From Legacy Gas Fields to Hydrogen Storage: 3D Seismic-Driven Geological Modelling and Dynamic Simulation in the Northern Upper Rhine Graben
Abstract
1. Introduction
2. Geology and Operational History of the Study Area
3. Methodology and Database
3.1. Methodology
3.2. Database
3.3. Structural Model
3.4. Dynamic Model for History Match of Production and UGS Phase
3.5. Dynamic Model for Hypothetical UHS Phase
4. Results
4.1. Seismic Interpretation and Structural Model
4.2. Dynamic Simulation
4.3. Hypothetical UHS Simulation
4.4. Analogue-Based Volumetric Screening
5. Discussion of Model Uncertainties
6. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
| URG | Upper Rhine Graben |
| UHS | Underground hydrogen storage |
| UGS | Underground gas storage |
| WG | Working gas |
| CG | Cushion gas |
| JTI | Jungtertiär I/Upper Tertiary I |
| JTII | Jungtertiär II/Upper Tertiary II |
| OHY | Obere Hydrobienschichten/Upper Hydrobia Beds |
| MMm3 | Million cubic meters |
| HLNUG | Hessisches Landesamt für Naturschutz, Umwelt und Geologie |
| LBEG | Landesamt für Bergbau, Energie und Geologie |
| VM | Volume multiplier |
References
- Al-Shafi, M.; Massarweh, O.; Abushaikha, A.S.; Bicer, Y. A review on underground gas storage systems: Natural gas, hydrogen and carbon sequestration. Energy Rep. 2023, 9, 6251–6266. [Google Scholar] [CrossRef] [Scilit]
- Katz, D.L.; Lee, R.L. Natural Gas Engineering: Production and Storage. 1993. Available online: https://journals.flvc.org/cee/article/view/123795 (accessed on 13 January 2026).
- Evans, D.J.; Chadwick, R.A. Underground Gas Storage: Worldwide Experiences and Future Development in the UK and Europe. 2009. Available online: https://www.semanticscholar.org/paper/Underground-gas-storage-%3A-worldwide-experiences-and-Evans-Chadwick/faa31e2fa4929f5c7c638cc243126d4acabfa2a2 (accessed on 13 January 2026).
- Małachowska, A.; Łukasik, N.; Mioduska, J.; Gębicki, J. Hydrogen Storage in Geological Formations—The Potential of Salt Caverns. Energies 2022, 15, 5038. [Google Scholar] [CrossRef] [Scilit]
- Underground Sun Storage—Contact—Project. Available online: https://www.underground-sun-storage.at/en/project/contact.html (accessed on 16 July 2023).
- Hychico. Available online: https://hychico.com.ar/en/underground-hydrogen-storage-3/ (accessed on 7 March 2023).
- Berrezueta, E.; Kovács, T.; Herrera-Franco, G.; Caicedo-Potosí, J.; Jaya-Montalvo, M.; Ordóñez-Casado, B.; Carrión-Mero, P.; Carneiro, J. Laboratory Studies on Underground H2 Storage: Bibliometric Analysis and Review of Current Knowledge. Appl. Sci. 2024, 14, 11286. [Google Scholar] [CrossRef] [Scilit]
- H2-Ökosystem—TH2ECO. Available online: https://www.th2eco.de/ (accessed on 19 March 2026).
- Heinemann, N.; Alcalde, J.; Miocic, J.M.; Hangx, S.J.; Kallmeyer, J.; Ostertag-Henning, C.; Hassanpouryouzband, A.; Thaysen, E.M.; Strobel, G.J.; Schmidt-Hattenberger, C.; et al. Enabling large-scale hydrogen storage in porous media—The scientific challenges. Energy Environ. Sci. 2021, 14, 853–864. [Google Scholar] [CrossRef] [Scilit]
- HyStorage. Available online: https://www.uniper.energy/hystorage (accessed on 19 March 2026).
- Manoorkar, S.; Pakkaner, G.K.; Omar, H.; Barbaix, S.; Ceursters, D.; Latinis, M.; Van Offenwert, S.; Bultreys, T. Pore-scale imaging of hydrogen and methane storage in fractured aquifer rock: The impact of gas type on relative permeability. Adv. Water Resour. 2025, 206, 105109. [Google Scholar] [CrossRef] [Scilit]
- Amez, I.; Gonzalez, S.; Sanchez-Martin, L.; Ortega, M.F.; Llamas, B. 5—Underground methanation, a natural way to transform carbon dioxide into methane. In Climate Change Science: Causes, Effects and Solutions for Global Warming; Stagner, D.T.a.J., Stagner, J.A., Ting, D.K., Eds.; Elsevier: Amsterdam, The Netherlands, 2021; pp. 81–106. Available online: https://www.sciencedirect.com/science/article/pii/B9780128237670000057 (accessed on 15 May 2023).
