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Short Note

1-Tosyl-6-vinyl-4,5,6,7-tetrahydro-1H-benzo [d] imidazole-2-amine

School of Chemistry, National University of Ireland, H91 TK33 Galway, Ireland
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Author to whom correspondence should be addressed.
Academic Editor: Nicholas E. Leadbeater
Molbank 2021, 2021(3), M1262; https://doi.org/10.3390/M1262
Received: 30 June 2021 / Revised: 26 July 2021 / Accepted: 28 July 2021 / Published: 31 July 2021
(This article belongs to the Section Organic Synthesis)
The alkene functionalised 2-aminobenzimidazole ring found in terrazoanthine natural products was synthesized in 3 steps from 1,2-epoxy-4-vinylcyclohexane via epoxide ring opening with toluenesulphonamide yielding 2 regioisomeric, separable amino alcohols. One isomer was oxidized to the corresponding ketone and subsequently condensed with cyanamide to furnish the title compound, which was characterized by 1H-NMR and 13C-NMR spectroscopy. View Full-Text
Keywords: natural products; synthesis; NMR spectroscopy; condensation; 2-aminoimidazole natural products; synthesis; NMR spectroscopy; condensation; 2-aminoimidazole
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MDPI and ACS Style

Meany, F.B.; O’Rourke, S.; Murphy, P.V. 1-Tosyl-6-vinyl-4,5,6,7-tetrahydro-1H-benzo [d] imidazole-2-amine. Molbank 2021, 2021, M1262. https://doi.org/10.3390/M1262

AMA Style

Meany FB, O’Rourke S, Murphy PV. 1-Tosyl-6-vinyl-4,5,6,7-tetrahydro-1H-benzo [d] imidazole-2-amine. Molbank. 2021; 2021(3):M1262. https://doi.org/10.3390/M1262

Chicago/Turabian Style

Meany, Fiach B., Sarah O’Rourke, and Paul V. Murphy 2021. "1-Tosyl-6-vinyl-4,5,6,7-tetrahydro-1H-benzo [d] imidazole-2-amine" Molbank 2021, no. 3: M1262. https://doi.org/10.3390/M1262

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