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Article

Application of a Phase-Change Material Heat Exchanger to Improve the Efficiency of Heat Pumps at Partial Loads

1
Graduate School of Advanced Science and Engineering, Hiroshima University, Higashihiroshima 739-8527, Japan
2
Department of Architecture and Structural Engineering, National Institute of Technology (KOSEN), Kure College, Kure 737-8506, Japan
*
Author to whom correspondence should be addressed.
Energies 2025, 18(14), 3694; https://doi.org/10.3390/en18143694
Submission received: 27 May 2025 / Revised: 23 June 2025 / Accepted: 9 July 2025 / Published: 12 July 2025
(This article belongs to the Section J1: Heat and Mass Transfer)

Abstract

Inverter-equipped heat pumps allow for increased energy efficiency. However, air conditioning (AC) systems often operate at low load ratios below where inverter control is effective, which reduces their energy efficiency. We developed an AC system that increases the apparent load ratio of the heat pump by using a phase-change material (PCM). Cooling and heating experiments were conducted with a PCM heat exchanger, which comprised aluminum plates and fins filled with paraffinic PCM. The result indicated a high heat transfer coefficient of >70 W/(m2·K). A simplified numerical model of the PCM heat exchanger as a lumped constant system was created based on the experiment. The calculations generally reproduced the experimental results, with root mean squared errors of 0.39 K for cooling and 0.84 K for heating, confirming their accuracy. Simulations were then conducted to evaluate the energy performance of the proposed system for the cooling season. While low load operation accounted for 39% of the total AC time for a non-PCM system, it was reduced to 2.7% for the proposed system. The proposed system demonstrated load ratios of 50–60% for most of the season, achieving an energy reduction of 11.4% owing to the improved efficiency at partial load ratios.

1. Introduction

While the promotion of renewable energy sources is important for achieving carbon neutrality, an equally necessary step is improving energy efficiency on the demand side through the use of heat pumps [1]. In Japan, air conditioning (AC) systems are commonly based on heat pumps equipped with inverters, which offer variable speed control so that the heat pump can operate efficiently not only at large load ratios close to the compressor capacity but also at partial load ratios [2]. However, inverter control becomes invalid at small load ratios below ~20% during which the compressor is simply turned on or off as necessary, which is inefficient [3]. During actual operation, heat pumps tend to be at low load ratios because AC systems are generally designed with excess capacity so that they can sufficiently cool and heat buildings during even the hottest and coldest days throughout the year. We performed field measurements showing that the energy efficiency of heat pumps in actual residential buildings decreases at low load ratios [4,5]. Therefore, it is necessary to improve the energy efficiency of heat pumps at low load ratios below the lower limit of inverter control to further reduce the energy consumption and CO2 emissions of AC systems.
Thermal energy storage (TES) is a technology that can be used to adjust the temporal gap between energy supply and demand, which tend to peak at different times [6]. Unlike general sensible heat storage, in which water or concrete is utilized as the storage medium, phase-change materials (PCMs) can charge or discharge large amounts of heat at a constant temperature when they change phase [6]. Various studies have explored applying PCMs to buildings [7,8,9,10,11], such as mixing PCMs with flooring, wall, and roof materials, to extend the thermal capacity of buildings and stabilize the indoor thermal environment [12,13,14] or encapsulating PCMs in radiation panels to function as part of a thermally activated building structure [15,16]. Many studies have utilized PCMs to store natural thermal energy, such as solar heat [17,18] or cool air at night [19,20,21], to reduce the load and energy consumption of AC systems. Several studies have investigated precooling or prewarming PCMs at night, during which the energy supply tends to exceed demand, as a load leveling or peak shaving strategy [22,23]. Some researchers have proposed applications for PCMs in which heat pumps operate during energy-efficient hours, such as in the early morning in warm regions [24] and in the daytime in cold regions [25]. However, few studies have considered applying PCMs to improve the energy efficiency of inverter-equipped heat pumps at low load ratios.
The practical application of PCMs requires an increase in the heat transfer coefficient of the PCM itself or a heat exchanger. Several studies have reported that adding nanoparticles increases the apparent heat conductivity of a PCM [26]. Several researchers have investigated the heat exchange characteristics of functional PCMs enclosed in shell-and-tube type heat exchangers [27,28,29], triple tube heat exchangers [30,31], and porous foam materials forming wavy air channels [32]. While shell-and-tube type heat exchangers are commonly used for PCM applications where heat is exchanged with water [33,34,35], different heat exchangers have been investigated for buildings where heat is exchanged with air [10,36,37], such as the tube type [38,39], ball type [40], plate type [41], and finned plate type [42,43]. We also investigated using a packed bed of granulated PCM as a heat exchanger [44,45]. Although the granulated PCM had a large surface area that resulted in a large heat transfer coefficient with air, problems remained in terms of sealing and pressure drop for use in actual AC systems. Thus, research has been insufficient on PCM applications where heat is exchanged with air that achieve both a high thermal performance and a low pressure drop.
In this study, we utilized the TES concept through a high-performance PCM heat exchanger to operate a heat pump at a high apparent load ratio and avoid low-efficiency intermittent operation. To evaluate the effectiveness of our design, we fabricated a prototype heat exchanger containing about 1 kg of PCM and conducted experiments to observe the heat exchange characteristics and pressure loss at different air flow rates. Numerical simulations were carried out to evaluate the energy efficiency of the proposed AC system in different seasons and at partial load ratios compared to a conventional AC system without TES.