- Yekta, A.E.; Manceau, J.-C.; Gaboreau, S.; Pichavant, M.; Audigane, P. Determination of Hydrogen–Water Relative Permeability and Capillary Pressure in Sandstone: Application to Underground Hydrogen Injection in Sedimentary Formations. Transp. Porous Media 2018, 122, 333–356. [Google Scholar] [CrossRef] [Scilit]
- Heinemann, N.; Wilkinson, M.; Adie, K.; Edlmann, K.; Thaysen, E.M.; Hassanpouryouzband, A.; Haszeldine, R.S. Cushion Gas in Hydrogen Storage—A Costly CAPEX or a Valuable Resource for Energy Crises? Hydrogen 2022, 3, 550–563. [Google Scholar] [CrossRef] [Scilit]
- Lysyy, M.; Ersland, G.; Fernø, M. Pore-scale dynamics for underground porous media hydrogen storage. Adv. Water Resour. 2022, 163, 104167. [Google Scholar] [CrossRef] [Scilit]
- Khan, M.I.; Machado, M.V.B.; Khanal, A.; Delshad, M. Evaluating capillary trapping in underground hydrogen storage: A pore-scale to reservoir-scale analysis. Fuel 2024, 376, 132755. [Google Scholar] [CrossRef] [Scilit]
- Panfilov, M. Underground Storage of Hydrogen: In Situ Self-Organisation and Methane Generation. Transp. Porous Media 2010, 85, 841–865. [Google Scholar] [CrossRef] [Scilit]
- Rhouma, S.B.; Chabab, S.; Broseta, D. Synergies of storing hydrogen at the crest of CO2 or other gas storage. Greenh. Gases 2024, 14, 587–606. [Google Scholar] [CrossRef] [Scilit]
- Basniev, K.S.; Omelchenko, R.J.; Adzynova, F.A. Underground Hydrogen Storage Problems in Russia. 2010. Available online: https://www.researchgate.net/publication/48693440_Underground_Hydrogen_Storage_Problems_in_Russia (accessed on 10 November 2022).
- Hashemi, L.; Boon, M.; Glerum, W.; Farajzadeh, R.; Hajibeygi, H. A comparative study for H2–CH4 mixture wettability in sandstone porous rocks relevant to underground hydrogen storage. Adv. Water Resour. 2022, 163, 104165. [Google Scholar] [CrossRef] [Scilit]
- Zhong, L.; Baek, S.; Guo, M.; Bagwell, C.; Huerta, N. Hydrogen, Methane, Brine Flow Behavior, and Saturation in Sandstone Cores During H2 and CH4 Injection and Displacement. Energies 2024, 17, 5800. [Google Scholar] [CrossRef] [Scilit]
- Panfilov, M. 4—Underground and pipeline hydrogen storage. In Compendium of Hydrogen Energy: Hydrogen Storage, Transportation and Infrastructure Volume 2: Hydrogen Storage, Distribution and Infrastructure; Gupta, R.B., Basile, A., Veziroğlu, T.N., Eds.; Woodhead Publishing Series in Energy; Elsevier Science & Technology: Amsterdam, The Netherlands, 2015; pp. 91–115. Available online: https://www.sciencedirect.com/science/article/pii/B9781782423621000043 (accessed on 20 November 2022).
