Two-Dimensional Materials: From Synthesis to Applications
1. Introduction
2. Synthesis and Characterization: Building the Foundation of 2D Materials
- Hexagonal boron nitride thin films.This study employed high-power impulse reactive magnetron sputtering to deposit hexagonal boron nitride (h-BN) thin films. By tuning deposition parameters such as temperature, nitrogen flow, and time, the team achieved control over crystallinity, surface roughness, and chemical composition. The results provide insights into optimizing h-BN films for electronic and optical devices, underscoring the importance of process parametrization. (Contribution 1).
- Carbon nitride nanosheets for silica film adhesion.A critical challenge in fabricating VMSF is ensuring their stability on carbonaceous electrodes. This study demonstrated that carbon nitride nanosheets act as effective adhesive layers, improving the mechanical stability of VMSF. This enhancement enabled the development of robust immunosensors with broad detection ranges, highlighting the role of hybrid material interfaces. (Contribution 2).
- GO-based anticorrosion coatings.Functionalizing GO with ethylenediamine introduced a sustainable way to enhance waterborne polyurethane coatings’ anticorrosion performance. The low GO content effectively improved the coatings’ barrier properties, offering environmentally friendly solutions for corrosion protection. This study illustrates the potential of GO-based additives for large-scale industrial applications. (Contribution 3).
3. Energy Applications: Powering a Sustainable Future
- MoS2-based broadband solar absorbers.A single-layer molybdenum disulfide (MoS2) was used to design a broadband solar absorber with exceptional absorption efficiency, maintaining over 95% absorption across a wide spectral range. The absorber’s polarization insensitivity and thermal stability make it a promising candidate for photovoltaics and other energy conversion applications. (Contribution 4).
- Photocatalytic water splitting with GeC/ heterojunctions.GeC/ ( Zr, Hf; S, Se) heterojunctions were explored for water splitting. These structures demonstrated strong light-harvesting capabilities, small bandgaps, and efficient charge carrier separation due to built-in electric fields at the heterointerface. This research emphasizes the potential of 2D materials for producing clean hydrogen energy. (Contribution 5).
- Catalysts for hydrogen evolution reaction.A gold nanoparticle–mesoporous carbon composite was developed as a catalyst for hydrogen evolution. The material achieved high stability and low activation energy, making it an efficient solution for sustainable hydrogen production. This work exemplifies the importance of 2D material composites in addressing the growing energy demands. (Contribution 6).
- Pt-Pd nanoparticles for fuel cells.Pt-Pd alloy nanoparticles anchored on graphene nanoplates demonstrated enhanced mass activity and durability in oxygen reduction reactions. These materials hold significant promise for advancing proton exchange membrane fuel cells, a key technology for clean energy systems. (Contribution 7).
4. Environmental and Catalytic Applications
- Tribocatalytic degradation of antibiotics.Rare-earth-modified zinc oxide powders were shown to degrade tetracycline antibiotics using triboelectric effects. This approach converts mechanical energy into catalytic activity, providing a sustainable method for water purification and pollution control. (Contribution 8).
- Gas desulfurization with recycled graphite.Recycled graphite from spent Zn/C batteries was transformed into reduced GO-based sorbents. These materials demonstrated competitive desulfurization performance, offering a cost-effective and environmentally friendly alternative to commercial sorbents. (Contribution 9).
- Ethylene adsorption for agricultural applications.Activated carbons derived from agricultural waste were impregnated with copper oxide, significantly improving ethylene adsorption. This innovation has practical applications in prolonging the post-harvest life of fruits and vegetables, showcasing the versatility of 2D materials in agriculture. (Contribution 10).
5. Sensors and Optoelectronics
- Graphene nanoplatelets for optoelectronics.Graphene nanoplatelets integrated with amorphous germanium substrates exhibited enhanced optical absorption and increased refractive indices. These findings pave the way for the development of high-performance optoelectronic devices, such as photodetectors and solar cells. (Contribution 11).
- Modified quantum dots for optical devices.Theoretical studies on GaAs quantum dots with modified confining potentials revealed tunable optical absorption coefficients. This study contributes to the design of new optoelectronic devices leveraging inter-sub-band transitions. (Contribution 12).