2. Design

Figure 1 shows conceptual diagrams of the proposed AC system in charge and discharge modes. A PCM heat exchanger is connected to the indoor unit, which is installed in a ceiling space with air ducts. For cooling operation during the summer, charge mode involves storing cold energy in the PCM, while discharge mode involves extracting the cold energy from the PCM. In charge mode, air taken from the room is first cooled in the indoor unit, which acts as an evaporator in the heat pump cycle. The air then passes through the PCM heat exchanger, which cools the PCM inside and is returned to the room as conditioned air. The air flow rate of the fan in the indoor unit is varied to remove the cooling load in the room and to cool the PCM within the rated value. Because the room and PCM are cooled simultaneously, the load ratio of the outdoor unit is increased, which increases the energy efficiency ratio (EER). In discharge mode, the fan in the indoor unit contributes to ventilation rather than the heat pump cycle. The air taken from the room is cooled by the PCM heat exchanger and circulated back to the room to remove the cooling load. The charge and discharge modes switch according to the outlet temperature (Tout) under the assumption that the PCM completes the phase change.

3. Experimental Setup

Figure 2 and Figure 3 show the dimensions and schematic diagrams, respectively, of the PCM heat exchanger prototype. The prototype was made of aluminum with a weight of 8.9 kg and external dimensions of 235 × 300 × 374 mm. Air passes through the heat exchange element filled with PCM (shaded in orange). The heat exchange element consisted of aluminum plates connected by aluminum fins. The 1 mm-thick aluminum plates had a hollow structure, with additional mesh-like fins arranged inside. The total heat exchange area was 4 m2. Air exchanges heat with the heat exchange element by passing between the fins. PCM temperature (Tp) was measured at the junction of the PCM filling sections, as shown in Figure 3b, because of the limited space for inserting a thermocouple. Table 1 presents the physical properties of the PCM used to fill the heat exchange element. The PCM mainly consisted of paraffin wax. Differential scanning calorimetry of a 1.7 mg sample determined the melting and solidification temperatures as 17.8 and 17 °C, respectively. The amount of latent heat was determined as 188 kJ/kg. The PCM was enclosed in the heat exchange element in liquid form with a filling weight of 0.8 kg.
Figure 4 shows a schematic diagram of the experimental system, including an exterior view. Air ducts were connected in front of and behind the PCM heat exchanger with plastic guides installed in the front duct to regulate the air. A chilled/warmed water coil and a fan were installed at the inlet and outlet of the air duct. The water in the coil was controlled to a specific temperature by a constant-temperature chiller. The PCM heat exchanger was covered with thermal insulation during the experiment. Figure 5 shows the measurement points, while Table 2 presents the specifications of the measurement devices and sensors. The temperature, differential pressure, and wind speed were measured every 30 s. The inlet air temperature (Tin) and outlet air temperature (Tout) were measured by thermocouples placed at nine points near the front and back surfaces, respectively, of the fins. The differential pressure was measured before and after the heat exchange element. The air velocity was measured by a one-dimensional hot-wire anemometer placed at the center of the duct cross-section.
Experiments were performed to evaluate first the cooling process and then the heating process. For the cooling process, the PCM was solidified, and the Tin was controlled at 10 °C by using chilled water, which was set at 5 °C in the coil. The cooling process was completed once the PCM temperature (Tp) dropped below 12 °C. For the heating process, Tin was increased to 30 °C by the chiller under the assumption that cold energy was extracted from the PCM in ventilation mode without the aid of the heat pump. The heating process continued until Tp > 20 °C, at which point the PCM was completely melted.
Table 3 presents the experimental cases 1–3. The air velocity was set to 0.5, 1.0, and 1.5 m/s, respectively, by adjusting the fan frequency. The air flow rate was calculated as the product of the measured air velocity and cross-sectional area and was 32, 64, and 95 m3/h, respectively. Each case was tested at least twice between May and July 2024.

