Next Article in Journal
Battery Management in Electric Vehicle Routing Problems: A Review
Previous Article in Journal
Numerical Simulation of Vertical Well Depressurization with Different Deployments of Radial Laterals in Class 1-Type Hydrate Reservoir
Previous Article in Special Issue
Reservoir Characteristics and Influencing Factors of Organic-Rich Siliceous Shale of the Upper Permian Dalong Formation in Western Hubei
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Energies
Volume 17
Issue 5
10.3390/en17051140
energies-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Pore Structure and Factors Controlling Shale Reservoir Quality: A Case Study of Chang 7 Formation in the Southern Ordos Basin, China

by
Qing Li
1,2,
Xuelian You
3,*,
Jiangshan Li
1,2,
Yuan Zhou
1,2,
Hao Lu
1,2,
Shenghe Wu
1,2,
Dali Yue
1,2 and
Houmin Zhang
1,2
1
National Key Laboratory of Petroleum Resources and Engineering, Beijing 102249, China
2
College of Geosciences, China University of Petroleum, Beijing 102249, China
3
School of Ocean Sciences, China University of Geosciences (Beijing), Beijing 100083, China
*
Author to whom correspondence should be addressed.
Energies 2024, 17(5), 1140; https://doi.org/10.3390/en17051140
Submission received: 19 January 2024 / Revised: 13 February 2024 / Accepted: 20 February 2024 / Published: 28 February 2024
(This article belongs to the Special Issue Unconventional Oil and Gas: Reservoir Evaluation and Accumulation Mechanism Research)
Browse Figures
Versions Notes

Abstract

:
The lithofacies types, pore structure differences, and main controlling factors on the shale reservoirs are vital problems that need to be addressed in the process of shale oil exploration and development. This study explores the Luohe oilfield in the southern Ordos Basin, which is composed of organic-rich shale in the Chang 7 member, to clarify the reservoir properties and analyze major factors affecting the reservoir quality. The shale reservoir can be divided into five lithofacies using ternary diagrams of TOC, argillaceous minerals, and siliceous minerals: high organic-rich siliceous shale (HOSS), high organic-rich argillaceous shale (HOAS), medium organic-rich siliceous shale (MOSS), medium organic-rich argillaceous shale (MOAS), and low organic-rich shale (LOS). The type of organic matter in the studied samples is mainly Type I kerogen and Type II kerogen, predominantly Type II1 kerogen. The kerogen mostly lie within the mature zone in the study area. Various types of pores have been identified in the studied shale: intergranular pores, intragranular pores, intercrystalline pores, organic matter pores, and seams around organic matter. The pores are commonly nanoscale to micrometer in scale, with diameters ranging from 10 nm to several microns. The S1 content in shale is positively correlated with the macropore content, indicating that macropores in shale are the main effective oil storage spaces and are important for oil-bearing reservoirs. There is a good positive relationship between the macropore volume of shale and the content of organic matter. Organic matter in the shale can be beneficial for generating organic matter pores, dissolution pores, and seams at organic matter edge, resulting in better physical properties of shale reservoirs. There is a negative relationship between the quartz/feldspar content and macropores content, indicating that quartz and feldspar are detrimental for the macropore volume development. The lithofacies type is one of the important factors controlling the macropore volume. MOAS and HOAS are favorable lithofacies for the development of macropores. The findings of this study can be utilized for hydrocarbon exploration and development in the lacustrine shale formation of the Ordos Basin and other similar basins.

1. Introduction

Shale oil and gas have become a hot spot in global petroleum exploration and development. Shale oil and gas have great exploration potential and development prospects [1]. In the past few decades, research on the sedimentary and reservoir characteristics of shale reservoirs has also become a hot topic in the field of unconventional oil and gas geology [2,3]. The composition of minerals, rock texture, and sedimentary structure in shale formations commonly display strong heterogeneity, as well as reservoir qualities of shale reservoirs [4,5,6,7].
The composition of shale reservoirs is complex, including silt and clay minerals formed by mechanical deposition, organic matter related to biological origin, and carbonate minerals formed by chemical sediment.
Extensive studies have been performed on the reservoir space of shale. Pore types in shale reservoirs can be divided into four categories: organic pores, intergranular pores, intragranular pores, and fractures [8]. According to pore size, pores in shale reservoir are generally classified into micropores (<2 nm), mesopores (2–50 nm), and macropores (>50 nm) by the International Society of Theoretical and Applied Chemistry (IUPAC) standards [9,10]. There are multiple and complex factors that control the quality of shale reservoir systems, including inorganic factors (mineral composition, particle size, lithofacies type, diagenesis, etc.) and organic factors (TOC content, organic matter type, maturity, hydrocarbon generation, etc.)
The Chang 7 member of the Triassic Yanchang Formation in the Ordos Basin has enormous shale oil and gas resources [11,12]. The organic-rich shale in the Chang 7 formation has enormous potential for shale oil exploration and development, making it an important supplement for future petroleum storage and production growth.
Although a large number of studies has been performed on shale reservoirs in recent years, the lithofacies types, pore structure differences, and main controlling factors on the shale reservoirs in the Chang 7 formations of the southern Ordos Basin, especially in the Luohe oilfield, are not clear. For example, how organic matter, different mineral composition and lithofacies affect the shale reservoir quality are not fully understood. Research on differences in the reservoir quality and controlling factors of the different shale lithofacies of the southern Ordos Basin is relatively weak.
To address this gap, this study explores the Luohe oilfield in the southern Ordos Basin, which is mainly composed of organic-rich shale in the Chang 7 member. The main purpose of this study is to characterize the shale reservoir properties of the Chang 7 and analyze major factors that control the reservoir quality. The results of this study can be utilized for hydrocarbon exploration in shale formation in the Ordos Basin and other similar basins.