6. Theoretical Insights and Fundamental Studies
- Topological insulators and magnetic proximity.Bi2Se3/CrWI6 heterostructure was studied to achieve magnetic proximity-induced spin splitting, enabling the quantum anomalous Hall effect. This study advances the field of topological insulators, essential for quantum computing and spintronics. (Contribution 13).
- Cation– interactions in graphene.Pi-stacked host molecules were synthesized to study their interactions with metal cations. The results demonstrated enhanced binding in stacked configurations, informing the design of materials for ion intercalation and energy storage. (Contribution 14).
- Corrosion potentials of zinc alloys.Using DFT simulations, researchers analyzed the corrosion behavior of zinc alloys in various harsh environments. The findings provide valuable indicators for developing biodegradable metals and corrosion-resistant coatings. (Contribution 15).
7. Advanced Functional Materials
- GO/MXene composite membranes for ion separation.Polyethyleneimine-coated GO/MXene membranes exhibited high efficiency in separating Mg and Li+ ions from salt lake brines. This technology addresses the critical need for lithium extraction in renewable energy systems. (Contribution 16).
- Biomass-derived catalysts for sulfonylation.A biomass-derived copper catalyst enabled efficient sulfonylation of aniline derivatives, demonstrating a recyclable and sustainable approach to heterogeneous catalysis. (Contribution 17).
8. Conclusions
Funding
Acknowledgments
Conflicts of Interest
Abbreviations
2D | Two-dimensional |
GO | Graphene oxide |
SI | Special Issue |
VMSF | Vertically ordered mesoporous silica films |
DFT | Density functional theory |
List of Contributions
- Stankus, V.; Vasiliauskas, A.; Guobienė, A.; Andrulevičius, M.; Meškinis, Š. Synthesis and Characterization of Boron Nitride Thin Films Deposited by High-Power Impulse Reactive Magnetron Sputtering. Molecules 2024, 29, 5247. https://doi.org/10.3390/molecules29225247.
- Xing, J.; Wang, H.; Yan, F. Carbon Nitride Nanosheets as an Adhesive Layer for Stable Growth of Vertically-Ordered Mesoporous Silica Film on a Glassy Carbon Electrode and Their Application for CA15-3 Immunosensor. Molecules 2024, 29, 4334. https://doi.org/10.3390/molecules29184334.
- Aramayo, M.A.F.; Ferreira Fernandes, R.; Santos Dias, M.; Bozzo, S.; Steinberg, D.; Rocha Diniz da Silva, M.; Maroneze, C.M.; de Carvalho Castro Silva, C. Eco-Friendly Waterborne Polyurethane Coating Modified with Ethylenediamine-Functionalized Graphene Oxide for Enhanced Anticorrosion Performance. Molecules 2024, 29, 4163. https://doi.org/10.3390/molecules29174163.
- Liu, W.; Wu, F.; Yi, Z.; Tang, Y.; Yi, Y.; Wu, P.; Zeng, Q. Broadband Solar Absorber and Thermal Emitter Based on Single-Layer Molybdenum Disulfide. Molecules 2024, 29, 4515. https://doi.org/10.3390/molecules29184515.
- Wang, G.; Xie, W.; Guo, S.; Chang, J.; Chen, Y.; Long, X.; Zhou, L.; Ang, Y.S.; Yuan, H. Two-Dimensional GeC/MXY (M = Zr, Hf; X, Y = S, Se) Heterojunctions Used as Highly Efficient Overall Water-Splitting Photocatalysts. Molecules 2024, 29, 2793. https://doi.org/10.3390/molecules29122793.
- Biehler, E.; Quach, Q.; Abdel-Fattah, T.M. Gold Nanoparticle Mesoporous Carbon Composite as Catalyst for Hydrogen Evolution Reaction. Molecules 2024, 29, 3707. https://doi.org/10.3390/molecules29153707.
- Yaldagard, M.; Arkas, M. Enhanced Mass Activity and Durability of Bimetallic Pt-Pd Nanoparticles on Sulfated-Zirconia-Doped Graphene Nanoplates for Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cell Applications. Molecules 2024, 29, 2129. https://doi.org/10.3390/molecules29092129.
- Ivanova, D.; Kolev, H.; Stefanov, B.I.; Kaneva, N. Enhanced Tribodegradation of a Tetracycline Antibiotic by Rare-Earth-Modified Zinc Oxide. Molecules 2024, 29, 3913. https://doi.org/10.3390/molecules29163913.
