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Volume 2023
Issue 2
10.3390/M1660
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[4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III)

by
Irina V. Ershova
,
Anton V. Cherkasov
and
Alexandr V. Piskunov
*
G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str., 603950 Nizhny Novgorod, Russia
*
Author to whom correspondence should be addressed.
Molbank 2023, 2023(2), M1660; https://doi.org/10.3390/M1660
Submission received: 19 May 2023 / Revised: 1 June 2023 / Accepted: 2 June 2023 / Published: 6 June 2023
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Abstract

A six-coordinated indium(III) complex (APMe)(imSQMe)In(bipy) (1), bearing two types of redox-active ligands—mono- (imSQMe) and dianion (APMe) of 4,6-di-tert-butyl-N-(2,6-dimethylphenyl)-o-iminobenzoquinone and 2,2′-bipyridyl—was synthesized and characterized in detail. The intense, well-resolved ESR spectrum of 1 in dichloromethane solution clearly indicates the spin density delocalization between both AP and imSQ ligands. The UV-vis spectrum of 1 possesses an absorption band in the NIR region. The molecular structure of compound 1 was established by single-crystal X-ray diffraction analysis.
Keywords: indium; redox-active ligand; o-amidophenolate; o-iminobenzosemiquinolate; bipyridyl; charge transfer; ESR; X-ray diffraction indium; redox-active ligand; o-amidophenolate; o-iminobenzosemiquinolate; bipyridyl; charge transfer; ESR; X-ray diffraction

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MDPI and ACS Style

Ershova, I.V.; Cherkasov, A.V.; Piskunov, A.V. [4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III). Molbank 2023, 2023, M1660. https://doi.org/10.3390/M1660

AMA Style

Ershova IV, Cherkasov AV, Piskunov AV. [4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III). Molbank. 2023; 2023(2):M1660. https://doi.org/10.3390/M1660

Chicago/Turabian Style

Ershova, Irina V., Anton V. Cherkasov, and Alexandr V. Piskunov. 2023. "[4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III)" Molbank 2023, no. 2: M1660. https://doi.org/10.3390/M1660

APA Style

Ershova, I. V., Cherkasov, A. V., & Piskunov, A. V. (2023). [4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Amidophenolato][4,6-Di-tert-butyl-N-(2,6-Dimethylphenyl)-o-Iminobenzosemiquinolato](2,2′-Bipyridyl)Indium(III). Molbank, 2023(2), M1660. https://doi.org/10.3390/M1660

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