2. Geological Setting

The Ordos Basin, which is located in the central part of China (Figure 1A), appeared as an asymmetrical rectangle extending from north to south, ranking the second largest basin in China [13,14]. The edge of the Ordos Basin is surrounded by active folded mountain and graben systems, with the basement consisting of the Lower Proterozoic and Archean metamorphic rock series. The internal structure of the Ordos Basin is relatively simple and the subsidence is stable. The overall tectonic movement is descending in the west and rising in the east, resulting in lower strata in the west and higher strata in the east. There are six tectonic units in the Ordos Basin. The north part of the basin is a Yimeng uplift while the south part is a Weibei uplift. The Jinxi fold belt is located in the east part of the basin while the Tianhuan depression and thrust belt are located in the west. The center of the basin is an expansive Yishan slope (Figure 1). The studied area is located in the southern part of the Yishan slope (Figure 1B). The Ordos Basin is a multi-cycle craton basin. The basin has a stable subsidence in the Paleozoic era, with a migration of the depression in the Mesozoic era, and distortion and rifts in the Cenozoic era [15]. During the Late Triassic Period, the southern Ordos Basin became a lacustrine basin with deposition from the fluvial-lacustrine sedimentary system due to the collision between the Yangtze Plate and the North China Plate [16,17,18].
Combined with sedimentary cycles and lithological assemblages, the Upper Triassic Yanchang Formation of the Ordos Basin is further subdivided into ten members (from top to bottom: Chang 1 to Chang 10) (Figure 2). The Chang 7 member can be further subdivided into three parts: Chang 73, Chang 72, and Chang 71, from bottom to top [19].
The lacustrine basin subsided significantly in the Chang 7 period. A series of organic-rich shale and mudstone was deposited at the bottom of the Chang 7 formation, with a thickness of more than 100 m [11]. The Chang 7 member of the Ordos Basin has become an important target for unconventional petroleum exploration and development [20,21].
Energies 17 01140 g002
Figure 2. The stratigraphic and lithological column chart of the Yanchang Formation in the Ordos Basin (modified from [16,22]).
Figure 2. The stratigraphic and lithological column chart of the Yanchang Formation in the Ordos Basin (modified from [16,22]).
Energies 17 01140 g002

3. Samples and Methods

The shale samples used in this study were obtained from the cores in the Chang 7 Member of the Yanchang Formation of the Luohe oilfield, which is located in the southern Ordos Basin (Figure 1). The samples were analyzed by thin section firstly to select representative samples of different lithofacies. The samples were collected for multiple testing experiments, such as microscopic observations, porosity and permeability, X-ray diffraction (XRD) analysis, high-resolution field emission scanning electron microscopy (FE-SEM) analyses, total organic carbon (TOC) testing, Rock-Eval analyses, and the high-pressure mercury injection (HPMI) analysis.
The XRD analysis was used to determine the type and content of different minerals. The instrument for XRD analysis is the D8 DISCOVER system. The voltage and current parameters are 40 kV and 25 mA, respectively. A total of 3 g fresh sample was ground to <40 μm in an agate mortar before the XRD analysis. The software Jade 6.0 was used to identify mineral types. The relative abundances of different minerals were assessed using semiquantitative analysis in weight percent.
The FE-SEM was used to observe mineral and pore characteristics using FEI Quanta200F produced by FEI Corporation in the United States. The porosity and permeability were measured by the meter CAT112 and CAT113 from American CoreLab in the United States, according to Boyle’s theorem and Darcy’s law of gas percolation.
The TOC test was performed by using a LECO CS-200 carbon analyzer, according to the Chinese national standard GB/T19145-2003. The ranges of the measuring error of the TOC test and porosity test are both ±0.2%. The free hydrocarbons (S1), hydrocarbons cracked from kerogen (S2), carbon dioxide relieved from organic matter (S3), and the maximum temperature of pyrolysate (Tmax) were obtained by Rock-Eval analyses [23,24]. The computational method of the hydrogen index (HI) and the oxygen index (OI) were used according to Espitalie et al., 1977 [25].
The mesopore structure parameters were measured from nitrogen adsorption (NA) experiments. The automatic specific surface was used to obtain the isothermal adsorption experiments of nitrogen and pore size distribution. The gas adsorption capacity at different relative pressures was tested in the NA analysis by using nitrogen as an adsorbent at −196 °C (77 K). The high-pressure mercury injection (HPMI) method was performed according to the capillary bundle model by the intrusion instruments of American CoreLab CMS300 from the United States.

4. Results

4.1. Mineral Compositions and Lithofacies Classification

Thin-section examination and XRD analysis show that the shale is mainly composed of quartz, feldspar, pyrite, clay minerals, and mica, with few types of carbonate and other minerals. The average quartz content is 17 wt.%. The feldspar ranges from 33 to 46.7 wt.% (with an average of 37.6 wt.%). The clay minerals range from 36 to 54 wt.%, with an average of 45 wt.%. The content of pyrite is commonly less than 2 wt.%. The difference in mineral content has a significant impact on the storage performance and fracturing ability of shale. According to a previous study, quartz, pyrite, and feldspar (siliceous minerals) are brittle minerals, which are in favor of hydraulic fracturing. However, clay minerals and mica (argillaceous minerals) are plastic minerals, which have an adverse effect on the fracturing. Organic matter content affects the storage space and hydrocarbon generation potential of shale reservoir [26].
The total organic carbon (TOC) and minerals contents of shale vary greatly. The shale reservoir can be divided into five lithofacies using the ternary diagrams of TOC, argillaceous minerals (clay minerals + mica), and siliceous minerals (quartz + feldspar + pyrite) (Figure 3A): (1) high organic-rich siliceous shale (HOSS): TOC > 6%, siliceous minerals/argillaceous minerals >1; (2) high organic-rich argillaceous shale (HOAS): TOC > 6%, siliceous minerals/argillaceous minerals <1; (3) medium organic-rich siliceous shale (MOSS): 2% < TOC < 6%, siliceous minerals/argillaceous minerals >1; (4) medium organic-rich argillaceous shale (MOAS): 2% < TOC < 6%, siliceous minerals/argillaceous minerals <1; (5) low organic-rich shale (LOS): TOC < 2%. The lithofacies in the study area is mainly MOSS and MOAS, with few types of HOAS and LOS. According to samples collected from the core of the Chang 7 shale in the study area, the MOSS is the most developed lithofacies in the Luohe oilfield, which accounts for 45.9%, followed by MOAS (30.6%), HOAS (15.3%), and LOS (8.2%) (Figure 3B).
The HOAS is dark-colored with a high organic matter content. The minerals in HOAS are mainly clay minerals and contain a significant amount of pyrite (Figure 4A). MOSS is an important lithofacies distributed in the study area. The color of MOSS is gray black. There are silt lamina and organic matter rich lamina in MOSS. The mineral types in MOSS are mainly siliceous minerals (such as feldspar and quartz) and clay minerals, with a small amount of pyrite (Figure 4B). MOAS is another important lithofacies in the study area. MOAS is dark colored and is commonly composed of regular or irregular laminae (Figure 4C). The mineral type is mainly clay minerals, containing a small amount of pyrite. LOS contains relatively large amounts of terrigenous debris particles and low organic matter (Figure 4D). The mineral type is mainly clay minerals, with little pyrite content.

