Influence of Bath Hydrodynamics on the Micromechanical Properties of Electrodeposited Nickel-Cobalt Alloys
Abstract
:1. Introduction
2. Materials and Methods
2.1. Electrochemical Deposition Experimental Setup
2.2. Material Characterization
3. Modelling of Electrolyte Vortex Flow Created by Magnetic Stirring and Determination of Optimum Electrode Position within the Vortex
3.1. Simulation of the Electrolyte Vortex Flow Created by Magnetic Stirrer
3.2. Measurement of Electrolyte Vortex Velocity
3.3. Determination of an Optimum Electrode Position in the Electrolyte Vortex Flow
4. Results and Discussion
4.1. Chronopotentiometric Electrodeposition
4.2. Degree of Anomaly as a Function of Varying BHD Conditions
4.3. SEM and AFM Surface Morphology Characterization
4.4. X-ray Diffractograms, Growth Phase and Grain Size
4.5. Microhardness Characterization of eNi and eNiCo Alloy Samples
5. Model for the Influence of BHD on Nucleation, Growth Kinetics and Micromechanical Properties
5.1. Electrochemical Effects of BHD on Nucleation and Growth Kinetics during ECD
5.2. Physical Effects of BHD on Nucleation and Growth Kinetics during ECD
6. Conclusions
- The convective velocity profile within the vortex created by magnetic stirrer has an inhomogeneous nature across the electrolytic cell, wherein the electrolytic flow region with a minimum variation occurs near the boundary of the electrolytic cell;
- The degree of anomaly dA, in the case of electrodeposited nickel-cobalt alloys, increased initially strongly as a function of increasing bath hydrodynamic velocity, i.e., from dA = 7.5 to dA = 15.7 for an increment in BHD velocity from 0 to 26 cm/s, and it only gradually increased from dA 15.7 to 17.2 for bath hydrodynamics beyond the critical velocity up to investigated maximum velocity of 42 cm/s. This finding is also a proof that the chosen BHD provides, by magnetic stirring, a suitable range of velocities to investigate the influence of BHD;
- The surface morphology of electrodeposited nickel-cobalt alloy and nickel coating samples changed from granular to more planar as a function of increasing bath hydrodynamic velocity, indicating the electrodeposition of fine grained and compact coatings;
- The AFM micrographs showed that the average surface roughness and the fractal dimension values decreased with increasing bath hydrodynamic velocity, i.e., it decreased from 207 nm (FD = 2.97) to 11 nm (FD = 2.15), and from 181 nm (FD = 2.91) to 33 nm (FD = 2.2) on increasing the velocity from 0 to 42 cm/s for nickel-cobalt and nickel coatings, respectively;
- The X-ray diffraction characterization of electrodeposited nickel-cobalt alloys and nickel coating samples revealed, firstly, the fcc nature of the coatings, and secondly, showed a peak broadening of the diffractograms as a function of increasing bath hydrodynamic velocity;
- The computed grain size using the Debye–Scherrer relation from the diffractograms decreased from 31 nm to 12 nm, and 69 nm to 26 nm as function of increasing bath hydrodynamic velocity (up to 42 cm/s) for nickel-cobalt and nickel coating samples, respectively;
- Consecutively, the microhardness increased by 43% (i.e., from 393 HV0.01 to 692 HV0.01), and by 33% (from 255 HV0.01 to 381 HV0.01) on increasing the convective velocity from 0 to 42 cm/s for nickel-cobalt and nickel coating samples, respectively, which fits well with the Hall–Petch relationship.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Electrolyte Constituents and ECD Operating Conditions | |
---|---|
Ni(NH2SO3)2.6H2O | 1.8 (mol/L) |
Co(NH2SO3)2.6H2O | 0.03 (mol/L) |
H3BO3 | 0.5 (mol/L) |
Deionized H2O | 14 (mol/L) |
Bath pH value | 4 |
Temperature | 45 ± 2 °C |
Current Density | 50 mA/cm2 |
Sample | v (cm/s) | EWE (V) | t (µm) | CoA (wt%) | dA | Ra (nm) | FD | XRD FWHM (2θ°) | d (nm) | H (HV0.01) |
---|---|---|---|---|---|---|---|---|---|---|
eNiCo alloy coatings | 0 | −0.89 ± 0.016 | 13.5 ± 0.9 | 15.1 | 7.5 | 207.5 ± 9.8 | 2.97 | 0.29 | 31.83 | 393 ± 12 |
8.8 | −0.76 ± 0.004 | 13.6 ± 1.1 | 21.6 | 10.8 | 197 ± 7 | 2.89 | 0.37 | 24.95 | 462 ± 18 | |
18 | −0.66 ± 0.005 | 12.4 ± 0.8 | 27.8 | 13.9 | 138.6 ± 8.5 | 2.77 | 0.66 | 13.98 | 570 ± 11.5 | |
26 | −0.61 ± 0.013 | 12.8 ± 1.3 | 31.4 | 15.7 | 31.3 ± 6.7 | 2.65 | 0.68 | 13.57 | 600 ± 17.8 | |
34 | −0.59 ± 0.010 | 12.6 ± 1.4 | 31.3 | 15.6 | 23.9 ± 3.9 | 2.21 | 0.66 | 13.98 | 613 ± 9.7 | |
42 | −0.57 ± 0.006 | 12.8 ± 1.4 | 34.4 | 17.2 | 11.1 ± 1.65 | 2.15 | 0.76 | 12.14 | 692 ± 21 | |
eNi coatings | 0 | −1.27 ± 0.016 | 44.8 ± 0.9 | - | - | 181.7 ± 8.7 | 2.91 | 0.13 | 68.95 | 255 ± 13.8 |
12 | −1.08 ± 0.02 | 42.2 ± 1.1 | - | - | 157.5 ± 7.7 | 2.68 | 0.18 | 50.21 | 287 ± 17 | |
22 | −1.05 ± 0.02 | 42.7 ± 1.3 | - | - | 114 ± 6.9 | 2.54 | 0.28 | 31.42 | 315 ± 22 | |
32 | −0.93 ± 0.016 | 41.4 ± 0.8 | - | - | 51 ± 7.4 | 2.4 | 0.29 | 31.19 | 325 ± 17.8 | |
42 | −0.92 ± 0.01 | 42.6 ± 0.8 | - | - | 33.4 ± 1.9 | 2.2 | 0.34 | 26.19 | 381 ± 4.7 |
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Khazi, I.; Mescheder, U.; Wilde, J. Influence of Bath Hydrodynamics on the Micromechanical Properties of Electrodeposited Nickel-Cobalt Alloys. Materials 2021, 14, 3898. https://doi.org/10.3390/ma14143898
Khazi I, Mescheder U, Wilde J. Influence of Bath Hydrodynamics on the Micromechanical Properties of Electrodeposited Nickel-Cobalt Alloys. Materials. 2021; 14(14):3898. https://doi.org/10.3390/ma14143898
Chicago/Turabian StyleKhazi, Isman, Ulrich Mescheder, and Jürgen Wilde. 2021. "Influence of Bath Hydrodynamics on the Micromechanical Properties of Electrodeposited Nickel-Cobalt Alloys" Materials 14, no. 14: 3898. https://doi.org/10.3390/ma14143898