4. Experimental Results

The amount of heat exchanged by the PCM heat exchanger (Q) was calculated as follows:
Q = c a ρ a V ( T in T out ) ,
where ca is the specific heat of air [kJ/(kg·K)], ρa is the density of air [kg/m3], and V is the air flow rate [m3/s]. V, Tin, and Tout were measured in the experiments. The overall heat transfer coefficient (U) was calculated as follows:
U = Q / ( A e x   ×   T ) ,
where Aex is the heat exchange area [m2], and ∆T is the difference between Tp and Tout [K].
Figure 6 shows the spatial distributions of Tin and Tout measured at nine points on each side in case 3. During the cooling process, Tin had a range of 11.9–13.9 °C and was up to 2 °C lower at the center than at the edges. This can probably be attributed to the air velocity distribution in the duct cross-section. Although Tout was relatively low in column 3, it was generally maintained around 17 °C, which corresponds to the phase change temperature, and had a smaller range than Tin. During the heating process, Tin varied by only 0.8 °C, which was less than the variation during the cooling process. This suggests that supplied air with a low density helped equalize the velocity entering the heat exchange element. Tout again stayed near the phase change temperature during the heating process. These results indicate that the air flow entering the PCM heat exchanger was regulated by the fins, which facilitated a uniform heat exchange and led to adequate heat extraction at the outlet side. Below, the mean of the values obtained at the nine measurement points is used to represent Tin and Tout.
Figure 7 shows the relationship between the face air velocity and pressure drop in the heat exchange element. The face air velocity was calculated by dividing V by 0.09 m2, which is the surface area of the heat exchange element. At a face air velocity of 0.1–0.3 m/s, the pressure drop was only 2–9 Pa and was generally below 10 Pa. This pressure drop is much smaller than that of typical fin-tube heat exchangers, which require a face air velocity of approximately 3.0 m/s to achieve U values of 55–60 W/(m2·K) [46].
Figure 8 shows the temperature, Q, and U profiles of case 3 during the cooling and heating processes. During the cooling process, Tp dropped to 18 °C after 10 min and remained constant for 17 min during which the PCM solidified. Tout dropped earlier than Tp but stayed constant with Tp during the phase change period. This stable behavior for Tout resulted in Q remaining constant at 140 W. U increased with smaller ∆T and reached a maximum of 61 W/(m2·K) during the phase change period. During the heating process, Tp increased to 17 °C after 3 min and remained stable for 7 min, during which the PCM melted. Although an increase in Tout was suppressed during the phase change period, the difference with Tp was greater than during the cooling process. Q was 220–250 W during the phase change period, which was larger than in the cooling process and can be attributed to the larger difference between Tin and Tout in the heating process. On average, U was approximately 28 W/(m2·K) during the phase change period. After the phase change, both Tp and Tout rose to approach Tin. However, the rise in Tp was suppressed to around 25 °C for 12 min after 20–25 min. This behavior was probably due to the delayed melting of the PCM deep inside the heat exchanger. This suggests that Tp was affected by the heat capacity of the surrounding PCM. In addition, the fin structure in the PCM heat exchanger may make natural convection difficult to occur. This meant that the low heat conductivity of the liquid phase had a relatively large impact. Therefore, PCM in the junction may have partially delayed or not contributed to the heat exchange. Thus, we decided to determine the effective weight that contributed to the heat exchange, which we then used to develop the model for our later numerical simulations.
To predict Tout after the heat exchange, we formulated empirical formulas for calculating U based on the experimental results. Figure 9 shows the relationships between Tp and U obtained in the cooling and heating processes. The values observed every 30 s are plotted on the figure. Large values of U were observed at temperatures of 17 and 18 °C, which correspond to the phase change temperature of the PCM. During the cooling process, U was 10–20 W/(m2·K) above the phase change temperature and increased sharply when Tp was below 18 °C. U became small again below the phase change temperature with an average value of 4.1 W/(m2·K). During the heating process, U was around 20 W/(m2·K) below the phase change temperature and increased drastically when Tp exceeded 17 °C. While U decreased to 10 W/(m2·K) after the phase change, it rose again in several cases, which may be due to the melting of the PCM deep inside the heat exchange element. The formulation procedure was as follows.
(1)
The maximum U and corresponding Tp for each case were averaged to obtain U = 69 W/(m2·K) at Tp = 17.60 °C during the cooling process and U = 77 W/(m2·K) at Tp = 17.55 °C during the heating process.
(2)
During the phase change, the relationship between U and Tp can be approximated as a power law that asymptotically approaches 17.57 °C during the cooling process and 17.60 °C during the heating process, where a bi-square weighting function is applied to prevent the influence of outliers.
U = 16.17 ( T p 17.57 ) 0.31 .
U = 24.80 ( 17.60 T p ) 0.24 .
When compared with the experimental results, both Equations (3) and (4) showed a high explanatory power with R2 > 0.7.
(3)
After the phase change, U decreased linearly from the maximum U value with a temperature difference of 0.2 K to constant values of 4.1 W/(m2·K) during the cooling process and 9.5 W/(m2·K) during the heating process, on average.

