Piezoelectricity and Thermophysical Properties of Ba0.90Ca0.10Ti0.96Zr0.04O3 Ceramics Modified with Amphoteric Nd3+ and Y3+ Dopants
Abstract
:1. Introduction
2. Experimental Procedure
2.1. Preparation
2.2. Characterisation
3. Results and Discussion
3.1. Phases and Structures
3.2. Dielectric Properties
3.3. Activation Energy
3.4. Ferroelectricity
3.5. Piezoelectricity
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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x (mol%) | a (Å) | b (Å) | c (Å) | Axial Angle (o) | ρ (g/cm−3) | ρr (%) |
---|---|---|---|---|---|---|
0 | 4.013(3) | 4.013(3) | 4.013(3) | 89.05 | 5.491 | 95.54 |
0.06 | 4.015(1) | 4.015(1) | 4.015(1) | 88.96 | 5.517 | 96.00 |
0.12 | 4.018(2) | 4.018(2) | 4.018(2) | 88.89 | 5.536 | 96.34 |
0.18 | 4.022(0) | 4.022(0) | 4.022(0) | 88.85 | 5.541 | 96.42 |
0.24 | 4.017(8) | 4.017(8) | 4.017(8) | 88.97 | 5.533 | 96.27 |
0.30 | 4.014(7) | 4.014(7) | 4.014(7) | 89.01 | 5.529 | 96.10 |
x (mol%) | Ea (eV) | Tf (K) | f0 (×1021 Hz) |
---|---|---|---|
0 | 0.676 | 106.5 | 5.32 |
0.06 | 0.584 | 106.9 | 6.75 |
0.12 | 0.475 | 107.3 | 7.63 |
0.18 | 0.401 | 107.9 | 8.44 |
0.24 | 0.527 | 106.9 | 7.69 |
0.30 | 0.633 | 105.8 | 5.84 |
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Tian, Y.; Ma, M.; Li, S.; Dong, J.; Ji, X.; Wu, H.; Wang, J.; Jing, Q. Piezoelectricity and Thermophysical Properties of Ba0.90Ca0.10Ti0.96Zr0.04O3 Ceramics Modified with Amphoteric Nd3+ and Y3+ Dopants. Materials 2023, 16, 2369. https://doi.org/10.3390/ma16062369
Tian Y, Ma M, Li S, Dong J, Ji X, Wu H, Wang J, Jing Q. Piezoelectricity and Thermophysical Properties of Ba0.90Ca0.10Ti0.96Zr0.04O3 Ceramics Modified with Amphoteric Nd3+ and Y3+ Dopants. Materials. 2023; 16(6):2369. https://doi.org/10.3390/ma16062369
Chicago/Turabian StyleTian, Yongshang, Mingyang Ma, Shuiyun Li, Junli Dong, Xiang Ji, Haitao Wu, Jinshuang Wang, and Qiangshan Jing. 2023. "Piezoelectricity and Thermophysical Properties of Ba0.90Ca0.10Ti0.96Zr0.04O3 Ceramics Modified with Amphoteric Nd3+ and Y3+ Dopants" Materials 16, no. 6: 2369. https://doi.org/10.3390/ma16062369