4.2. Organic Geochemistry Classification

The TOC values of samples from the Chang 73 range from 1.85 wt.% to 7.42 wt.%, with an average of 4.8 wt.%. The HC yield (S1 + S2) for the samples analyzed range from 5.56 mg HC/g rock to 20.16 mg HC/g rock, with an average of 12.10 mg HC/g rock. The samples from the Chang 72 have TOC values ranging from 2.78 wt.% to 3.95 wt.% (average 3.24 wt.%) and HC yield (S1 + S2) ranging from 3.5 mg HC/g rock to 9.11 mg HC/g rock (5.56 mg HC/g rock), respectively. According to the cross plot of TOC and (S1 + S2), the generative potential of source rock samples from Chang 73 is commonly excellent and that from Chang 72 is mainly fair or good (Figure 5A).
The Rock-Eval pyrolysis data (such as HI and Tmax values) are commonly used to analyze the characterization of organic matter type. The Tmax value is the temperature when the S2 peak reaches the maximum. The Tmax values of Chang 73 samples range from 441 to 450 °C (with an average of 447 °C) and the Tmax values of Chang 72 samples range from 434 to 443 °C (with an average of 441 °C) (Figure 5B).
The hydrogen index (HI) values of Chang 73 samples range from 138.26 to 208.45 mg HC/g TOC, and average 176.49 mg HC/g TOC. The HI values of Chang 72 samples are between 138.26 and 208.45 mg HC/g TOC, with an average of 176.49 mg HC/g TOC (Figure 5C). The degradation rates of Chang 73 samples are between 15.19% and 24.91%, with an average of 20.91%, while the degradation rates of Chang 72 samples range from 15.19% to 24.91%, with an average of 20.91% (Figure 5D).
A cross plot of the HI versus the pyrolysis Tmax and a plot of degradation rates (D) versus the pyrolysis Tmax are usually used to classify the maturity and type of organic matter [24,27]. These two plots show that the organic matter in the studied samples is mainly Type I to Type II kerogen, predominantly Type II1 kerogen (Figure 5C,D). The Tmax values suggest that most of the samples reach the mature level of hydrocarbon generation (430–455 °C) [24,28]. The maturity of Chang 73 samples is slightly higher than that of Chang 72 samples.

4.3. Porosity

The average porosity difference among different lithofacies in the Luohe area is relatively small. The MOAS has the highest porosities (average, 2.17%), followed by LOS (average, 2.07%), MOSS (average, 1.93%), and HOAS (average, 1.81%) (Figure 6A). The average permeability of different lithofacies varies greatly (Figure 6B). The MOSS has the highest permeability of these lithofacies (average, 0.00184 mD). The average permeabilities of the other lithofacies are all less than 0.00036 mD.

4.4. Pore Types

To address the pore types, abundance, and connectivity of different pores, the photomicrographs taken by SEM of ion-milled shale samples were studied carefully and the pores were point-counted. Various types and shapes of pores in the studied shale have been identified (Figure 7): (1) intergranular pores, (2) intragranular pores, (3) intercrystalline pores, (4) organic matter pores, and (5) seams around organic matter. The main pore type of the shale is intergranular pores, with a few intragranular pores, intercrystalline pores, organic matter pores, and seams around organic matter. The average plane porosity of the MOSS is 0.97% The average plane porosity of the MOAS is 1.63%, which is higher than that of MOSS.
The sizes of pores in the shale reservoir are mainly nano-to micron-scale (Figure 8). The diameters of the intergranular pores usually range from 20 nm to 10 μm. The sizes of other pores are relatively small, with diameter mainly less than 1 micron. The abundance of intergranular pores is highest among all of the pore types, followed by intercrystalline pores and organic matter pores. The amount of intragranular pores and seams around organic matter is relatively low (Figure 8).

4.5. Quantitative Analyses of Pore Structure

4.5.1. Pore Structure Characterized by Nitrogen Adsorption (NA)

The NA experiment can obtain isothermal adsorption curves and desorption curves. The shape of the isothermal adsorption curve is related to the pore characteristics of tested material. According to International Union of Pure and Applied Chemistry (IUPAC), the isotherm adsorption curves of NA can be divided into six types (type I–VI) [29].
If the adsorption curve and desorption curve are not completely reversible, a hysteresis loop will occur. According to IUPAC, the hysteresis loops can be divided into four types [29]: H1 type corresponds to capillary pores (columnar pores); H2 type corresponds to small diameter and ink-bottle like pores (pores with columnar and spherical pores); H3 corresponds to trough-shaped pores which are formed by stacking non-rigid aggregates of sheet-like particles (disordered layered pores and narrow wedge-shaped pores); and H4 type corresponds to narrow slit-shaped pores, generated by layered structures.
The isothermal adsorption curves of all lithofacies in the study area are mainly type IV, suggesting that these shales have mesopore capillary condensation phenomenon. When the pressure approaches its maximum value, saturation does not occur, suggesting that the pores system in the shale is continuous from nanometer to micronmeter [30]. The hysteresis loops of high organic-rich argillaceous shale are mainly type H3 (Figure 9), suggesting the development of trough-shaped pores which are formed by stacking non-rigid aggregates of sheet-like particles (disordered layered pores and narrow wedge-shaped pores). The hysteresis loops of MOAS and LOS are between type H2 and H3, suggesting that these lithofacies have not only disordered layered pores and narrow wedge-shaped pores but also small diameter and ink-bottle like pores (pores with columnar and spherical shapes). The hysteresis loops of medium organic-rich siliceous shale are between those of high organic-rich argillaceous shale and medium organic-rich argillaceous shale, including the development of both narrow wedge-shaped pores and ink-bottle pores.

