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Materials 2018, 11(9), 1723; https://doi.org/10.3390/ma11091723

Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions

Faculty of Natural Sciences II, Martin Luther University Halle-Wittenberg, D-06099 Halle (Saale), Germany
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Received: 23 August 2018 / Revised: 7 September 2018 / Accepted: 11 September 2018 / Published: 14 September 2018
(This article belongs to the Section Materials Physics)
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Abstract

1,2,3-Triazolium salts are an important class of materials with a plethora of sophisticated applications. A series of three novel 1,3-dimethyl-1,2,3-triazolium salts with fluorine, containing anions of various size, is synthesized by methylation of 1,2,3-triazole. Their ion conductivity is measured by impedance spectroscopy, and the corresponding ionicities are determined by diffusion coefficients obtained from 1H and 19F pulsed field gradient nuclear magnetic resonance (PFG NMR) spectroscopy data, revealing that the anion strongly influences their ion conductive properties. Since the molar ion conductivities and ionicities of the 1,3-dimethyl-1,2,3-triazolium salts are enhanced in comparison to other 1,2,3-triazolium salts with longer alkyl substituents, they are promising candidates for applications as electrolytes in electrochemical devices. View Full-Text
Keywords: 1,2,3-triazolium salts; ionic liquids; ionicity; impedance spectroscopy; ion conductivity; diffusion coefficients; viscosity 1,2,3-triazolium salts; ionic liquids; ionicity; impedance spectroscopy; ion conductivity; diffusion coefficients; viscosity
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Pulst, M.; Golitsyn, Y.; Reichert, D.; Kressler, J. Ion Transport Properties and Ionicity of 1,3-Dimethyl-1,2,3-Triazolium Salts with Fluorinated Anions. Materials 2018, 11, 1723.

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