Implications on Feedstock Processing and Safety Issues for Semi-Batch Operations in Supercritical Water Gasification of Biomass
Abstract
:1. Introduction
- Feedstock should be used in a diluted form in SCWG, which means that water accounts for most of the inlet mass, which means that the medium expansion represents the major concern for pressure difference; and
- By using water only, the experimental results are more homogeneous; this gives a more stable data series.
2. Materials and Methods
2.1. Experimental Setup
2.2. Operational Conditions of SCWG
3. Results and Discussion
3.1. Pressure Fluctuations
3.2. Pressure Fluctuations in the Presence of Biomass
3.3. Safety Considerations and Improvement Opportunities
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
Nomenclature
Symbol | Physical Significance | Range | Units |
a | Burst pressure to wall thickness relation parameter, preexponential | 2.3824 | - |
b | Burst pressure to wall thickness relation parameter, exponent | −1.035 | - |
Reactor external diameter | 2.54 | cm | |
Reactor internal diameter | 1.43 | cm | |
Creep crack growth activation energy | 85–105 | kJ/mol | |
K | Stress intensity factor | 1–60 | MPa m1/2 |
Burst pressure | 70–150 | MPa | |
Reactor internal pressure | 220–260 | Bar | |
External pressure | 1 | Bar | |
Lower bound critical burst pressure | 50–200 | MPa | |
T | Reactor temperature | 420–650 | °C |
V | Reactor volume | 81.6 | cm3 |
Y | Geometric factor | 1 | - |
Crack growth rate to stress factor relation parameter, preexponential | |||
Crack growth rate to stress factor relation parameter, exponent | 7.5 | - | |
γ″ | Grain intermetallic structure | - | - |
Reactor wall thickness | 5.5 | mm | |
Material fracture width | 10−5–10−1 | mm | |
Material initial fracture width | 10−5–10−2 | mm | |
Creep crack growth rate | 10−9–10−4 | mm/s | |
Hoop stress | 5–130 | MPa | |
Ultimate tensile strength | 20–440 | MPa | |
Young modulus | 710–745 | MPa |
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Property | Value | Unit |
---|---|---|
Density (20 °C) | 8440 | kg/m3 |
Coeff. Of thermal expansion (538 °C) | 14 | µm/m·K |
Specific heat (21 °C) | 410 | J/Kg·K |
Thermal conductivity | 9.8 | W/m·K |
Tensile strength (21 °C) | 8550 | Bar |
Tensile strength (540 °C) | 7450 | Bar |
Tensile strength (650 °C) | 7100 | Bar |
Stress-rupture strength (650 °C; 100 h) | 4400 | Bar |
Stress-rupture strength (650 °C; 1000 h) | 3700 | Bar |
Maximum working pressure (21 °C) | 1360 | Bar |
Maximum working pressure (650 °C) | 1130 | Bar |
Series | Test Set Pressure (bar) | Minimum Reseal Pressure as Percentage of Set Pressure, % |
---|---|---|
RL3, RL4 | 0.7–1.3 | 50 |
12.0–15.5 | 91 | |
R3A, R4 | 6.8–13.7 | 50 |
58.5–68.9 | 84 |
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De Blasio, C.; Salierno, G.; Magnano, A. Implications on Feedstock Processing and Safety Issues for Semi-Batch Operations in Supercritical Water Gasification of Biomass. Energies 2021, 14, 2863. https://doi.org/10.3390/en14102863
De Blasio C, Salierno G, Magnano A. Implications on Feedstock Processing and Safety Issues for Semi-Batch Operations in Supercritical Water Gasification of Biomass. Energies. 2021; 14(10):2863. https://doi.org/10.3390/en14102863
Chicago/Turabian StyleDe Blasio, Cataldo, Gabriel Salierno, and Andrea Magnano. 2021. "Implications on Feedstock Processing and Safety Issues for Semi-Batch Operations in Supercritical Water Gasification of Biomass" Energies 14, no. 10: 2863. https://doi.org/10.3390/en14102863