4.5.2. Pore Structure Characterized by High-Pressure Mercury Injection (HPMI)

The high-pressure mercury injection analysis is commonly used to characterize the pore structure of different reservoirs [31,32]. It is generally believed that the HPMI analyses cannot accurately characterize micropore and mesopore structures of shale reservoirs, because of the influence of compressibility effects. However, the HPMI is a very effective method to measure the characteristics of macropore structures in shale reservoirs [33,34].
The capillary pressure curves of different shale lithofacies in the study area are similar, with all curves upward to the right (Figure 10). The displacement pressure, at which mercury begins to enter the samples in large quantities, is higher than 13 Mpa. Mercury entering the shale pore throats requires a higher capillary pressure, indicating that the pore throat of the shale is overall very small. The average diameters of pore throats in the shales are close, ranging from 22.50 nm to 24.37 nm. The maximum mercury saturation of the shales ranges from 78.89% to 86.5%. The mercury withdrawal efficiency of the shales is from 78.67% to 88.52% (Figure 10). The mercury withdrawal efficiency of medium organic-rich siliceous shale is the highest (88.52%), indicating that mercury easily flows out of the pores and the capillary pressure difference between pores is relatively small compared to other lithofacies. On the contrary, the efficiency of the mercury withdrawal of medium organic-rich argillaceous shale is the smallest (78.67%), indicating that the capillary pressure difference between pore throats is relatively large, which is not conducive to fluid flow.

5. Discussion

5.1. PSD Characteristics Integrated NA and HPMI

Although the size, volume, and surface area parameters of pores can be measured by many experimental methods, such as high-pressure mercury injection (HPMI), nitrogen adsorption (NA), and scanning electron microscopy (SEM), it is impossible to quantitatively characterize the full pore size distribution (PSD) by only one experimental method. Previous studies have shown that the HPMI experiment cannot accurately characterize micropore and mesopore structures while NA experiments cannot accurately characterize macropores. NA is suitable for characterizing mesopores. HPMI can be used to evaluate the characteristics of macropore content, which is measured by the specific pore volume of macropores, that is, the volume of macropores per gram of rock. Considering the different pore size measurement range of different measuring methods, the experimental data of NA and HPMI were integrated to analyze the characteristics of the PSD of the shale reservoir. Using the pore diameter of 50 nm as the boundary, the pore parameters of mesopores and macropores were derived from NA and HPMI experiments, respectively.
The pore size distribution of the HOAS has a bimodal characteristic, located in the mesopore and macropore interval, respectively (Figure 11A). The mesopores of HOAS are concentrated in the range of 6–30 nm and the macropores are concentrated between 60 nm and 150 nm. The pore size distribution of the MOAS also has a bimodal characteristic and the two peaks were both located in the micropore interval (Figure 11C). The pore sizes of the MOAS are concentrated in the range of 6–10 nm and 20–40 nm. The pore size distributions of the MOAS and LOS are both unimodal types, which are concentrated in the range of 3–8 nm and 4–10 nm, respectively (Figure 11). The results show that the HOAS has the largest concentration range of macropores, while for other lithofacies the macropore concentrations are not obvious. The pore size concentration of the mesopores of HOAS and MOAS is larger than that of MOSS and LOS (Figure 11).
The pores in HOAS are mainly macropores, with the highest content of macropores and lowest content of mesopores compared to other lithofacies. The pores in MOSS, MOAS, and LOS are mainly mesopores. The contents of macropore in MOSS, MOAS, and LOS decrease sequentially while the contents of mesopore increase sequentially (Figure 12). The average specific pore volume of macropores in HOAS and MOAS, which is 0.0012 cc/g, is relatively large. The average specific pore volumes of MOSS and low organic-rich shale are 0.0011 cc/g and 0.0010 cc/g, respectively.

5.2. Effective Pore Type

The parameters measured by Rock-Eval included the free hydrocarbons (S1), the hydrocarbons cracked from kerogen (S2), and the carbon dioxide relieved from organic matter (S3) [23,24]. The free hydrocarbons (S1) can reflect the oil content in the reservoir. A high S1 value commonly indicates high oil content. Therefore, the amount of S1 content can be used to represent the oil-bearing capacity of effective pores in shale reservoirs [35]. Through the correlation analysis between macropores, mesopores, and free oil (S1), it can be seen that the S1 content in shale is positively correlated with the macropore content (Figure 13A). However, there is no correlation, or even a negative relationship, between S1 content and the content of mesopores (Figure 13B). This indicates that macropores in shale are the main effective oil storage space and are important for oil-bearing reservoirs. The content of macropores can indirectly represent the ability of its reservoir storage performance. Thus, a study of the influencing factors on macropore development can uncover the main controlling factors on reservoir storage abilities in the study area.

5.3. Main Controlling Factors on Reservoir Quality

5.3.1. Influence of Organic Matter on Reservoir Quality

The content of shale macropore is significantly influenced by organic matter content. There is a good positive relationship between shale macropore volume and organic matter content (Figure 14A). The higher the organic matter content, the larger the content of macropores and the average pore size.
Organic pores are usually considered to be formed because of the conversion of organic matter during the thermal maturation stage [3]. Organic matter in the study area is in the mature stage of hydrocarbon generation. Organic matter pores can be frequently observed in the shale. Thus, the organic matter abundance is a strong controlling factor on organic pores. Organic acids are commonly produced during the thermal evolution of organic matter and the decarboxylation of kerogen, which can further dissolve minerals producing dissolution pores. In addition, due to differences in the physical properties of organic matter and minerals, organic matter edge seams commonly develop between organic matter and mineral particles, which can also produce storage space for oil. Therefore, organic matter in the shale can be beneficial for generating organic matter pores, dissolution pores, and organic matter edge seams, resulting in better physical properties of shale reservoirs.

