On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis
Abstract
:1. Introduction
2. Results and Discussion
2.1. Pnictogen Bonding
Arsenic and Antimony
2.2. Chalcogen Bonding
Selenium and Tellurium
3. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Pn | α | RvdW | MEP (PnF3) |
---|---|---|---|
N | 5.3 | 1.55 | 15.9 |
P | 16.9 | 1.80 | 27.4 |
As | 21.6 | 1.85 | 38.5 |
Sb | 30.8 | 2.06 | 46.7 |
Pn-Catalyst | KD | ||||
P(PFP)3 | N/A | ||||
As(PFP)3 | 13,300 ± 800 | ||||
Sb(Ph)3 | N/A | ||||
Sb(Ph)2PFP | N/A | Ch-Catalyst | KD | Ha-Catalyst | KD |
SbPh(PFP)2 | 570 ± 70 | Se(PFP)2 | 27,000 ± 4000 | BrPFP | N/A |
Sb(PFP)3 | 19 ± 7 | Te(PFP)2 | 470 ± 70 | IPFP | 1370 ± 30 |
Ch | α | RvdW | MEP (ChF2) |
---|---|---|---|
O | 3.0 | 1.52 | 16.8 |
S | 11.8 | 1.80 | 35.6 |
Se | 17.5 | 1.90 | 44.9 |
Te | 25.9 | 2.06 | 52.6 |
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Frontera, A.; Bauza, A. On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis. Int. J. Mol. Sci. 2021, 22, 12550. https://doi.org/10.3390/ijms222212550
Frontera A, Bauza A. On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis. International Journal of Molecular Sciences. 2021; 22(22):12550. https://doi.org/10.3390/ijms222212550
Chicago/Turabian StyleFrontera, Antonio, and Antonio Bauza. 2021. "On the Importance of Pnictogen and Chalcogen Bonding Interactions in Supramolecular Catalysis" International Journal of Molecular Sciences 22, no. 22: 12550. https://doi.org/10.3390/ijms222212550