5. Numerical Model

5.1. Setup

A numerical model was developed to predict Tout from the PCM heat exchanger. The temperature distribution in the PCM heat exchanger was not considered under the assumption that the air flow is uniform across the cross-section. The heat balance in the PCM heat exchanger can then be represented as a lumped constant system where the internal PCM and exterior aluminum are a single unit:
( W ale + W pe ) dH p + al dt = U A ex ( T out T p ) ,
where Wpe and Wale are the effective weights of the PCM and aluminum [kg], respectively, contributing to the heat exchange. The heat capacity of the PCM heat exchanger can be expressed as the change in enthalpy per the total effective weight of PCM and aluminum (Hp+al) [kJ/kg]. Hp+al can be converted to Tp by the enthalpy method. The amount of heat exchanged with air can then be calculated by using U as determined from the experimental results. The heat balance on the air side can be represented by the heat from advection and heat exchanged by the PCM heat exchanger:
c a ρ a V ( T out T in ) = U A ex ( T p T out ) + Q loss ,
where the heat storage of air can be neglected as its heat capacity was sufficiently smaller than that of the PCM heat exchanger. Equation (6) can then be used to determine Tout. Qloss is the heat loss and is calculated as follows:
Q loss =     K l o s s A s u r T in + T o u t / 2 T a m b ,
where Kloss is the heat loss coefficient identified as 2.0 W/(m2·K) from experimental validation, Asur is the surface area of the PCM heat exchanger (=4.0) [m2], and Tamb is the ambient air temperature [°C].
Figure 10 shows the relationship between temperature and enthalpy for the combined mass of PCM and aluminum as given by the enthalpy method. The latent heat due to the phase change of the PCM can be obtained from the linear relationship at 17–18 °C. The enthalpy change outside the phase change temperature can be calculated by using the mean specific heat of the PCM heat exchanger:
c p + al = ( W pe   ×   c p + W ale   ×   c al ) / ( W pe + W ale )
where cp+al, cp, and cal are the specific heats of the PCM heat exchanger, PCM, and aluminum [kJ/(kg·K)].
As shown in Figure 8, the PCM in the junction may have been partially delayed or not contributed to the heat exchange. To represent the phenomenon in the model, Wpe and Wale were determined according to the following procedure. To identify Wale, experiments were performed using the same PCM heat exchanger prototype as before, but without PCM. Then, Wale was calculated by setting Wpe = 0 in Equations (5) and (8) and varying the weight of aluminum in 0.1 kg increments to reproduce the experimentally obtained Tout with the smallest error. Figure 11 shows the root mean squared error (RMSE) between the experimental and calculated Tout at different aluminum weights. RMSE was minimized at 5.83 kg, which corresponded to 72% of the total aluminum weight of the prototype (8.1 kg). Thus, Wale was set to 5.83 kg for the following simulations. Similarly, Wpe was determined as the weight of the PCM at which the experimental Tout was reproduced with the smallest error. As shown in Figure 12, the smallest RMSE between the experimental and calculated Tout was obtained at a PCM weight of 0.53 kg, which was equivalent to 66% of the total weight of the prototype. Thus, Wpe was set to 0.53 kg.