5.3.2. Influence of Mineral Composition on Reservoir Quality

The samples display a negative correlation between the quartz content and macropores content (Figure 14B). There is also a negative relationship between feldspar and macropores content (Figure 14C). In contrast, clay minerals content shows a positive correlation with macropores content (Figure 14F). The above relationships suggest that quartz and feldspar are adverse for the generation of macropores, especially quartz content. The quartz and feldspar minerals in the shale mainly originate from terrigenous detrital. The quartz and feldspar content in the study area is not high enough to form a large number of intergranular pores between terrestrial debris like that in sandstones. In contrast, high quartz and feldspar mineral contents commonly reflect a high input of terrestrial debris, which is not conducive to the enrichment of organic matter. Thus, the development of quartz is not beneficial for improving the reservoir quality of the shale in the study area. There is no obvious relationship between carbonate mineral and macropores content, as carbonate mineral content in the shale is low (Figure 14D).

5.3.3. Influence of Lithofacies on Reservoir Quality

As analyzed above, there are significant differences in pore type, pore size, pore structure, specific pore volume of macropores, porosity, and permeability among different lithofacies. The macropore content of HOAS and MOAS is relatively high, while the macropores content of MOSS, and LOS is relatively low. The MOAS has the highest porosity (2.17%) among all lithofacies. It can be seen that lithofacies is one of the important controlling factors on the development of macropores. MOAS and HOAS are favorable lithofacies for the development of macropores.

6. Conclusions

(1)
The shale reservoir can be divided into five lithofacies using the ternary diagrams of TOC, argillaceous minerals, and siliceous minerals: high organic-rich siliceous shale (HOSS); high organic-rich argillaceous shale (HOAS); medium organic-rich siliceous shale (MOSS); medium organic-rich argillaceous shale (MOAS); and low organic-rich shale (LOS). The organic matter type is mainly Type I to Type II kerogen in the study area, predominantly Type II1 kerogen. Most of the samples lie within the mature stage of hydrocarbon generation.
(2)
Various types of pores were identified in the studied shale: intergranular pores, intragranular pores, intercrystalline pores, organic matter pores, and seams around organic matter. The pores are commonly nanoscale to micrometer in scale, with diameters ranging from 10 nm to a few microns. The NA and HPMI experimental results were integrated to analyze the characteristics of the PSD. The contents of macropore in MOSS, MOAS, and LOS decrease sequentially while the contents of mesopore increase sequentially.
(3)
The S1 content in shale is positively correlated with the macropore content, indicating that macropores in shale are the main effective oil storage space and are important for oil-bearing reservoirs.
(4)
There is a good positive relationship between shale macropore volume and organic matter content. Organic matter in the shale can be beneficial for generating organic matter pores, dissolution pores, and organic matter edge seams, resulting in better physical properties of shale reservoirs. The samples have a negative relationship between the quartz/feldspar content and macropores content, indicating that quartz and feldspar are adverse for the development of macropores. The lithofacies is one of the important controlling factors for the development of macropores. MOAS and HOAS are favorable lithofacies for the development of macropores.
The findings of this study further clarified the influence of organic matter, mineral composition, and lithofacies on the reservoir quality of shale in the Ordos Basin, which can be utilized for hydrocarbon exploration and development in the lacustrine shale formation of the Ordos Basin and other similar basins.

Author Contributions

Conceptualization, Q.L. and X.Y.; methodology, J.L. and Y.Z.; software, H.L.; formal analysis, S.W. and D.Y.; investigation, Q.L., X.Y. and H.Z.; writing—original draft preparation, Q.L. and X.Y.; review, S.W. and D.Y.; funding acquisition, Q.L. and X.Y. All authors have read and agreed to the published version of the manuscript.

Funding

This study was financially supported by the National Natural Science Foundation of China (Grant No. 42372146 and 41972107) and the Strategic Cooperation Technology Projects of CNPC and CUPB (ZLZX 2020-02).

Data Availability Statement

Data are contained within the article.

Acknowledgments

We are grateful to the Petroleum Exploration and Development Institute of SINOPEC for providing samples and data access, and for permission to publish the results.

Conflicts of Interest

The authors declare no conflicts of interest.