- Fernández-Martínez, R.; Ortiz, I.; Gómez-Mancebo, M.B.; Alcaraz, L.; Fernández, M.; López, F.A.; Rucandio, I.; Sánchez-Hervás, J.M. Transformation of Graphite Recovered from Batteries into Functionalized Graphene-Based Sorbents and Application to Gas Desulfurization. Molecules 2024, 29, 3577. https://doi.org/10.3390/molecules29153577.
- Oliveira, A.C.d.J.; Rodrigues, C.A.P.; de Almeida, M.C.; Mársico, E.T.; Scalize, P.S.; de Oliveira, T.F.; Solar, V.A.; Valdés, H. Ethylene Elimination Using Activated Carbons Obtained from Baru (Dipteryx alata vog.) Waste and Impregnated with Copper Oxide. Molecules 2024, 29, 2717. https://doi.org/10.3390/molecules29122717.
- Politano, G.G. Optical Properties of Graphene Nanoplatelets on Amorphous Germanium Substrates. Molecules 2024, 29, 4089. https://doi.org/10.3390/molecules29174089.
- Alauwaji, R.M.; Dakhlaoui, H.; Algraphy, E.; Ungan, F.; Wong, B.M. Binding Energies and Optical Properties of Power-Exponential and Modified Gaussian Quantum Dots. Molecules 2024, 29, 3052. https://doi.org/10.3390/molecules29133052.
- Huang, H.; He, F.; Liu, Q.; Yu, Y.; Zhang, M. Magnetic Exchange Mechanism and Quantized Anomalous Hall Effect in Bi2Se3 Film with a CrWI6 Monolayer. Molecules 2024, 29, 4101. https://doi.org/10.3390/molecules29174101.
- Uetake, Y.; Takemura, H. Complex Formation of Ag+ and Li+ with Host Molecules Modeled on Intercalation of Graphite. Molecules 2024, 29, 3987. https://doi.org/10.3390/molecules29173987.
- Mukhametov, A.; Samikov, I.; Korznikova, E.A.; Kistanov, A.A. Density Functional Theory-Based Indicators to Estimate the Corrosion Potentials of Zinc Alloys in Chlorine-, Oxidizing-, and Sulfur-Harsh Environments. Molecules 2024, 29, 3790. https://doi.org/10.3390/molecules29163790.
- Wang, J.; Wang, A.; Liu, J.; Niu, Q.; Zhang, Y.; Liu, P.; Liu, C.; Wang, H.; Zeng, X.; Zeng, G. Polyethyleneimine Modified Two-Dimensional GO/MXene Composite Membranes with Enhanced Mg/Li+ Separation Performance for Salt Lake Brine. Molecules 2024, 29, 4326. https://doi.org/10.3390/molecules29184326.
- Yan, X.; Wang, J.; Chen, C.; Zheng, K.; Zhang, P.; Shen, C. Remote Sulfonylation of Anilines with Sodium Sulfifinates Using Biomass-Derived Copper Catalyst. Molecules 2024, 29, 4815. https://doi.org/10.3390/molecules29204815.
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- Molecules|Special Issue: Two-Dimensional Materials: From Synthesis to Applications, 2nd Edition. Available online: https://www.mdpi.com/journal/molecules/special_issues/VY337364WE (accessed on 25 January 2025).
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Wang, S.; Hung, N.T.; Sun, M. Two-Dimensional Materials: From Synthesis to Applications. Molecules 2025, 30, 741. https://doi.org/10.3390/molecules30030741
Wang S, Hung NT, Sun M. Two-Dimensional Materials: From Synthesis to Applications. Molecules. 2025; 30(3):741. https://doi.org/10.3390/molecules30030741
Chicago/Turabian StyleWang, Sake, Nguyen Tuan Hung, and Minglei Sun. 2025. "Two-Dimensional Materials: From Synthesis to Applications" Molecules 30, no. 3: 741. https://doi.org/10.3390/molecules30030741
APA StyleWang, S., Hung, N. T., & Sun, M. (2025). Two-Dimensional Materials: From Synthesis to Applications. Molecules, 30(3), 741. https://doi.org/10.3390/molecules30030741