5.2. Verification

The accuracy of the numerical model was verified under the same boundary conditions as in the experiment, using Wale and Wpe, as determined previously. Figure 13 shows the relationship between the experimental and calculated Tout. The calculated Tout was sometimes higher than the experimental Tout during the cooling and lower during the heating process. The calculated Tout generally remained constant while the experimental Tout varied under the influence of Tin. Deviations were observed in cases 1 and 2, which had relatively small air volumes. The experimental results suggested that the phase change occurred in a distributed manner in the prototype, but the numerical model assumed that the heat exchanger was a lumped constant system. This had the clear effect of regulating the temperature during the phase change in the calculated results compared with the experimental observations. In cases with a smaller air volume, the phase change progressed more slowly, which may have facilitated the dispersion of heat extracted from the PCM to the air during the experiment. Overall, the average RMSE for all cases was 0.39 K for the cooling process and 0.84 K for the heating process, indicating relatively good reproducibility. Thus, the numerical model showed reasonable accuracy for evaluating seasonal or annual system behavior despite its simplicity. Further validation may be needed with modified heat exchangers that reflect the ideal heat exchange behavior of a lumped constant system.

6. Simulations

6.1. Conditions

Energy simulations were performed by applying the developed numerical model to an office space with windows on the south side, as shown in Figure 14. An AC system was constructed by using the Life Cycle Energy Management (LCEM) tool ver. 3.10 distributed by MLIT [47], as shown in Figure 15. The system was assumed to be a variable refrigerant flow (VRF) system comprising eight indoor units and one outdoor unit, where a PCM heat exchanger was connected to each indoor unit. The energy consumption was calculated at 5 min intervals by using cooling loads from May 1 to October 31 obtained from the Building Energy Simulation Tool (BEST) Program [48] as the input. The weather data in Tokyo, standard values of heat gains through structure and windows, and internal loads were used to calculate the cooling load. Table 4 presents the specifications of the AC system, which were determined so that the outdoor unit operated at an average load ratio of 30% in July. The eight indoor units were assumed to exhibit the same behavior, and the set of one indoor unit and PCM heat exchanger shared one-eighth of the cooling load. The inlet air temperature (Tin) after the indoor unit and air flow rate (V) as determined by the cooling load were used as inputs to calculate the outlet air temperature (Tout) after the PCM heat exchanger. The charge and discharge modes were switched based on Tout, as shown in Figure 1. In charge mode, the outdoor unit was operated to cool the room space and the PCM at the same time. When Tout fell below 15 °C, the system switched to discharge mode, in which the room space was cooled by the charged PCM, and the outdoor unit did not operate. When Tout rose above 21 °C, the system switched back to charge mode.