References

  1. Jarvie, D.M.; Hill, R.J.; Ruble, T.E.; Pollastro, R.M. Unconventional shale-gas systems: The Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment. AAPG Bull. 2007, 91, 475–499. [Google Scholar] [CrossRef]
  2. Clarkson, C.R.; Jensen, J.L.; Chipperfield, S. Unconventional gas reservoir evaluation: What do we have to consider? J. Nat. Gas Sci. Eng. 2012, 8, 9–33. [Google Scholar] [CrossRef]
  3. Loucks, R.G.; Reed, R.M.; Ruppel, S.C.; Jarvie, D.M. Morphology, genesis, and distribution of nanometer-scale pores in siliceous mudstones of the Mississippian Barnett Shale. J. Sediment. Res. 2009, 79, 848–861. [Google Scholar] [CrossRef]
  4. Li, Q.; Lu, H.; Li, J.; Wu, S.; Wu, Y.; Wen, L.; He, Y.; Qi, F. Characteristics and formation mechanism of the tight tuff reservoirs of the Upper Triassic Chang 7 member in the southern Ordos Basin, China. Mar. Pet. Geol. 2022, 139, 105625. [Google Scholar] [CrossRef]
  5. Lu, H.; Li, Q.; Yue, D.; Wu, Y.; Gao, J.; Wu, S.; Wang, W.; Li, M.; An, K. Quantitative characterization and formation mechanism of the pore system heterogeneity: Examples from organic-rich laminated and organic-poor layered shales of the upper triassic chang 7 member in the southern Ordos Basin, China. Mar. Pet. Geol. 2023, 147, 105999. [Google Scholar] [CrossRef]
  6. Zheng, D.; Ozbayoglu, E.; Miska, S.; Zhang, J. Experimental Study of Anisotropic Strength Properties of Shale. In Proceedings of the 57th U.S. Rock Mechanics/Geomechanics Symposium, Atlanta, GA, USA, 25–28 June 2023. [Google Scholar] [CrossRef]
  7. Zheng, D.; Ozbayoglu, E.; Miska, S.; Zhang, J. Combined Experimental and Well Log Study of Anisotropic Strength of Shale. In Proceedings of the SPE Annual Technical Conference and Exhibition, San Antonio, TX, USA, 16–18 October 2023. [Google Scholar]
  8. Loucks, R.G.; Reed, R.M.; Ruppel, S.C.; Hammes, U. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores. AAPG Bull. 2012, 96, 1071–1098. [Google Scholar] [CrossRef]
  9. Rouquerol, J.; Avnir, D.; Fairbridge, C.W.; Everett, D.H.; Haynes, J.M.; Pernicone, N.; Ramsay, J.D.F.; Sing, K.S.W.; Unger, K.K. Recommendations for the characterization of porous solids (Technical Report). Pure Appl. Chem. 1994, 66, 1739–1758. [Google Scholar] [CrossRef]
  10. Yang, F.; Ning, Z.; Liu, H. Fractal characteristics of shales from a shale gas reservoir in the Sichuan Basin, China. Fuel 2014, 115, 378–384. [Google Scholar] [CrossRef]
  11. Wang, C.; Wang, Q.; Chen, G.; He, L.; Xu, Y.; Chen, L.; Chen, D. Petrographic and geochemical characteristics of the lacustrine black shales from the upper triassic yanchang formation of the ordos basin, China: Implications for the organic matter accumulation. Mar. Pet. Geol. 2017, 86, 52–65. [Google Scholar] [CrossRef]
  12. Li, Q.; Wu, S.; Xia, D.; You, X.; Zhang, H.; Lu, H. Major and trace element geochemistry of the lacustrine organic-rich shales from the Upper Triassic Chang 7 Member in the southwestern Ordos Basin, China: Implications for paleoenvironment and organic matter accumulation. Mar. Pet. Geol. 2020, 111, 852–867. [Google Scholar] [CrossRef]
  13. He, C.; Ji, L.; Wu, Y.; Su, A.; Zhang, M. Characteristics of hydrothermal sedimentation process in the yanchang formation, south ordos basin, China: Evidence from element geochemistry. Sediment. Geol. 2016, 345, 33–41. [Google Scholar] [CrossRef]
  14. Xian, B.; Wang, J.; Gong, C.; Yin, Y.; Chao, C.; Liu, J.; Zhang, G.; Yan, Q. Classification and sedimentary characteristics of lacustrine hyperpycnal channels: Triassic outcrops in the south ordos basin, central China. Sediment. Geol. 2018, 368, 68–82. [Google Scholar] [CrossRef]
  15. Yang, Y.; Li, W.; Ma, L. Tectonic and stratigraphic controls of hydrocarbon systems in the Ordos basin: A multicycle cratonic basin in central China. AAPG Bull. 2005, 89, 255–269. [Google Scholar] [CrossRef]
  16. Qiu, X.; Liu, C.; Mao, G.; Deng, Y.; Wang, F.; Wang, J. Major, trace and platinumgroup element geochemistry of the upper triassic nonmarine hot shales in the Ordos basin, central China. Appl. Geochem. 2015, 53, 42–52. [Google Scholar] [CrossRef]
  17. Qiu, X.W.; Liu, C.Y.; Wang, F.F.; Deng, Y.; Mao, G.Z. Trace and rare earth element geochemistry of the upper triassic mudstones in the southern Ordos basin, central China. Geol. J. 2015, 50, 399–413. [Google Scholar] [CrossRef]
  18. Zhang, W.; Yang, W.; Xie, L. Controls on organic matter accumulation in the Triassic chang 7 lacustrine shale of the Ordos basin, central China. Int. J. Coal Geol. 2017, 183, 38–51. [Google Scholar] [CrossRef]
  19. Li, L.; Huang, B.; Li, Y.; Hu, R.; Li, X. Multi-scale modeling of shale laminas and fracture networks in the Yanchang formation, Southern Ordos Basin, China. Eng. Geol. 2018, 243, 231–240. [Google Scholar] [CrossRef]
  20. Tang, X.; Zhang, J.; Jin, Z.; Xiong, J.; Lin, L.; Yu, Y.; Han, S. Experimental investigation of thermal maturation on shale reservoir properties from hydrous pyrolysis of chang 7 shale, Ordos basin. Mar. Petrol. Geol. 2015, 64, 165–172. [Google Scholar] [CrossRef]
  21. Dou, W.; Liu, L.; Wu, K.; Xu, Z.; Liu, X.; Xu, F. Diagenetic heterogeneity, pore throats characteristic and their effects on reservoir quality of the Upper Triassic tight sandstones of Yanchang Formation in Ordos Basin, China. Mar. Petrol. Geol. 2018, 98, 243–257. [Google Scholar] [CrossRef]
  22. Liu, F.; Zhu, X.; Li, Y.; Xue, M.; Sun, J. Sedimentary facies analysis and depositional model of gravity-flow deposits of the Yanchang Formation, southwestern Ordos Basin, NW China. Aust. J. Earth Sci. 2016, 63, 885–902. [Google Scholar] [CrossRef]
  23. Barker, C. Pyrolysis techniques for source rock evaluation. AAPG Bull. 1974, 58, 2349–2361. [Google Scholar]
  24. Espitalie, J.; Deroo, G.; Marquis, F. Rock-Eval pyrolysis and its applications. Rev. Inst. Fr. Pet. 1986, 41, 73–89. [Google Scholar] [CrossRef]
  25. Espitalie, J.; Madec, M.; Tissot, B.; Mennig, J.; Leplat, P. Source rock characterization method for petroleum exploration. In Proceedings of the Offshore Technology Conference, Houston, TX, USA, 1–4 May 1977; p. OTC-2935-MS. [Google Scholar]
