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Molbank
Volume 2024
Issue 4
10.3390/M1890
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Short Note

Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)]

by
Irina N. Meshcheryakova
1,*,
Nikolay O. Druzhkov
1,
Ilya A. Yakushev
2,
Kseniya V. Arsenyeva
1,
Anastasiya V. Klimashevskaya
1 and
Alexandr V. Piskunov
1,*
1
G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 49 Tropinina Str., 603950 Nizhny Novgorod, Russia
2
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninskii Prosp., 119071 Moscow, Russia
*
Authors to whom correspondence should be addressed.
Molbank 2024, 2024(4), M1890; https://doi.org/10.3390/M1890
Submission received: 4 September 2024 / Revised: 23 September 2024 / Accepted: 24 September 2024 / Published: 26 September 2024
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Abstract

A new cage-like dimeric nickel(II) complex Ni2L2(DMSO)4 based on a ditopic redox-active hydroxy-para-iminobenzoquinone type ligand LH2 (L is 4,4′-(1,3-phenylene-bis(azaneylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one dianion) was synthesized in DMSO at 120 °C. The molecular structure of the synthesized compound was determined by X-ray diffraction analysis. The complex Ni2L2(DMSO)4 is almost insoluble in all organic solvents, probably due to the presence of a large number of intermolecular contacts in its structure. The electronic spectrum and thermal stability of the crystalline compound have been studied.
Keywords: redox-active ligand; metal–organic cages; nickel(II); thermogravimetric analysis; X-ray diffraction analysis; UV spectroscopy redox-active ligand; metal–organic cages; nickel(II); thermogravimetric analysis; X-ray diffraction analysis; UV spectroscopy

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MDPI and ACS Style

Meshcheryakova, I.N.; Druzhkov, N.O.; Yakushev, I.A.; Arsenyeva, K.V.; Klimashevskaya, A.V.; Piskunov, A.V. Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)]. Molbank 2024, 2024, M1890. https://doi.org/10.3390/M1890

AMA Style

Meshcheryakova IN, Druzhkov NO, Yakushev IA, Arsenyeva KV, Klimashevskaya AV, Piskunov AV. Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)]. Molbank. 2024; 2024(4):M1890. https://doi.org/10.3390/M1890

Chicago/Turabian Style

Meshcheryakova, Irina N., Nikolay O. Druzhkov, Ilya A. Yakushev, Kseniya V. Arsenyeva, Anastasiya V. Klimashevskaya, and Alexandr V. Piskunov. 2024. "Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)]" Molbank 2024, no. 4: M1890. https://doi.org/10.3390/M1890

APA Style

Meshcheryakova, I. N., Druzhkov, N. O., Yakushev, I. A., Arsenyeva, K. V., Klimashevskaya, A. V., & Piskunov, A. V. (2024). Bis [4,4′-(1,3-Phenylenebis(azanylylidene))-bis(3,6-di-tert-butyl-2-oxycyclohexa-2,5-dien-1-one)-bis(dimethylsulfoxide)nickel(II)]. Molbank, 2024(4), M1890. https://doi.org/10.3390/M1890

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