6.2. Optimization of the PCM Weight

The amount of PCM was optimized by varying the effective weight of the heat exchanger for an indoor unit (Wale + Wpe) obtained in the previous experiments (case A) by four times (case B), eight times (case C), and 12 times (case D). We assumed that the PCM heat exchanger could be extended in the direction of air flow without changing the thickness of the heat exchange element and the pressure loss. Figure 16 shows the monthly integrated energy consumption for each case. The energy consumption tended to decrease in cases with larger weights. Although cases C and D had similar energy consumptions, case C had a smaller amount of heat insufficient for the cooling load than case D. Thus, the optimal PCM weight to satisfy the cooling load of the target room was eight times the experimental weight (i.e., case C). This value was applied in the following simulations.

6.3. Thermal Behavior on a Representative Day

Figure 17 shows the changes in temperature and amounts of heat of the AC system on May 1, where Qroom is the heat to cool the room, Qc-PCM is the heat charged to the PCM, and Qd-PCM is the heat discharged from the PCM. In charge mode, Tp was maintained around 17 °C, owing to solidification of the PCM, and then decreased to 15 °C, owing to changes in the sensible heat. Tout accordingly dropped until it fell below 15 °C, which was the lower limit for the AC system to switch to discharge mode. In discharge mode, Tp was maintained around 17 °C as the PCM melted and then rose to 20 °C. The charge and discharge times for each cycle were 25 and 47 min, respectively, on average. The charge time, during which the outdoor unit was required to operate, was approximately one-third of the total AC time. Qc-PCM was larger than Qroom at 8:00 because the PCM was cooled from its initial temperature of Tp = 26 °C. After 8:00, Qc-PCM was added to Qroom at the same rate in charge mode, while Qd-PCM was always equivalent to Qroom in discharge mode because the outdoor unit was not operating. The maximum load was approximately 15 kW even when the heat for cooling the PCM was added to the indoor cooling load, which was small relative to the total cooling capacity of the eight indoor units (58 kW).

6.4. Effects of the PCM Heat Exchanger

Figure 18 compares the load ratios of the outdoor unit on the same day. Without PCM, low load ratios of <20% were observed throughout the day, suggesting a low energy efficiency. With PCM, the load ratio increased to 50–60%, except for in the late afternoon at around 18:00. Figure 19 shows the load ratio frequencies at 10% intervals and the EER for each load ratio during the whole cooling season. Without PCM, low load ratios of <20% (EER < 3.4) corresponded to an AC time of 680 h, which was 38.6% of the total AC time. With PCM, low load ratios of <20% were reduced to 2.7% of the total AC time. Instead, load ratios of 50–60% (EER = 5.4) took up most of the AC time. Thus, the PCM heat exchanger clearly helped increase the load ratio of the AC system and achieve a high EER. Seasonal EER (SEER) with PCM was 4.97, which was 19% higher than that without PCM. Figure 20 shows the monthly energy consumption of the whole AC system with and without PCM, including the outdoor and indoor units. With PCM, a reduction in energy consumption was observed in all months. The reduction was relatively small in July and August when the cooling load was large and there was little available capacity to cool the PCM. The total reduction in energy consumption for the cooling season was calculated as 11.4%, which indicates that the PCM heat exchanger effectively improved the partial load efficiency of the AC system.

