A Rare Natural Benzo[k,l]xanthene as a Turn-Off Fluorescent Sensor for Cu2+ Ion
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
3.1. Preparation of Methyl Ester of Caffeic Acid
3.2. Preparation of Dimethyl 6,9,10-Trihydroxybenzo[k,l]Xanthene-1,2-Dicarboxylate (1)
3.3. Preparation of UV-Vis and Fluorometric Titration Solutions
3.4. Theoretical Calculations
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Atom | O25 | O26 | O65 | O66 | O105 | O106 |
---|---|---|---|---|---|---|
Wiberg bond index | 0.1263 | 0.2850 | 0.2300 | 0.2717 | 0.1283 | 0.2850 |
Donor NBO | Acceptor NBO | Energy (kcal/mol) |
---|---|---|
LP O25 | LP* Cu121 | 3.93 |
LP O25 | LP* Cu121 | 3.81 |
LP O26 | LP* Cu121 | 13.86 |
LP O26 | LP* Cu121 | 12.08 |
LP O65 | LP* Cu121 | 11.28 |
LP O65 | LP* Cu121 | 10.14 |
LP O66 | LP* Cu121 | 13.21 |
LP O66 | LP* Cu121 | 9.71 |
LP O105 | LP* Cu121 | 4.24 |
LP O105 | LP* Cu121 | 3.89 |
LP O106 | LP* Cu121 | 12.87 |
LP O106 | LP* Cu121 | 12.49 |
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Floresta, G.; Cardullo, N.; Spatafora, C.; Rescifina, A.; Tringali, C. A Rare Natural Benzo[k,l]xanthene as a Turn-Off Fluorescent Sensor for Cu2+ Ion. Int. J. Mol. Sci. 2020, 21, 6933. https://doi.org/10.3390/ijms21186933
Floresta G, Cardullo N, Spatafora C, Rescifina A, Tringali C. A Rare Natural Benzo[k,l]xanthene as a Turn-Off Fluorescent Sensor for Cu2+ Ion. International Journal of Molecular Sciences. 2020; 21(18):6933. https://doi.org/10.3390/ijms21186933
Chicago/Turabian StyleFloresta, Giuseppe, Nunzio Cardullo, Carmela Spatafora, Antonio Rescifina, and Corrado Tringali. 2020. "A Rare Natural Benzo[k,l]xanthene as a Turn-Off Fluorescent Sensor for Cu2+ Ion" International Journal of Molecular Sciences 21, no. 18: 6933. https://doi.org/10.3390/ijms21186933