Catalytic Hydrogenation of CO2 to Methanol over Cu/MgO Catalysts in a Semi-Continuous Reactor
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
- Calcination: To prepare the catalyst carrier MgO, MagGran© granulate was calcined in air in a muffle furnace (Heraeus M110) for five hours under mild conditions at 723 K followed by two hours at 823 K (Equation (7)).
- Impregnation: The calcined MgO granulate (13 g, white) was impregnated with 0.25 dm3 of an aqueous copper(II) nitrate solution (cCu = 35 g dm−3) in a water cooled flask under constant stirring. After two hours, the impregnated catalyst precursor (blue) was filtered off and dried overnight in a drying furnace at 303 K.
- Thermal decomposition: The impregnated dry catalyst precursor was calcined in the muffle furnace for one hour at 423 K followed by five hours at 723 K (Equation (8)). Calcination resulted in a change of color from blue to black.
- Reduction (catalyst activation): To generate the catalytically active Cu0 sites, the calcined CuO/MgO precursor was treated in H2 atmosphere for 3.5 h in the tank reactor that was also used for the hydrogenation experiments (Equation (9)). The activation of the catalyst was performed at the reaction conditions of the CO2 hydrogenation experiments at 573 K and 5 MPa.
2.2. Experimental Setup and Procedure
2.3. Analysis
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Kleiber, S.; Pallua, M.; Siebenhofer, M.; Lux, S. Catalytic Hydrogenation of CO2 to Methanol over Cu/MgO Catalysts in a Semi-Continuous Reactor. Energies 2021, 14, 4319. https://doi.org/10.3390/en14144319
Kleiber S, Pallua M, Siebenhofer M, Lux S. Catalytic Hydrogenation of CO2 to Methanol over Cu/MgO Catalysts in a Semi-Continuous Reactor. Energies. 2021; 14(14):4319. https://doi.org/10.3390/en14144319
Chicago/Turabian StyleKleiber, Sascha, Moritz Pallua, Matthäus Siebenhofer, and Susanne Lux. 2021. "Catalytic Hydrogenation of CO2 to Methanol over Cu/MgO Catalysts in a Semi-Continuous Reactor" Energies 14, no. 14: 4319. https://doi.org/10.3390/en14144319