Dopamine Photochemical Behaviour under UV Irradiation
Abstract
:1. Introduction
2. Materials and Methods
2.1. Samples’ Preparation
2.2. Steady-State UV–Vis Absorption and Fluorescence Spectroscopy
2.3. Time-Resolved Fluorescence Spectroscopy
2.4. Theoretical Methods
3. Results and Discussion
3.1. UV–Vis Absorption and Fluorescence Spectra
3.2. Fluorescence Lifetimes and Quantum Yield
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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State | Geometries | ||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
DA | DA | DAH | DAH | ||||||||
S | 266 | 0.0275 | 292 | 0.0014 | 270 | 0.0379 | 302 | 0.0009 | |||
S | 226 | 0.0024 | 286 | 0.0803 | 222 | 0.0011 | 287 | 0.0858 | |||
S | 208 | 0.0637 | 249 | 0.0008 | 209 | 0.0378 | 255 | 0.0033 | |||
S | 242 | 0.0033 | 250 | 0.0164 | |||||||
S | 239 | 0.0088 | 230 | 0.0947 | |||||||
S | 224 | 0.0108 | 226 | 0.1094 | |||||||
S | 216 | 0.0119 | 219 | 0.0050 | |||||||
S | 214 | 0.0034 | 216 | 0.0018 | |||||||
S | 211 | 0.0045 | 216 | 0.0107 | |||||||
S | 209 | 0.0351 | 211 | 0.0002 |
pH | Solution | Reconv. Method | (ns) | Error | Ampl. (%) | (ns) | Error | Ampl. (%) | (ns) | Error |
---|---|---|---|---|---|---|---|---|---|---|
5.5 | Concentrated | 1-exp | 0.89 | 0.01 | 100 | - | - | - | - | - |
2-exp | 0.91 | 0.02 | 99.58 | 4.86 | 0.38 | 0.42 | 0.99 | 0.03 | ||
Diluted | 1-exp | 0.93 | 0.07 | 100 | - | - | - | - | - | |
8.0 | Concentrated | 2-exp | 0.89 | 0.01 | 95.83 | 2.98 | 0.20 | 4.17 | 0.97 | 0.05 |
Diluted | 2-exp | 0.71 | 0.10 | 88.97 | 3.23 | 0.24 | 11.03 | 1.56 | 0.15 | |
9.0 | Concentrated | 2-exp | 0.69 | 0.02 | 92.61 | 2.41 | 0.20 | 7.40 | 0.82 | 0.01 |
Diluted | 2-exp | 0.64 | 0.10 | 88.20 | 2.96 | 0.18 | 11.80 | 0.91 | 0.11 |
DA | DA | DAH | DAH | |
---|---|---|---|---|
FC | 4.39 × 10 | 8.47 × 10 | 4.70 × 10 | 1.36 × 10 |
(100%) | (100%) | (100%) | (100%) | |
FC+HT | 3.79 × 10 | 2.75 × 10 | 4.51 × 10 | 1.14 × 10 |
(86%, 14%) | (0%, 100%) | (96%, 4%) | (1%, 99%) | |
FC+(HT+D ) | 3.16 × 10 | 1.02 × 10 | 2.95 × 10 | 7.10 × 10 |
(81%, 19%) | (0%, 100%) | (78%, 22%) | (0%, 100%) |
pH | Solution | QY (%) |
---|---|---|
5.5 | Concentrated | 3.4 |
Diluted | 3.4 | |
8.0 | Concentrated | 2.0 |
Diluted | 2.4 |
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Falamaş, A.; Petran, A.; Hada, A.-M.; Bende, A. Dopamine Photochemical Behaviour under UV Irradiation. Int. J. Mol. Sci. 2022, 23, 5483. https://doi.org/10.3390/ijms23105483
Falamaş A, Petran A, Hada A-M, Bende A. Dopamine Photochemical Behaviour under UV Irradiation. International Journal of Molecular Sciences. 2022; 23(10):5483. https://doi.org/10.3390/ijms23105483
Chicago/Turabian StyleFalamaş, Alexandra, Anca Petran, Alexandru-Milentie Hada, and Attila Bende. 2022. "Dopamine Photochemical Behaviour under UV Irradiation" International Journal of Molecular Sciences 23, no. 10: 5483. https://doi.org/10.3390/ijms23105483