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Short Note

tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate

1
N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
2
Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia
*
Author to whom correspondence should be addressed.
Academic Editor: Bartolo Gabriele
Molbank 2021, 2021(3), M1247; https://doi.org/10.3390/M1247
Received: 10 June 2021 / Revised: 21 June 2021 / Accepted: 23 June 2021 / Published: 5 July 2021
(This article belongs to the Special Issue Metal-Catalyzed Synthesis)
New donor building blocks, i.e., triarylamino derivatives, are of great interest for the production of organic photovoltaic materials. In this communication, bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine was synthesized in a two-step process via hydrolysis of its tert-butyl carbamate derivative. tert-Butyl bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate was obtained by Suzuki cross-coupling reaction of tert-butyl bis(4-bromophenyl)carbamate and (4-(hexyloxy)phenyl)boronic acid in the presence of tetrakis(triphenylphosphine)palladium(0). The structure of newly synthesized compounds was established by means of elemental analysis, high resolution mass-spectrometry, 1H, 13C-NMR, IR and UV spectroscopy and mass-spectrometry. View Full-Text
Keywords: donor building blocks; Suzuki cross-coupling reaction; triarylamines; bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine donor building blocks; Suzuki cross-coupling reaction; triarylamines; bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine
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MDPI and ACS Style

Chmovzh, T.N.; Rakitin, O.A. tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate. Molbank 2021, 2021, M1247. https://doi.org/10.3390/M1247

AMA Style

Chmovzh TN, Rakitin OA. tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate. Molbank. 2021; 2021(3):M1247. https://doi.org/10.3390/M1247

Chicago/Turabian Style

Chmovzh, Timofey N., and Oleg A. Rakitin 2021. "tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate" Molbank 2021, no. 3: M1247. https://doi.org/10.3390/M1247

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