Comparative Analysis of PM2.5-Bound Polycyclic Aromatic Hydrocarbons (PAHs), Nitro-PAHs (NPAHs), and Water-Soluble Inorganic Ions (WSIIs) at Two Background Sites in Japan
Abstract
:1. Introduction
2. Materials and Methods
2.1. PM2.5 Sampling
2.2. PAH, NPAH, and WSII Analysis
2.3. Data Analysis
3. Results
3.1. Concentrations
3.2. Compositions
4. Discussion
4.1. Meteorological Conditions
4.2. Diagnostic Ratios
4.3. Backward Trajectory Analysis
4.4. Acid–Base Balance of WSIIs
4.5. Potential Sources
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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WAMS | FAMS | ||||||||
---|---|---|---|---|---|---|---|---|---|
PC 1 | PC 2 | PC 3 | PC 4 | PC 1 | PC 2 | PC 3 | PC 4 | PC 5 | |
FR | 0.91 | 0.26 | −0.15 | 0.29 | 0.73 | 0.00 | 0.58 | 0.06 | 0.35 |
Pyr | 0.91 | 0.31 | −0.13 | 0.22 | 0.75 | 0.04 | 0.58 | 0.08 | 0.31 |
BaA | 0.87 | 0.44 | −0.11 | 0.02 | 0.96 | 0.14 | 0.14 | 0.07 | 0.15 |
Chr | 0.80 | 0.54 | −0.11 | 0.22 | 0.85 | 0.05 | 0.44 | 0.10 | 0.27 |
BbF | 0.83 | 0.49 | −0.09 | 0.22 | 0.96 | 0.16 | 0.21 | −0.03 | 0.08 |
BkF | 0.83 | 0.52 | −0.11 | 0.14 | 0.96 | 0.17 | 0.18 | 0.02 | 0.08 |
BaP | 0.85 | 0.50 | −0.11 | 0.06 | 0.96 | 0.05 | 0.22 | 0.07 | 0.13 |
BgPe | 0.87 | 0.47 | −0.08 | 0.13 | 0.95 | 0.24 | 0.17 | 0.04 | 0.03 |
IDP | 0.85 | 0.48 | −0.10 | 0.18 | 0.94 | 0.16 | 0.22 | 0.02 | 0.02 |
2-NFR | 0.69 | 0.68 | 0.02 | 0.12 | 0.92 | −0.09 | −0.16 | 0.24 | 0.10 |
2-NP | 0.77 | 0.52 | 0.18 | 0.09 | 0.25 | 0.07 | 0.14 | −0.19 | 0.93 |
1-NP | 0.74 | 0.58 | 0.08 | 0.22 | 0.84 | 0.02 | −0.11 | 0.25 | 0.15 |
Na+ | −0.13 | 0.11 | 0.95 | −0.07 | 0.58 | 0.54 | 0.06 | 0.18 | 0.56 |
NH4+ | 0.46 | 0.86 | −0.14 | 0.07 | 0.16 | −0.26 | 0.35 | 0.88 | −0.06 |
K+ | 0.77 | −0.09 | 0.12 | 0.47 | 0.09 | 0.27 | 0.90 | 0.13 | 0.14 |
Ca2+ | 0.32 | 0.16 | 0.13 | 0.91 | −0.04 | 0.87 | 0.40 | −0.21 | −0.05 |
Mg2+ | − * | 0.09 | 0.87 | 0.30 | −0.03 | 0.33 | |||
Cl− | 0.02 | −0.28 | 0.89 | 0.26 | 0.35 | 0.86 | −0.13 | −0.27 | −0.09 |
Br− | − * | − * | |||||||
NO3− | 0.83 | 0.25 | 0.10 | 0.44 | 0.54 | 0.28 | 0.74 | 0.09 | −0.06 |
SO42− | 0.36 | 0.91 | −0.07 | 0.07 | 0.17 | −0.11 | −0.06 | 0.96 | −0.09 |
% of Variance | 75.1% | 11.3% | 6.81% | 3.12% | 58.5% | 16.5% | 10.1% | 6.58% | 5.05% |
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Yang, L.; Zhang, L.; Zhang, H.; Zhou, Q.; Zhang, X.; Xing, W.; Takami, A.; Sato, K.; Shimizu, A.; Yoshino, A.; et al. Comparative Analysis of PM2.5-Bound Polycyclic Aromatic Hydrocarbons (PAHs), Nitro-PAHs (NPAHs), and Water-Soluble Inorganic Ions (WSIIs) at Two Background Sites in Japan. Int. J. Environ. Res. Public Health 2020, 17, 8224. https://doi.org/10.3390/ijerph17218224
Yang L, Zhang L, Zhang H, Zhou Q, Zhang X, Xing W, Takami A, Sato K, Shimizu A, Yoshino A, et al. Comparative Analysis of PM2.5-Bound Polycyclic Aromatic Hydrocarbons (PAHs), Nitro-PAHs (NPAHs), and Water-Soluble Inorganic Ions (WSIIs) at Two Background Sites in Japan. International Journal of Environmental Research and Public Health. 2020; 17(21):8224. https://doi.org/10.3390/ijerph17218224
Chicago/Turabian StyleYang, Lu, Lulu Zhang, Hao Zhang, Quanyu Zhou, Xuan Zhang, Wanli Xing, Akinori Takami, Kei Sato, Atsushi Shimizu, Ayako Yoshino, and et al. 2020. "Comparative Analysis of PM2.5-Bound Polycyclic Aromatic Hydrocarbons (PAHs), Nitro-PAHs (NPAHs), and Water-Soluble Inorganic Ions (WSIIs) at Two Background Sites in Japan" International Journal of Environmental Research and Public Health 17, no. 21: 8224. https://doi.org/10.3390/ijerph17218224