Next Article in Journal
Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination
Previous Article in Journal
Previous Article in Special Issue
Short Note

tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate

N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia
Author to whom correspondence should be addressed.
Academic Editor: Bartolo Gabriele
Molbank 2021, 2021(3), M1247;
Received: 10 June 2021 / Revised: 21 June 2021 / Accepted: 23 June 2021 / Published: 5 July 2021
(This article belongs to the Special Issue Metal-Catalyzed Synthesis)
New donor building blocks, i.e., triarylamino derivatives, are of great interest for the production of organic photovoltaic materials. In this communication, bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine was synthesized in a two-step process via hydrolysis of its tert-butyl carbamate derivative. tert-Butyl bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate was obtained by Suzuki cross-coupling reaction of tert-butyl bis(4-bromophenyl)carbamate and (4-(hexyloxy)phenyl)boronic acid in the presence of tetrakis(triphenylphosphine)palladium(0). The structure of newly synthesized compounds was established by means of elemental analysis, high resolution mass-spectrometry, 1H, 13C-NMR, IR and UV spectroscopy and mass-spectrometry. View Full-Text
Keywords: donor building blocks; Suzuki cross-coupling reaction; triarylamines; bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine donor building blocks; Suzuki cross-coupling reaction; triarylamines; bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine
Show Figures

Scheme 1

MDPI and ACS Style

Chmovzh, T.N.; Rakitin, O.A. tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate. Molbank 2021, 2021, M1247.

AMA Style

Chmovzh TN, Rakitin OA. tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate. Molbank. 2021; 2021(3):M1247.

Chicago/Turabian Style

Chmovzh, Timofey N., and Oleg A. Rakitin 2021. "tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate" Molbank 2021, no. 3: M1247.

Find Other Styles
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Access Map by Country/Region

Back to TopTop