Copper-Doped Cobalt Spinel Electrocatalysts Supported on Activated Carbon for Hydrogen Evolution Reaction
Abstract
:1. Introduction
2. Experimental
2.1. Materials and Reagents
2.2. Synthesis Procedure
2.3. Characterization Techniques
2.4. Electrochemical Measurements
3. Results and Discussion
3.1. Structural and Morphological Characterization
3.2. Surface Analysis
3.3. Textural Characterization of As-prepared Materials
3.4. Electrochemical Characterization and Catalytic Activity Towards HER
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | a (Å) ICDD Cards | a (Å) | V (Å3) | dc (nm) |
---|---|---|---|---|
Co3O4 | 8.09 | 8.10 | 532.72 | 13 |
CuCo2O4 | 8.06 | 8.07 | 526.47 | 14 |
Sample | Co 2p (eV) | Cu 2p (eV) | Surface Atomic Composition (at.%) | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
2p3/2 | 2p1/2 | Sat. 1 | Sat. 2 | 2p3/2 | 2p1/2 | Sat. | Isat/Imain | Co | Cu | Cu/Co | |
Co3O4 | 780.2 | 795.2 | 789.4 | 785 | – | – | – | – | 5.1 | – | – |
CuCo2O4 | 779.9 | 794.9 | 789.4 | 785.6 | 934.9 | 954.9 | 942.4 | 0.50 | 3.9 | 1.7 | 0.44 |
Sample | SBET (m2 g−1) | VDR N2 (cm3 g−1) | VDR CO2 (cm3 g−1) | C (F g−1) |
---|---|---|---|---|
AC | 3310 | 1.30 | 0.76 | 262 |
Co3O4 | 112 [32] | – | – | 1 |
CuCo2O4 | 42 [40] | – | – | 2 |
AC-Co5 | 2810 | 1.21 | 0.52 | 261 |
AC-Co10 | 2780 | 1.16 | 0.43 | 247 |
AC-Co20 | 2460 | 1.03 | 0.37 | 154 |
AC-CuCo5 | 2910 | 1.20 | 0.51 | 188 |
AC-CuCo10 | 2780 | 1.15 | 0.51 | 178 |
AC-CuCo20 | 2220 | 0.92 | 0.40 | 174 |
Sample | Tafel Slope (mV/dec) | Current (A·g−1) at −0.4 V vs. RHE | Current (A·cm−2) at −0.4 vs. RHE |
---|---|---|---|
AC | 416 | −1.65 | −9.5 |
Co3O4 | 132 | −0.75 | −5.2 |
CuCo2O4 | 124 | −0.15 | −1.0 |
AC-Co5 | 574 | −1.60 | −11.4 |
AC-Co10 | 457 | −2.10 | −12.8 |
AC-Co20 | 438 | −1.45 | −9.3 |
AC-CuCo5 | 454 | −1.30 | −8.1 |
AC-CuCo10 | 347 | −2.15 | −13.8 |
AC-CuCo20 | 300 | −2.85 | −14.6 |
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Flores-Lasluisa, J.X.; Quílez-Bermejo, J.; Ramírez-Pérez, A.C.; Huerta, F.; Cazorla-Amorós, D.; Morallón, E. Copper-Doped Cobalt Spinel Electrocatalysts Supported on Activated Carbon for Hydrogen Evolution Reaction. Materials 2019, 12, 1302. https://doi.org/10.3390/ma12081302
Flores-Lasluisa JX, Quílez-Bermejo J, Ramírez-Pérez AC, Huerta F, Cazorla-Amorós D, Morallón E. Copper-Doped Cobalt Spinel Electrocatalysts Supported on Activated Carbon for Hydrogen Evolution Reaction. Materials. 2019; 12(8):1302. https://doi.org/10.3390/ma12081302
Chicago/Turabian StyleFlores-Lasluisa, Jhony Xavier, Javier Quílez-Bermejo, Ana Cristina Ramírez-Pérez, Francisco Huerta, Diego Cazorla-Amorós, and Emilia Morallón. 2019. "Copper-Doped Cobalt Spinel Electrocatalysts Supported on Activated Carbon for Hydrogen Evolution Reaction" Materials 12, no. 8: 1302. https://doi.org/10.3390/ma12081302