  26. Zhao, X.Z.; Li, Q.; Jiang, Z.X.; Zhang, R.; Li, H. Organic geochemistry and reservoir characterization of the organic matter-rich calcilutite in the Shulu Sag, Bohai Bay Basin, North China. Mar. Pet. Geol. 2014, 51, 239–255. [Google Scholar] [CrossRef]
  27. Tissot, B.; Welte, D.H. Petroleum Formation and Occurrence; Springer: Berlin/Heidelberg, Germany, 1984. [Google Scholar]
  28. Mukhopadhyay, P.K.; Wade, J.A.; Kruge, M.A. Organic facies and maturation of Jurassic/Cretaceous rocks, and possible oil-source rock correlation based on pyrolysis of asphaltenes, Scotian Basin, Canada. Org. Geochem. 1995, 22, 85–104. [Google Scholar] [CrossRef]
  29. Sing, K.S.W.; Everett, D.H.; Haul, R.A.W.; Moscou, L.; Pierotti, R.A.; Rouquérol, J.; Siemieniewska, T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (recommendations 1984). Pure Appl. Chem. 1985, 57, 603–619. [Google Scholar] [CrossRef]
  30. Li, A.; Ding, W.; He, J.; Dai, P.; Yin, S.; Xie, F. Investigation of pore structure and fractal characteristics of organic-rich shale reservoirs: A case study of Lower Cambrian Qiongzhusi formation in Malong block of eastern Yunnan Province, South China. Mar. Pet. Geol. 2016, 70, 46–57. [Google Scholar] [CrossRef]
  31. Wang, W.; Yue, D.; Eriksson, K.A.; Qu, X.; Li, W.; Lv, M.; Zhang, J.; Zhang, X. Quantification and Prediction of Pore Structures in Tight Oil Reservoirs Based on Multifractal Dimensions from Integrated Pressure- and Rate-Controlled Porosimetry for the Upper Triassic Yanchang Formation, Ordos Basin, China. Energy Fuels 2020, 34, 4366–4383. [Google Scholar] [CrossRef]
  32. Lu, H.; Xia, D.; Li, Q.; Yue, D.; Wu, S.; Wang, W.; Zhang, X. Quantitative Characterization and Differences of the Pore Structure in Lacustrine Siliceous Shale and Argillaceous Shale: A Case Study of the Upper Triassic Yanchang Formation Shales in the Southern Ordos Basin, China. Energy Fuels 2021, 35, 15525–15544. [Google Scholar] [CrossRef]
  33. Clarkson, C.R.; Solano, N.; Bustin, R.M.; Bustin, A.M.M.; Chalmers, G.R.L.; He, L.; Melnichenko, Y.B.; Radlinski, A.P.; Blach, T.P. Pore structure characterization of North American shale gas reservoirs using USANS/SANS, gas adsorption, and mercury intrusion. Fuel 2013, 103, 606–616. [Google Scholar] [CrossRef]
  34. Wang, X.; Hou, J.; Song, S.; Wang, D.; Gong, L.; Ma, K.; Liu, Y.; Li, Y.; Yan, L. Combining pressure-controlled porosimetry and rate-controlled porosimetry to investigate the fractal characteristics of full-range pores in tight oil reservoirs. J. Pet. Sci. Eng. 2018, 171, 353–361. [Google Scholar] [CrossRef]
  35. Jarvir, D.M. Shale resource systems for oil and gas: Part 2—Shale-oil resource systems. In Shale Reservoirs Giant Resources for the 21st Century; Breyer, J.A., Ed.; AAPG Memoir: Washington, DC, USA, 2012; pp. 89–119. [Google Scholar]
Energies 17 01140 g001
Figure 1. (A) The geographic location of the Ordos Basin. (B) The study area and geological background in the Ordos Basin (modified after [4]).
Figure 1. (A) The geographic location of the Ordos Basin. (B) The study area and geological background in the Ordos Basin (modified after [4]).
Energies 17 01140 g001
Energies 17 01140 g003
Figure 3. Classification and proportion of lithofacies of the Ch7 shale in in the Luohe area. (A) Ternary diagram of the lithofacies in the study area. (B) The proportion of different lithofacies in the study area.
Figure 3. Classification and proportion of lithofacies of the Ch7 shale in in the Luohe area. (A) Ternary diagram of the lithofacies in the study area. (B) The proportion of different lithofacies in the study area.
Energies 17 01140 g003
Energies 17 01140 g004
Figure 4. Microscopic characteristics of the different lithofacies within the Chang 73 unit. (A) high organic-rich argillaceous shale (HOAS), well LH3, 939.72 m; (B) medium organic-rich siliceous shale (MOSS), well LH2, 962.17 m; (C) medium organic-rich argillaceous shale, well LH2, 934 m; (D) low organic-rich shale (LOS), well LH3, 938.81 m.
Figure 4. Microscopic characteristics of the different lithofacies within the Chang 73 unit. (A) high organic-rich argillaceous shale (HOAS), well LH3, 939.72 m; (B) medium organic-rich siliceous shale (MOSS), well LH2, 962.17 m; (C) medium organic-rich argillaceous shale, well LH2, 934 m; (D) low organic-rich shale (LOS), well LH3, 938.81 m.
Energies 17 01140 g004
Energies 17 01140 g005
Figure 5. Organic geochemical characteristics of the shale in the Luohe oilfield. (A) Plot of S1 + S2 versus TOC. (B) Plot of pyrolysis Tmax versus TOC. (C) Plot of the hydrogen index (HI) versus the Tmax. (D) Plot of degradation rate versus Tmax.
Figure 5. Organic geochemical characteristics of the shale in the Luohe oilfield. (A) Plot of S1 + S2 versus TOC. (B) Plot of pyrolysis Tmax versus TOC. (C) Plot of the hydrogen index (HI) versus the Tmax. (D) Plot of degradation rate versus Tmax.
Energies 17 01140 g005
Energies 17 01140 g006
Figure 6. Mean porosity and permeability bar plot of each lithofacies in the Luohe area. (A) Mean porosity bar plot of each lithofacies in the Luohe area. (B) Mean permeability bar plot of each lithofacies in the Luohe area. HOAS: high organic-rich argillaceous shale; MOSS: medium organic-rich siliceous shale; MOAS: medium organic-rich argillaceous shale; LOS: low organic-rich shale.
Figure 6. Mean porosity and permeability bar plot of each lithofacies in the Luohe area. (A) Mean porosity bar plot of each lithofacies in the Luohe area. (B) Mean permeability bar plot of each lithofacies in the Luohe area. HOAS: high organic-rich argillaceous shale; MOSS: medium organic-rich siliceous shale; MOAS: medium organic-rich argillaceous shale; LOS: low organic-rich shale.
Energies 17 01140 g006
Energies 17 01140 g007
Figure 7. Microphotos of different pore types in the shale reservoir. (A) Intergranular pores, LH2, 970.99 m; (B) intercrystalline pores, LH3 935.96 m; (C) organic matter pores, and seams around organic matter, LH2 967.75 m; (D) intragranular pores, LH2 970.99 m; (E) intercrystalline pores, LH2 970.99 m; (F) intercrystalline pores, LH3 935.96 m.
