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Correlation of Structure, Tunable Colors, and Lifetimes of (Sr, Ca, Ba)Al2O4:Eu2+, Dy3+ Phosphors

School of Applied Physics and Materials, Wuyi University, Jiangmen 529020, China
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
Authors to whom correspondence should be addressed.
Materials 2017, 10(10), 1198;
Received: 15 September 2017 / Revised: 11 October 2017 / Accepted: 16 October 2017 / Published: 18 October 2017
PDF [6803 KB, uploaded 19 October 2017]


(Sr, Ca, Ba)Al2O4:Eu2+, Dy3+ phosphors were prepared via a high temperature solid-state reaction method. The correlation of phase structure, optical properties and lifetimes of the phosphors are investigated in this work. For the (Sr, Ca)Al2O4:Eu2+,Dy3+ phosphors, the different phase formation from monoclinic SrAl2O4 phase to hexagonal SrAl2O4 phase to monoclinic CaAl2O4 phase was observed when the Ca content increased. The emission color of SrAl2O4:Eu2+, Dy3+ phosphors varied from green to blue. For the (Sr, Ba)Al2O4:Eu2+, Dy3+ phosphors, different phase formation from the monoclinic SrAl2O4 phase to the hexagonal BaAl2O4 phase was observed, along with a shift of emission wavelength from 520 nm to 500 nm. More interestingly, the decay time of SrAl2O4:Eu2+, Dy3+changed due to the different phase formations. Lifetime can be dramatically shortened by the substitution of Sr2+ with Ba2+ cations, resulting in improving the performance of the alternating current light emitting diode (AC-LED). Finally, intense LEDs are successfully obtained by combining these phosphors with Ga(In)N near UV chips. View Full-Text
Keywords: phosphors; solid solution; average lifetime; AC-LEDs; photoluminescence phosphors; solid solution; average lifetime; AC-LEDs; photoluminescence

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Xie, Q.; Li, B.; He, X.; Zhang, M.; Chen, Y.; Zeng, Q. Correlation of Structure, Tunable Colors, and Lifetimes of (Sr, Ca, Ba)Al2O4:Eu2+, Dy3+ Phosphors. Materials 2017, 10, 1198.

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