- Ahlrichs, N.; Noack, V.; Hübscher, C.; Seidel, E.; Warwel, A.; Kley, J. Impact of Late Cretaceous inversion and Cenozoic extension on salt structure growth in the Baltic sector of the North German Basin. Basin Res. 2022, 34, 220–250. [Google Scholar] [CrossRef] [Scilit]
- Pollok, L.; Henneberg, M. Sub-areas in steep rock salt formations—What do we know about the geological composition of North German salt structures? Saf. Nucl. Waste Dispos. 2021, 1, 73–74. [Google Scholar] [CrossRef] [Scilit]
- Scholze, F.; Wang, X.; Kirscher, U.; Kraft, J.; Schneider, J.W.; Götz, A.E.; Joachimski, M.M.; Bachtadse, V. A multistratigraphic approach to pinpoint the Permian-Triassic boundary in continental deposits: The Zechstein–Lower Buntsandstein transition in Germany. Glob. Planet. Change 2017, 152, 129–151. [Google Scholar] [CrossRef] [Scilit]
- Ziegler, P.A.; Dèzes, P. Evolution of the lithosphere in the area of the Rhine Rift System. Int. J. Earth Sci. 2005, 94, 594–614. [Google Scholar] [CrossRef] [Scilit]
- Dèzes, P.; Schmid, S.M.; Ziegler, P.A. Evolution of the European Cenozoic Rift System: Interaction of the Alpine and Pyrenean orogens with their foreland lithosphere. Tectonophysics 2004, 389, 1–33. [Google Scholar] [CrossRef] [Scilit]
- Reinhold, C.; Schwarz, M.; Perner, M. The Northern Upper Rhine Graben: Re-dawn of a mature petroleum province? Swiss Bull. 2016, 21, 35–56. [Google Scholar] [CrossRef]
- Plein, E. Die Erdgasspeicher Hähnlein/Stockstadt (Exkursion H am 24. April 1992). Jahresber. Mitteilungen Oberrheinischen Geol. Ver. 1992, 74, 73–84. [Google Scholar] [CrossRef] [Scilit]
- Straub, E.W. Die Erdöl-und Erdgaslagerstätten in Hessen und Rheinhessen. Abh. Geol. Landesamtes Baden-Württ. 1962, 4, 123–136. [Google Scholar]
- Horáková, M.; Bujok, P.; Klempa, M.; Kunz, A.; Křístek, M.; Vašek, M. Safety of UGS Operation in Terms of the Importance of Primary Factors of Tightness of Structures. Geosci. Eng. 2020, 66, 136–149. [Google Scholar] [CrossRef] [Scilit]
- Veit, E. Die Tiefbohrungen bei Pfungstadt und der Bau des Rheintalgrabens im Raum um Darmstadt. Z. Dtsch. Geol. Ges. 1953, 105, 150–151. [Google Scholar]
- Landesamt für Bergbau, Energie und Geologie. Die Erdgasförderung in Deutshland von 1949 bis 2025. Available online: https://www.lbeg.niedersachsen.de/download/72476/Erdgasfoerderung_1949-2025.pdf (accessed on 13 August 2026).
- Boigk, H. Erdöl und Erdölgas in der Bundesrepublik Deutschland. Erdölprovinzen, Felder, Förderung, Vorräte, Lagerstättentechnik; Enke: Stuttgart, Germany, 1981. [Google Scholar]
- Roy, S.; Mair, J.; Tanner, D.C.; Djahansouzi, A.; Henk, A. Movement history of faults under variable stress fields—Insights derived from 3D seismics in the central northern Upper Rhine Graben, Germany. EGUsphere 2026, 1–25. [Google Scholar] [CrossRef] [Scilit]
- Sainz-Garcia, A.; Abarca, E.; Rubi, V.; Grandia, F. Assessment of feasible strategies for seasonal underground hydrogen storage in a saline aquifer. Int. J. Hydrogen Energy 2017, 42, 16657–16666. [Google Scholar] [CrossRef] [Scilit]
- Hassanpouryouzband, A.; Joonaki, E.; Edlmann, K.; Haszeldine, R.S. Offshore Geological Storage of Hydrogen: Is This Our Best Option to Achieve Net-Zero? ACS Energy Lett. 2021, 6, 2181–2186. [Google Scholar] [CrossRef] [Scilit]












| Exploration Phases | Gas Field | Year of Discovery | End of Production | No. of Producers | Production [MMm3] | Reservoirs |
|---|---|---|---|---|---|---|
| 2nd Phase | Wolfskehlen | 1951 | 1989 | 21 | 206.702 | Tertiary |
| * Subfield Büttelborn | 1956 | Tertiary | ||||
| * Subfield Dornheim | 1957 | Tertiary | ||||