7. Conclusions

We developed a new AC system that uses a PCM heat exchanger to increase the apparent load ratio of the heat pump. Experiments with a prototype heat exchanger demonstrated that the outlet air temperature close to the phase change temperature was obtained during the melting or solidification of the PCM, which led to a U value of greater than 70 W/(m2·K). The heat exchange element also achieved a small pressure drop of less than 10 Pa, suggesting that the PCM heat exchanger could achieve a high thermal performance while maintaining a small pressure drop. The relationship of U to Tp during phase change was formulated as power-law approximations with R2 > 0.7 for both the cooling and heating processes. Currently, U is calculated from Tout, which is the output obtained from the experiment. It will be necessary for future works to provide more physical explanations of the relationship with the input conditions.
A numerical model was developed for predicting the outlet air temperature of the PCM heat exchanger. The effective weights of the PCM and aluminum contributing to the heat exchange were determined as 0.53 kg and 5.83 kg, respectively. The numerical model reproduced the experimental outlet air temperatures relatively well, with the average RMSEs of 0.39 K for cooling and 0.84 K for heating, although some deviations were observed during the phase change, which may be attributed to simplifying assumptions such as a uniform phase change by the PCM. The numerical model was then used in simulations to compare the energy consumption of the proposed AC system with and without the PCM heat exchanger. The results showed that using the PCM heat exchanger increased the partial load ratio, avoiding low-efficiency intermittent operation, to approximately 50% in charge mode while allowing the outdoor unit to stay off in discharge mode. The higher partial load ratio in charge mode increased the EER, which is a key indicator of energy efficiency. The total energy consumption was reduced by 11.4% demonstrating the effectiveness of the proposed system.
In this study, the PCM heat exchanger was successfully applied to repeat the charge and discharge modes, while ensuring the room is air-conditioned. In the future, the prototype developed in this study should be extended for use in actual AC systems in buildings. The shape of the prototype is required to be improved to further use the heat capacity of PCMs and prevent the delayed heat transfer deep inside the junction of the prototype, which will cause the PCM to act as a lumped constant system function in the numerical model. In addition, the heat exchange element will be expanded to meet the air flow rate required in the room space, while maintaining high thermal performance and small pressure drops.

Author Contributions

Conceptualization, S.K. and K.K.; methodology, S.K. and K.T.; software, K.T.; validation, K.T. and K.K.; writing—original draft, K.T.; review and editing, S.K.; supervision, D.N. All authors have read and agreed to the published version of the manuscript.

Funding

This work was funded by JSPS KAKENHI Grant Numbers JP21K18768 and JP24K21646.

Data Availability Statement

Data are contained within the article.

Acknowledgments

The authors acknowledge the technical support by MDI Corporation and KANEKA Corporation, and the experimental assistance by Ryoya Hashimoto and Anju Tanaka.

Conflicts of Interest

The authors declare no conflicts of interest.

Abbreviations

The following abbreviations are used in this manuscript:
ACAir conditioning
EEREnergy efficiency ratio
PCMPhase change material
SEERSeasonal energy efficiency ratio
TESThermal energy storage

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Figure 1. Schematic diagrams of the proposed AC system in (a) charge and (b) discharge modes.
Figure 1. Schematic diagrams of the proposed AC system in (a) charge and (b) discharge modes.
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Figure 2. Dimensions of the PCM heat exchanger.
Figure 2. Dimensions of the PCM heat exchanger.
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Figure 3. Schematic diagrams of the PCM heat exchanger: (a) overall appearance and (b) enlarged view of the heat exchange element.
Figure 3. Schematic diagrams of the PCM heat exchanger: (a) overall appearance and (b) enlarged view of the heat exchange element.
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Figure 4. Schematic diagram of the experimental system.
Figure 4. Schematic diagram of the experimental system.
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Figure 5. Measurement points: (a) elevation view and (b) plan view.
Figure 5. Measurement points: (a) elevation view and (b) plan view.
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Figure 6. Spatial distributions of Tin and Tout during the phase change in case 3.
Figure 6. Spatial distributions of Tin and Tout during the phase change in case 3.
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Figure 7. Relationship between the face air velocity and pressure drop in the PCM heat exchanger.
Figure 7. Relationship between the face air velocity and pressure drop in the PCM heat exchanger.
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Figure 8. Profiles of temperature, Q, and U in case 3 during (a) cooling and (b) heating processes.
Figure 8. Profiles of temperature, Q, and U in case 3 during (a) cooling and (b) heating processes.
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Figure 9. Relationship between Tp and U during (a) cooling and (b) heating processes.
Figure 9. Relationship between Tp and U during (a) cooling and (b) heating processes.
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Figure 10. Relationship between the temperature and enthalpy per the total mass of PCM and aluminum.
Figure 10. Relationship between the temperature and enthalpy per the total mass of PCM and aluminum.
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Figure 11. RMSE between experimental and calculated Tout at different aluminum weights.
Figure 11. RMSE between experimental and calculated Tout at different aluminum weights.
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Figure 12. RMSE between experimental and calculated Tout at different PCM weights.
Figure 12. RMSE between experimental and calculated Tout at different PCM weights.
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Figure 13. Relationship between experimental and calculated values of Tout during (a) cooling and (b) heating processes.
Figure 13. Relationship between experimental and calculated values of Tout during (a) cooling and (b) heating processes.
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Figure 14. Office model used in the energy simulation: (a) elevation view, (b) plan view, and (c) 3D view.
Figure 14. Office model used in the energy simulation: (a) elevation view, (b) plan view, and (c) 3D view.
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Figure 15. Diagram of the AC system.
Figure 15. Diagram of the AC system.
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Figure 16. Monthly integrated energy consumption at each PCM weight.
Figure 16. Monthly integrated energy consumption at each PCM weight.
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Figure 17. Changes in (a) temperatures and (b) heat transfer on May 1.
Figure 17. Changes in (a) temperatures and (b) heat transfer on May 1.
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Figure 18. Changes in load ratio on May 1 with and without PCM.
Figure 18. Changes in load ratio on May 1 with and without PCM.
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Figure 19. Frequency of load ratios and their average EERs: (a) without PCM and (b) with PCM.
Figure 19. Frequency of load ratios and their average EERs: (a) without PCM and (b) with PCM.
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Figure 20. Monthly energy consumption with and without PCM.
Figure 20. Monthly energy consumption with and without PCM.
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Table 1. Physical properties of the PCM.
Table 1. Physical properties of the PCM.
Physical PropertiesValue
Latent heat amount188 kJ/kg
Melting point17.8 °C
Freezing point17.0 °C
Table 2. Measurement devices and sensors.
Table 2. Measurement devices and sensors.
Measurement ItemDeviceSensorsRangeAccuracy
Air temperatureHIOKI data logger *1Thermocouples

