Crystallization Pathways of FABr-PbBr2-DMF and FABr-PbBr2-DMSO Systems: The Comprehensive Picture of Formamidinium-Based Low-Dimensional Perovskite-Related Phases and Intermediate Solvates
Abstract
:1. Introduction
2. Results and Discussion
2.1. FABr-PbBr2-DMF/DMSO Systems: Equilibrium State
2.2. FABr-PbBr2-DMF/DMSO System: Thin Films
3. Materials and Methods
3.1. Materials
3.2. Single Crystal Growth
3.3. Single-Crystal X-ray Diffraction (XRD)
3.4. Powder X-ray Diffraction
3.5. Thin Films Preparation
3.6. Photoluminescence Measurements
3.7. DFT Calculations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Phase | FA3PbBr5 |
---|---|
Appearance | needle-shaped crystals |
Crystal system | monoclinic |
Space group | C2/c |
Unit cell parameters | a = 12.466(3) Å, b = 11.465(2) Å, c = 11.868(3) Å, α = 90°, β = 99.029(6)°, γ = 90° |
Cell volume, Å3 | 1675.2(7) |
Z | 4 |
Density (calculated), g/cm3 | 2.943 |
Reflections collected | 12281 |
Independent reflections | 3040 |
data/restraints/parameters | 3040/41/72 |
goodness-of-fit | 1.013 |
final R indices [I > 2σ(I)] | Robs = 0.0571, wRobs = 0.1347 |
R indices [all data] | Rall = 0.0931, wRall = 0.1553 |
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Fateev, S.A.; Marchenko, E.I.; Shatilova, A.S.; Khrustalev, V.N.; Goodilin, E.A.; Tarasov, A.B. Crystallization Pathways of FABr-PbBr2-DMF and FABr-PbBr2-DMSO Systems: The Comprehensive Picture of Formamidinium-Based Low-Dimensional Perovskite-Related Phases and Intermediate Solvates. Int. J. Mol. Sci. 2022, 23, 15344. https://doi.org/10.3390/ijms232315344
Fateev SA, Marchenko EI, Shatilova AS, Khrustalev VN, Goodilin EA, Tarasov AB. Crystallization Pathways of FABr-PbBr2-DMF and FABr-PbBr2-DMSO Systems: The Comprehensive Picture of Formamidinium-Based Low-Dimensional Perovskite-Related Phases and Intermediate Solvates. International Journal of Molecular Sciences. 2022; 23(23):15344. https://doi.org/10.3390/ijms232315344
Chicago/Turabian StyleFateev, Sergey A., Ekaterina I. Marchenko, Alexandra S. Shatilova, Victor N. Khrustalev, Eugene A. Goodilin, and Alexey B. Tarasov. 2022. "Crystallization Pathways of FABr-PbBr2-DMF and FABr-PbBr2-DMSO Systems: The Comprehensive Picture of Formamidinium-Based Low-Dimensional Perovskite-Related Phases and Intermediate Solvates" International Journal of Molecular Sciences 23, no. 23: 15344. https://doi.org/10.3390/ijms232315344