Figure 7. Microphotos of different pore types in the shale reservoir. (A) Intergranular pores, LH2, 970.99 m; (B) intercrystalline pores, LH3 935.96 m; (C) organic matter pores, and seams around organic matter, LH2 967.75 m; (D) intragranular pores, LH2 970.99 m; (E) intercrystalline pores, LH2 970.99 m; (F) intercrystalline pores, LH3 935.96 m.
Energies 17 01140 g007
Energies 17 01140 g008
Figure 8. Pore diameter range and relative abundance of various pore types in the shale reservoir.
Figure 8. Pore diameter range and relative abundance of various pore types in the shale reservoir.
Energies 17 01140 g008
Energies 17 01140 g009
Figure 9. The NA experiments’ isothermal adsorption and desorption curves (IADC) of different lithofacies (A) The IADC of HOAS; sample 1: well LH2, 934.48 m; (B) the IADC of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 4: LH2 970.99 m; (C) the IADC of MOAS; sample 5: LH2 927.97 m, sample 6: LH2, 966.26; (D) the IADC of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m. AC: isothermal adsorption curves; DC: isothermal desorption curves.
Figure 9. The NA experiments’ isothermal adsorption and desorption curves (IADC) of different lithofacies (A) The IADC of HOAS; sample 1: well LH2, 934.48 m; (B) the IADC of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 4: LH2 970.99 m; (C) the IADC of MOAS; sample 5: LH2 927.97 m, sample 6: LH2, 966.26; (D) the IADC of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m. AC: isothermal adsorption curves; DC: isothermal desorption curves.
Energies 17 01140 g009
Energies 17 01140 g010
Figure 10. Capillary pressure curves of different lithofacies. (A) Capillary pressure curves of HOAS; well LH2, 934.48 m; (B) capillary pressure curves of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 4: LH2 970.99 m; (C) capillary pressure curves of MOAS; sample 5: LH2 927.97 m, sample 6: LH2, 966.26; (D) capillary pressure curves of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m.
Figure 10. Capillary pressure curves of different lithofacies. (A) Capillary pressure curves of HOAS; well LH2, 934.48 m; (B) capillary pressure curves of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 4: LH2 970.99 m; (C) capillary pressure curves of MOAS; sample 5: LH2 927.97 m, sample 6: LH2, 966.26; (D) capillary pressure curves of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m.
Energies 17 01140 g010
Energies 17 01140 g011
Figure 11. Unit volume of different pore sizes. (A) Unit volume versus pore size of HOAS; well LH2, 934.48 m; (B) unit volume versus pore size of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 9: LH2, 928.54 m; (C) unit volume versus pore size of MOAS; LH2 927.97 m; (D) unit volume versus pore size of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m.
Figure 11. Unit volume of different pore sizes. (A) Unit volume versus pore size of HOAS; well LH2, 934.48 m; (B) unit volume versus pore size of MOSS; sample 2: well LH2, 929.12 m, sample 3: LH2 931.7 m, sample 9: LH2, 928.54 m; (C) unit volume versus pore size of MOAS; LH2 927.97 m; (D) unit volume versus pore size of LOS; sample 7: LH2 877.36 m, sample 8: LH2 939.46 m.
Energies 17 01140 g011
Energies 17 01140 g012
Figure 12. Volumes of mesopores and macropores of different lithofacies. HOAS: high organic-rich argillaceous shale; MOSS: medium organic-rich siliceous shale; MOAS: medium organic-rich argillaceous shale; LOS: low organic-rich shale.
Figure 12. Volumes of mesopores and macropores of different lithofacies. HOAS: high organic-rich argillaceous shale; MOSS: medium organic-rich siliceous shale; MOAS: medium organic-rich argillaceous shale; LOS: low organic-rich shale.
Energies 17 01140 g012
Energies 17 01140 g013
Figure 13. Plot of S1 versus specific pore volume of different pore types. (A) Plot of S1 vs. specific pore volume of macropores; (B) plot of S1 vs. specific pore volume of mesopores.
Figure 13. Plot of S1 versus specific pore volume of different pore types. (A) Plot of S1 vs. specific pore volume of macropores; (B) plot of S1 vs. specific pore volume of mesopores.
Energies 17 01140 g013
Energies 17 01140 g014
Figure 14. Macropore volume versus different composition content. (A) Macropore volume versus TOC; (B) macropore volume versus quartz content; (C) macropore volume versus feldspar content; (D) macropore volume versus carbonate content; (E) macropore volume versus siliceous minerals contents; (F) macropore volume versus argillaceous mineral content.
Figure 14. Macropore volume versus different composition content. (A) Macropore volume versus TOC; (B) macropore volume versus quartz content; (C) macropore volume versus feldspar content; (D) macropore volume versus carbonate content; (E) macropore volume versus siliceous minerals contents; (F) macropore volume versus argillaceous mineral content.
Energies 17 01140 g014
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Li, Q.; You, X.; Li, J.; Zhou, Y.; Lu, H.; Wu, S.; Yue, D.; Zhang, H. Pore Structure and Factors Controlling Shale Reservoir Quality: A Case Study of Chang 7 Formation in the Southern Ordos Basin, China. Energies 2024, 17, 1140. https://doi.org/10.3390/en17051140

AMA Style

Li Q, You X, Li J, Zhou Y, Lu H, Wu S, Yue D, Zhang H. Pore Structure and Factors Controlling Shale Reservoir Quality: A Case Study of Chang 7 Formation in the Southern Ordos Basin, China. Energies. 2024; 17(5):1140. https://doi.org/10.3390/en17051140

Chicago/Turabian Style

Li, Qing, Xuelian You, Jiangshan Li, Yuan Zhou, Hao Lu, Shenghe Wu, Dali Yue, and Houmin Zhang. 2024. "Pore Structure and Factors Controlling Shale Reservoir Quality: A Case Study of Chang 7 Formation in the Southern Ordos Basin, China" Energies 17, no. 5: 1140. https://doi.org/10.3390/en17051140

APA Style

Li, Q., You, X., Li, J., Zhou, Y., Lu, H., Wu, S., Yue, D., & Zhang, H. (2024). Pore Structure and Factors Controlling Shale Reservoir Quality: A Case Study of Chang 7 Formation in the Southern Ordos Basin, China. Energies, 17(5), 1140. https://doi.org/10.3390/en17051140

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop