Obtained
3.2. Bending Test Results
- (a)
- reinforcement dispersion and interfacial adhesion—local fiber agglomeration and weak interfacial bonding may promote stress concentration and earlier crack initiation;
- (b)
- consolidation quality during pressing—higher GFRP content may hinder densification of the charge and promote the formation of pores and voids;
- (c)
- the multi-component nature of the polymer matrix—the heterogeneous composition of the matrix (different polymers and additives) may locally alter matrix properties and affect reinforcement efficiency.
3.3. Impact Test Results
- Saturation Threshold and Limited Reinforcement Efficiency in Impact
- 2.
- Dispersion and Interfacial Adhesion at the Fiber–Matrix Boundary
- 3.
- Matrix Properties and Heterogeneity
- 4.
- Morphology of the Ground GFRP Reinforcement and Consolidation Defects
4. Conclusions
- (a)
- The incorporation of ground GFRP (10–30 wt.%) into the recycled polymer matrix did not result in a monotonic improvement in flexural or impact properties compared with the unreinforced material.
- (b)
- The highest average flexural strength was observed for the reference material without reinforcement, indicating that the addition of ground GFRP did not necessarily enhance the load-bearing capacity of the investigated recycled system.
- (c)
- Charpy impact strength values remained within a relatively narrow range (7.3–8.46 kJ/m2), showing no clear dependence on reinforcement content.
- (d)
- The mechanical performance of the investigated composites appears to be influenced primarily by microstructural heterogeneity, fiber morphology, and interfacial interactions rather than by reinforcement fraction alone.
- (e)
- The results indicate that ground GFRP recovered from wind turbine blades can be incorporated into recycled polymer blends; however, the effectiveness of reinforcement may be limited by fiber fragmentation, dispersion quality, and consolidation-related defects.
- (f)
- From a practical perspective, the investigated system demonstrates the potential for producing rigid boards from mixed textile-derived polymer recyclates and mechanically ground GFRP waste, although further optimization is required to improve reinforcement efficiency and property consistency.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
- Ritchie, H.; Roser, M. Our World in Data. In Global Plastic Production Projections, 1950 to 2060; OECD: Paris, France, 2022; Available online: https://ourworldindata.org/grapher/global-plastic-production-projections (accessed on 25 January 2026).
- Geyer, R.; Jambeck, J.R.; Law, K.L. Production, use, and fate of all plastics ever made. Sci. Adv. 2017, 3, e1700782. [Google Scholar] [CrossRef]
- Santos, G.; Esmizadeh, E.; Riahinezhad, M. Recycling Construction, Renovation, and Demolition Plastic Waste: Review of the Status Quo, Challenges and Opportunities. J. Polym. Environ. 2023, 32, 479–509. [Google Scholar] [CrossRef]
- Lahtela, V.; Hyvärinen, M.; Kärki, T. Composition of Plastic Fractions in Waste Streams: Toward More Efficient Recycling and Utilization. Polymers 2019, 11, 69. [Google Scholar] [CrossRef]
- Westlie, A.H.; Chen, E.Y.X.; Holland, C.M.; Stahl, S.S.; Doyle, M.; Trenor, S.R.; Knauer, K.M. Polyolefin Innovations toward Circularity and Sustainable Alternatives. Macromol. Rapid Commun. 2022, 43, 2200492. [Google Scholar] [CrossRef]
- Ragaert, K.; Delva, L.; Van Geem, K. Mechanical and chemical recycling of solid plastic waste. Waste Manag. 2017, 69, 24–58. [Google Scholar] [CrossRef]
- Vera-Sorroche, J.; Kelly, A.L.; Brown, E.C.; Gough, T.; Abeykoon, C.; Coates, P.D.; Deng, J.; Li, K.; Harkin-Jones, E.; Price, M. The effect of melt viscosity on thermal efficiency for single screw extrusion of HDPE. Chem. Eng. Res. Des. 2014, 92, 2404–2412. [Google Scholar] [CrossRef]
- Jmal, H.; Bahlouli, N.; Wagner-Kocher, C.; Leray, D.; Ruch, F.; Munsch, J.N.; Nardin, M. Influence of the grade on the variability of the mechanical properties of polypropylene waste. Waste Manag. 2018, 75, 160–173. [Google Scholar] [CrossRef] [PubMed]
- Bahlouli, N.; Pessey, D.; Raveyre, C.; Guillet, J.; Ahzi, S.; Dahoun, A.; Hiver, J.M. Recycling effects on the rheological and thermomechanical properties of polypropylene-based composites. Mater. Des. 2012, 33, 451–458. [Google Scholar] [CrossRef]
- Strömberg, E.; Karlsson, S. The Design of a Test Protocol to Model the Degradation of Polyolefins During Recycling and Service Life. J. Appl. Polym. Sci. 2008, 112, 1835–1844. [Google Scholar] [CrossRef]
- Vidakis, N.; Petousis, M.; Maniadi, A. Sustainable Additive Manufacturing: Mechanical Response of High-Density Polyethylene over Multiple Recycling Processes. Recycling 2021, 6, 4. [Google Scholar] [CrossRef]
- Boldizar, A.; Jansson, A.; Gevert, T.; Möller, K. Simulated recycling of post-consumer high density polyethylene material. Polym. Degrad. Stab. 2000, 68, 317–319. [Google Scholar] [CrossRef]
- Vohlídal, J. Polymer degradation: A short review. Chem. Teach. Int. 2021, 3, 213–220. [Google Scholar] [CrossRef]
- Ragaert, K.; Hubo, S.; Delva, L.; Veelaert, L.; Du Bois, E. Upcycling of Contaminated Post-Industrial Polypropylene Waste: A Design from Recycling Case Study. Polym. Eng. Sci. 2018, 58, 528–534. [Google Scholar] [CrossRef]
- Burgada, F.; Arrieta, M.P.; Borrell, B.; Fenollar, O. Development of Eco-Efficient Composite from Textile Waste with Polyamide Matrix. Polymers 2024, 16, 2061. [Google Scholar] [CrossRef]
- Rashid, M.E.; Khan, M.R.; Haque, R.U.; Hasanuzzaman, M. Challenges of textile waste composite products and its prospects of recycling. J. Mater. Cycles Waste Manag. 2023, 25, 1267–1287. [Google Scholar] [CrossRef]
- Ben Amor, I.; Klinkova, O.; Baklouti, M.; Elleuch, R.; Tawfiq, I. Mechanical Recycling and Its Effects on the Physical and Mechanical Properties of Polyamides. Polymers 2023, 15, 4561. [Google Scholar] [CrossRef]
- Çelik, Y.; Shamsuyeva, M.; Endres, H.J. Thermal and Mechanical Properties of the Recycled and Virgin PET—Part I. Polymers 2022, 14, 1326. [Google Scholar] [CrossRef]
- Pławecka, K.; Przybyła, J.; Korniejenko, K.; Lin, W.-T.; Cheng, A.; Łach, M. Recycling of Mechanically Ground Wind Turbine Blades as Filler in Geopolymer Composite. Materials 2021, 14, 6539. [Google Scholar] [CrossRef]
- Spychala, M.J.; Latko-Durałek, P.; Miedzińska, D.; Salaśińska, K.; Cetnar, I.; Popławski, A.; Boczkowska, A. Structural and Mechanical Properties of Recycled HDPE with Milled GFRP as a Filler. Materials 2024, 17, 5875. [Google Scholar] [CrossRef]
- Cai, H.; Ye, J.; Wang, Y.; Shi, Y.; Saafi, M.; Ye, J. Microscopic failure characteristics and critical length of short glass fiber reinforced composites. Compos. Part B Eng. 2023, 266, 110973. [Google Scholar] [CrossRef]
- Cestari, S.P.; Martin, P.J.; Hanna, P.R.; Kearns, M.P.; Mendes, L.C.; Millar, B. Use of virgin/recycled polyethylene blends in rotational moulding. J. Polym. Eng. 2021, 41, 509–516. [Google Scholar] [CrossRef]
- Miyahara, R.Y.; Melquiades, F.L.; Ligowski, E.; Santos, A.; Fávaro, S.L.; Antunes Junior, O.R. Preparation and characterization of composites from plastic waste and sugar cane fiber. Polímeros 2018, 28, 147–154. [Google Scholar] [CrossRef]
- Nukala, S.G.; Kong, I.; Kakarla, A.B.; Kong, W.; Kong, W. Development of Wood Polymer Composites from Recycled Wood and Plastic Waste: Thermal and Mechanical Properties. J. Compos. Sci. 2022, 6, 194. [Google Scholar] [CrossRef]
- Chowdhury, M.A.; Hossain, S. A Review on Tensile and Flexural Properties of Fiber-Reinforced Polymer Composites. IOSR J. Polym. Text. Eng. 2020, 7, 16–26. [Google Scholar]
- Raju, A.; Shanmugaraja, M. Recent Researches in Fiber Reinforced Composite Materials: A Review. Mater. Today Proc. 2021, 46, 9291–9296. [Google Scholar] [CrossRef]
- ISO 178:2019; Plastics—Determination of Flexural Properties. International Organization for Standardization: Geneva, Switzerland, 2019.
- ISO 179-1:2023; Plastics—Determination of Charpy Impact Properties—Part 1: Non-Instrumented Impact Test. International Organization for Standardization: Geneva, Switzerland, 2023.
