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Volume 16
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10.3390/ma16051876
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Review

Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials

by
Marzena Białek
and
Krystyna Czaja
*
Institute of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland
*
Author to whom correspondence should be addressed.
Materials 2023, 16(5), 1876; https://doi.org/10.3390/ma16051876
Submission received: 30 December 2022 / Revised: 20 February 2023 / Accepted: 21 February 2023 / Published: 24 February 2023
(This article belongs to the Special Issue Silsesquioxanes—Precursors to Functional Materials: Synthesis and Applications—a Themed Issue to Honor Professor Bogdan Marciniec on the Occasion of His 80th Birthday)
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Abstract

This paper is a review of studies on the use of the polyhedral oligomeric silsesquioxanes (POSS) of various structures in the synthesis of polyolefins and the modification of their properties, namely: (1) components of organometallic catalytic systems for the polymerization of olefins, (2) comonomers in the copolymerization with ethylene, and (3) fillers in composites based on polyolefins. In addition, studies on the use of new silicon compounds, i.e., siloxane–silsesquioxane resins, as fillers for composites based on polyolefins are presented. The authors dedicate this paper to Professor Bogdan Marciniec on the occasion of his jubilee.
Keywords: polyolefins; olefin; POSS; polymerization; copolymerization; POSS-comonomer; catalyst; transition metal–silsesquioxane complex; composite; siloxane–silsesquioxane resin polyolefins; olefin; POSS; polymerization; copolymerization; POSS-comonomer; catalyst; transition metal–silsesquioxane complex; composite; siloxane–silsesquioxane resin
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MDPI and ACS Style

Białek, M.; Czaja, K. Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials. Materials 2023, 16, 1876. https://doi.org/10.3390/ma16051876

AMA Style

Białek M, Czaja K. Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials. Materials. 2023; 16(5):1876. https://doi.org/10.3390/ma16051876

Chicago/Turabian Style

Białek, Marzena, and Krystyna Czaja. 2023. "Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials" Materials 16, no. 5: 1876. https://doi.org/10.3390/ma16051876

APA Style

Białek, M., & Czaja, K. (2023). Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials. Materials, 16(5), 1876. https://doi.org/10.3390/ma16051876

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