| Pfungstadt | 1952 | 1975 | 8 | 161.160 | Tertiary | |
| Stockstadt | 1953 | 1980 | 26 | 524.934 | Tertiary | |
| Eich | 1955 | 1973 | 7 | 117.834 | Tertiary | |
| Frankenthal | 1959 | 1961 | 5 | 20.093 | Tertiary | |
| 3rd Phase | Darmstadt-SW | 1981 | 1986 | 1 | 9.745 | Tertiary |
| Cumulative production [MMm3] | 1040.468 | |||||
| Full Name/Unit | Stratigraphic Markers (Drilling Reports) | Markers (Seismic Interpretation) |
|---|---|---|
| Quaternary | kz | QTR |
| QTR + JTII | ||
| Upper Tertiary I | tmiuJI | JTI Top |
| JTI | ||
| Upper Hydrobia Beds | tmiuHyo | OHY Top |
| OHY | ||
| Lower Hydrobia Beds | tmiuHyu | UHY Top |
| UHY | ||
| Corbicula/Inflata Beds | tmiuCo/In | CBS Top |
| CBS | ||
| Coloured Niederrödern Beds | tolu/oloN | BNS Top |
| BNS | ||
| Rupelton | toluB | RT Top |
| Pechelbronn Fm | ||
| Rotliegend | r | Tertiary Base |
| Rotliegend | ||
| Palaeozoic Basement | pzOKBE | Basement Top |
| Parameter | UGS Stockstadt | UGS Hähnlein |
|---|---|---|
| Total gas volume (106 m3) | 263 | 153 |
| Working gas (WG) volume (106 m3) | 135 | 80 |
| Cushion gas (CG) volume (106 m3) | 128 | 73 |
| Maximum reservoir pressure (kPa) | 6200 (Sand 7)/5500 (Sand 8) | 5400 (Sand 8) |
| Minimum reservoir pressure (kPa) | 2500 (Sand 7)/2500 (Sand 8) | 2500 (Sand 8) |
| Reservoir | NRV (106 m3) | Structural Model GIIP (106 m3) | Dynamic Model GIIP (106 m3) | Difference (%) |
|---|---|---|---|---|
| Stockstadt Gas field | 194.0 | 970 | 1070 | 10 |
| Stockstadt UGS (Sand 7) | 23.5 | 118 | 132 | 12 |
| Stockstadt UGS (Sand 8) | 28.0 | – | – | – |
| Hähnlein UGS (Sand 8) | 32.2 | – | – | – |
| Case X | Case Y | |||||||
|---|---|---|---|---|---|---|---|---|
| Cycle no. | Cum. Inj (H2 + CH4) (106 m3) | Cum. with (H2 + CH4) (106 m3) | Avg. Prod. H2 Mol. Frac. | Cum Wat. Prod. (103 m3) | Cum. Inj (H2) (106 m3) | Cum. with (H2) (106 m3) | Avg. Prod. H2 Mol. Frac. | Cum. Wat. Prod. (103 m3) |
| 1 | 106 | 78 | 0.042 | 14 | 112 | 71 | 0.81 | 18 |
| 2 | 110 | 79 | 0.046 | 12 | 110 | 69 | 0.91 | 15 |
| 3 | 106 | 78 | 0.047 | 12 | 109 | 67 | 0.945 | 14 |
| 4 | 105 | 78 | 0.048 | 12 | 107 | 67 | 0.963 | 14 |
| 5 | 104 | 78 | 0.049 | 12 | 106 | 67 | 0.973 | 14 |
| 6 | 103 | 77 | 0.049 | 13 | 104 | 67 | 0.979 | 14 |
| 7 | 103 | 78 | 0.049 | 12 | 104 | 66 | 0.984 | 15 |
| 8 | 102 | 77 | 0.0495 | 13 | 103 | 66 | 0.988 | 14 |
| 9 | 102 | 78 | 0.0495 | 13 | 103 | 66 | 0.991 | 15 |
| 10 | 102 | 76 | 0.0496 | 11 | 103 | 66 | 0.993 | 10 |
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Roy, S.; Djahansouzi, A.; Horáková, M.; Henk, A.; Lehné, R.J. From Legacy Gas Fields to Hydrogen Storage: 3D Seismic-Driven Geological Modelling and Dynamic Simulation in the Northern Upper Rhine Graben. Energies 2026, 19, 4140. https://doi.org/10.3390/en19174140
Roy S, Djahansouzi A, Horáková M, Henk A, Lehné RJ. From Legacy Gas Fields to Hydrogen Storage: 3D Seismic-Driven Geological Modelling and Dynamic Simulation in the Northern Upper Rhine Graben. Energies. 2026; 19(17):4140. https://doi.org/10.3390/en19174140
Chicago/Turabian StyleRoy, Sonu, Ariane Djahansouzi, Markéta Horáková, Andreas Henk, and Rouwen Johannes Lehné. 2026. "From Legacy Gas Fields to Hydrogen Storage: 3D Seismic-Driven Geological Modelling and Dynamic Simulation in the Northern Upper Rhine Graben" Energies 19, no. 17: 4140. https://doi.org/10.3390/en19174140
APA StyleRoy, S., Djahansouzi, A., Horáková, M., Henk, A., & Lehné, R. J. (2026). From Legacy Gas Fields to Hydrogen Storage: 3D Seismic-Driven Geological Modelling and Dynamic Simulation in the Northern Upper Rhine Graben. Energies, 19(17), 4140. https://doi.org/10.3390/en19174140