- Coates, J. Interpretation of Infrared Spectra, A Practical Approach. Encycl. Anal. Chem. 2000, 12, 10815–10837. [Google Scholar] [CrossRef]
- Thomason, J.L. The influence of fibre length and concentration on the properties of glass fibre reinforced polypropylene: 6. The properties of injection moulded long fibre PP at high fibre content. Compos. Part A Appl. Sci. Manuf. 2005, 36, 995–1003. [Google Scholar] [CrossRef]
- Thomason, J.L. The influence of fibre length and concentration on the properties of glass fibre reinforced polypropylene: 5. Injection moulded long and short fibre PP. Compos. Part A Appl. Sci. Manuf. 2002, 33, 1641–1652. [Google Scholar] [CrossRef]
- Pukánszky, B. Influence of interface interaction on the ultimate tensile properties of polymer composites. Composites 1990, 21, 255–262. [Google Scholar] [CrossRef]
- Shen, Y.; Apraku, S.E.; Zhu, Y. Recycling and recovery of fiber-reinforced polymer composites for end-of-life wind turbine blade management. Green Chem. 2023, 25, 9644–9658. [Google Scholar] [CrossRef]
- Spini, F.; Bettini, P. End-of-life wind turbine blades: Review on recycling strategies. Compos. B Eng. 2024, 275, 111290. [Google Scholar] [CrossRef]
- Thomason, J.L. Glass fibre sizing: A review. Compos. Part A Appl. Sci. Manuf. 2019, 127, 105619. [Google Scholar] [CrossRef]







| Sample ID | Matrix (wt.%) | Ground GFRP (wt%) |
|---|---|---|
| P0 | 100 | 0 |
| P10 | 90 | 10 |
| P20 | 80 | 20 |
| P30 | 70 | 30 |
| No. | Sample Designation | Polyamid | Thermoplastic Polyester | PE/HDPE | Fillers ** |
|---|---|---|---|---|---|
| 1. | P0 * | 25.22 | 21.81 | 16.48 | 36.49 |
| 2. | P1 | 29.15 | 20.89 | 13.98 | 35.98 |
| 3. | P2 | 28.00 | 22.00 | 17.99 | 32.01 |
| 4. | P3 | 25.80 | 20.45 | 16.60 | 37.15 |
| 5. | P4 | 26.89 | 21.99 | 18.70 | 32.42 |
| 6. | P5 | 20.50 | 20.17 | 18.80 | 40.53 |
| 7. | P6 | 24.70 | 21.79 | 12.63 | 40.88 |
| 8. | P7 | 25.64 | 19.86 | 15.67 | 38.83 |
| 9. | P8 | 22.75 | 26.45 | 19.12 | 31.68 |
| 10. | P9 | 23.56 | 22.69 | 14.83 | 38.92 |
| GFRP Content (wt.%) | Three-Point Bending | |||
|---|---|---|---|---|
| Flexural Strength Rg (MPa) | SD | N | ||
| 0 | 13.10 | 1.21 | 3 | |
| 10 | 11.90 | 0.27 | 9 | |
| 20 | 10.35 | 1.4 | 9 | |
| 30 | 11.37 | 2.14 | 9 | |
| Charpy Impact Test | |||
|---|---|---|---|
| Ground GFRP Content (wt.%) | Impact Strength an [kJ/m2] | SD | N |
| 0 | 7.30 | 0.20 | 3 |
| 10 | 8.03 | 0.74 | 9 |
| 20 | 8.46 | 0.55 | 9 |
| 30 | 8.10 | 0.46 | 9 |
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2026 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license.
Share and Cite
Wędrychowicz, M.; Papacz, W.; Walkowiak, J.; Kurowiak, J.; Siwczyk, B.; Skrzekut, T.; Noga, P.; Skarupska, D. Hot-Pressed Multicomponent Recycled Textile Polymer Blends Reinforced with Ground GFRP from Wind Turbine Blades: Microstructure–Property Relationships. Materials 2026, 19, 1306. https://doi.org/10.3390/ma19071306
Wędrychowicz M, Papacz W, Walkowiak J, Kurowiak J, Siwczyk B, Skrzekut T, Noga P, Skarupska D. Hot-Pressed Multicomponent Recycled Textile Polymer Blends Reinforced with Ground GFRP from Wind Turbine Blades: Microstructure–Property Relationships. Materials. 2026; 19(7):1306. https://doi.org/10.3390/ma19071306
Chicago/Turabian StyleWędrychowicz, Maciej, Władysław Papacz, Janusz Walkowiak, Jagoda Kurowiak, Bartosz Siwczyk, Tomasz Skrzekut, Piotr Noga, and Dominika Skarupska. 2026. "Hot-Pressed Multicomponent Recycled Textile Polymer Blends Reinforced with Ground GFRP from Wind Turbine Blades: Microstructure–Property Relationships" Materials 19, no. 7: 1306. https://doi.org/10.3390/ma19071306
APA StyleWędrychowicz, M., Papacz, W., Walkowiak, J., Kurowiak, J., Siwczyk, B., Skrzekut, T., Noga, P., & Skarupska, D. (2026). Hot-Pressed Multicomponent Recycled Textile Polymer Blends Reinforced with Ground GFRP from Wind Turbine Blades: Microstructure–Property Relationships. Materials, 19(7), 1306. https://doi.org/10.3390/ma19071306

