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Article

The Spontaneous Escape Behavior of Silver from Graphite-like Carbon Coatings and Its Effect on Corrosion Resistance

1
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211800, China
2
Instituto de Nanociencia y Materiales de Aragón (CSIC-Universidad de Zaragoza), 50018 Zaragoza, Spain
*
Author to whom correspondence should be addressed.
Materials 2023, 16(11), 3909; https://doi.org/10.3390/ma16113909
Submission received: 5 May 2023 / Revised: 20 May 2023 / Accepted: 22 May 2023 / Published: 23 May 2023

Abstract

Silver-doped graphite-like carbon (Ag-GLC) coatings were prepared on the surface of aluminum alloy and single-crystal silicon by magnetron sputtering under different deposition parameters. The effects of silver target current and deposition temperature, as well as of the addition of CH4 gas flow, on the spontaneous escape behavior of silver from the GLC coatings were investigated. Furthermore, the corrosion resistance of the Ag-GLC coatings were evaluated. The results showed that the spontaneous escape phenomenon of silver could take place at the GLC coating, regardless of preparation condition. These three preparation factors all had an influence on the size, number and distribution of the escaped silver particles. However, in contrast with the silver target current and the addition of CH4 gas flow, only the change in deposition temperature had a significant positive effect on the corrosion resistance of the Ag-GLC coatings. The Ag-GLC coating showed the best corrosion resistance when the deposition temperature was 500 °C, which was due to the fact that increasing the deposition temperature effectively reduced the number of silver particles escaping from the Ag-GLC coating.
Keywords: graphite-like carbon coating; spontaneous escape; silver particles; deposition temperature graphite-like carbon coating; spontaneous escape; silver particles; deposition temperature

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MDPI and ACS Style

Li, D.; Wang, W.; Liu, C.; Angurel, L.A.; de la Fuente, G.F.; Jiang, B. The Spontaneous Escape Behavior of Silver from Graphite-like Carbon Coatings and Its Effect on Corrosion Resistance. Materials 2023, 16, 3909. https://doi.org/10.3390/ma16113909

AMA Style

Li D, Wang W, Liu C, Angurel LA, de la Fuente GF, Jiang B. The Spontaneous Escape Behavior of Silver from Graphite-like Carbon Coatings and Its Effect on Corrosion Resistance. Materials. 2023; 16(11):3909. https://doi.org/10.3390/ma16113909

Chicago/Turabian Style

Li, Deye, Wenqiang Wang, Cancan Liu, Luis Alberto Angurel, Germán F. de la Fuente, and Bailing Jiang. 2023. "The Spontaneous Escape Behavior of Silver from Graphite-like Carbon Coatings and Its Effect on Corrosion Resistance" Materials 16, no. 11: 3909. https://doi.org/10.3390/ma16113909

APA Style

Li, D., Wang, W., Liu, C., Angurel, L. A., de la Fuente, G. F., & Jiang, B. (2023). The Spontaneous Escape Behavior of Silver from Graphite-like Carbon Coatings and Its Effect on Corrosion Resistance. Materials, 16(11), 3909. https://doi.org/10.3390/ma16113909

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