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Molbank 2018, 2018(4), M1035; https://doi.org/10.3390/M1035

1-(2-Hydroxyethyl)imidazolidine-2-thione

Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, Bandar Sunway 47500, Malaysia
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Received: 13 November 2018 / Revised: 27 November 2018 / Accepted: 30 November 2018 / Published: 3 December 2018
(This article belongs to the Section Structure Determination)
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Abstract

1-(2-Hydroxyethyl)imidazolidine-2-thione (1) was obtained as a product from an in situ reaction between N-(2-hydroxyethyl)ethylenediamine, carbon disulfide, potassium hydroxide, and di(4-fluorobenzyl)tin dichloride. Compound 1 was characterized by IR, UV, 1H, 13C{1H}, and 2D (COSY, NOESY, HSQC, and HMBC) NMR spectroscopies. The cyclic molecular structure was confirmed by single crystal X-ray crystallography which showed the five-membered ring to be non-planar and the π-electron density to be localized over the CN2S chromophore. In the crystal, thioamide–N–HO(hydroxy) and hydroxy–O–HS(thione) hydrogen bonds lead to supramolecular layers in the bc-plane. View Full-Text
Keywords: cyclization reaction; imidazolidine-2-thione; dithiocarbamate; 2D NMR; X-ray crystallography cyclization reaction; imidazolidine-2-thione; dithiocarbamate; 2D NMR; X-ray crystallography
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Lee, S.M.; Azizan, A.H.S.; Tiekink, E.R.T. 1-(2-Hydroxyethyl)imidazolidine-2-thione. Molbank 2018, 2018, M1035.

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