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Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination

Department of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana, Slovenia
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Academic Editor: Kristof Van Hecke
Molbank 2021, 2021(3), M1249; https://doi.org/10.3390/M1249
Received: 16 June 2021 / Revised: 23 June 2021 / Accepted: 25 June 2021 / Published: 6 July 2021
(This article belongs to the Section Structure Determination)
(PyH)2[MoOCl5] was obtained in the form of emerald green crystals unintentionally from (PyH)5[MoOCl4(H2O)]3Cl2 in acetonitrile. (PyH)2[MoOCl5] has been used as a starting material in molybdenum(V) coordination chemistry for decades, yet its true identity has not been known until now. The X-ray structure analysis has undoubtedly confirmed the existence of this compound. The [MoOCl5]2− ion displays the usual structural characteristics of the mononuclear MoO3+-containing compounds. View Full-Text
Keywords: pentachloridooxomolybdate(V); molybdenum; coordination chemistry; crystal structure pentachloridooxomolybdate(V); molybdenum; coordination chemistry; crystal structure
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MDPI and ACS Style

Šturm, J.; Modec, B. Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination. Molbank 2021, 2021, M1249. https://doi.org/10.3390/M1249

AMA Style

Šturm J, Modec B. Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination. Molbank. 2021; 2021(3):M1249. https://doi.org/10.3390/M1249

Chicago/Turabian Style

Šturm, Jaka, and Barbara Modec. 2021. "Pyridinium Pentachloridooxomolybdate(V), (PyH)2[MoOCl5], Revisited: Single-Crystal X-ray Structure Determination" Molbank 2021, no. 3: M1249. https://doi.org/10.3390/M1249

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