[Type T, Class1]
~100 °C±0.5 °C
PCM temperatureHIOKI data logger *1Thermocouples

sheath type
−200 to +300 °C±0.5 °C
Air velocityTesto480 multifunction measuring instrument *2Testo Hot-wire anemometer0 to 20 m/s±0.03 m/s
Pressure lossOMRON differential pressure station *3 −500 to 500 Pa±0.2 Pa
Manufacturer information: *1 HIOKI E.E. CORPORATION (Nagano, Japan), *2 Testo SE & Co. KGaA (Titisee-Neustadt, Germany), *3 OMRON Corporation (Kyoto, Japan).
Table 3. Experimental cases.
Table 3. Experimental cases.
PropertiesCase 1Case 2Case 3
Air velocity [m/s]0.51.01.5
Air flow rate [m3/h]326495
Table 4. Specifications of the AC system.
Table 4. Specifications of the AC system.
(a) Outdoor Unit(b) Indoor Units
Number of outdoor units1Number of indoor units8
Rated cooling capacity [kW]65Rated cooling capacity [kW]7.3
Rated power consumption [kW]17.8Rated power consumption [kW]0.3
Rated COP3.64Rated air volume [m3/h]1170
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Tani, K.; Kindaichi, S.; Kawasaki, K.; Nishina, D. Application of a Phase-Change Material Heat Exchanger to Improve the Efficiency of Heat Pumps at Partial Loads. Energies 2025, 18, 3694. https://doi.org/10.3390/en18143694

AMA Style

Tani K, Kindaichi S, Kawasaki K, Nishina D. Application of a Phase-Change Material Heat Exchanger to Improve the Efficiency of Heat Pumps at Partial Loads. Energies. 2025; 18(14):3694. https://doi.org/10.3390/en18143694

Chicago/Turabian Style

Tani, Koharu, Sayaka Kindaichi, Keita Kawasaki, and Daisaku Nishina. 2025. "Application of a Phase-Change Material Heat Exchanger to Improve the Efficiency of Heat Pumps at Partial Loads" Energies 18, no. 14: 3694. https://doi.org/10.3390/en18143694

APA Style

Tani, K., Kindaichi, S., Kawasaki, K., & Nishina, D. (2025). Application of a Phase-Change Material Heat Exchanger to Improve the Efficiency of Heat Pumps at Partial Loads. Energies, 18(14), 3694. https://doi.org/10.3390/en18143694

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