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Article

Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components

1
Institute of Cultural Heritage and History of Science & Technology, University of Science and Technology Beijing, Beijing 100083, China
2
National Center for Archaeology, Beijing 100013, China
3
Shanxi Provincial Institute for the Protection of Ancient Buildings, Painted Sculptures and Murals, Taiyuan 030000, China
4
Department of Chemistry, Tsinghua University, Beijing 100084, China
*
Authors to whom correspondence should be addressed.
Molecules 2023, 28(4), 1946; https://doi.org/10.3390/molecules28041946
Submission received: 28 January 2023 / Revised: 10 February 2023 / Accepted: 14 February 2023 / Published: 17 February 2023
(This article belongs to the Special Issue Recent Advances in Wood Chemistry)

Abstract

A greater understanding of moisture sorption behaviour of aged wooden structural components, which has a close relationship with dimensional stability, is required to effectively evaluate and preserve historical artefacts. This study focused on the effects of aging on Baotou beam samples from a Chinese historical wooden building. An analysis of the sorption isotherms and hysteresis loops of a naturally aged, decayed sample (AOS), an aged sound sample (AIS), and a reference sample (RS), using classical sorption isotherm models revealed that the moisture sorption behaviour of samples from the same growth ring in a Baotou beam can differ significantly. AOS showed higher hygroscopicity than AIS, and both these samples were more hygroscopic than RS. Furthermore, the mono/multilayer moisture contents of AOS were always higher than those of AIS and RS. In addition, Fourier transform infrared, second-derivative infrared, and two-dimensional correlation infrared spectroscopy were used to investigate chemical changes in the samples. The relative hemicellulose and lignin contents of the samples changed significantly with wood aging. Furthermore, AOS exhibited the highest calcium oxalate content, which may be associated with fungal infections. Overall, these results provide valuable insights into the effects of aging on wood samples and the dimensional stability of timber structures, which could inform future research on methods for the preservation or restoration of aging timber structures.
Keywords: historical wooden buildings; water vapor sorption; aged wood; FT-IR spectroscopy; two-dimensional correlation infrared spectroscopy historical wooden buildings; water vapor sorption; aged wood; FT-IR spectroscopy; two-dimensional correlation infrared spectroscopy

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MDPI and ACS Style

Han, L.; Xi, G.; Dai, W.; Zhou, Q.; Sun, S.; Han, X.; Guo, H. Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components. Molecules 2023, 28, 1946. https://doi.org/10.3390/molecules28041946

AMA Style

Han L, Xi G, Dai W, Zhou Q, Sun S, Han X, Guo H. Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components. Molecules. 2023; 28(4):1946. https://doi.org/10.3390/molecules28041946

Chicago/Turabian Style

Han, Liuyang, Guanglan Xi, Wei Dai, Qun Zhou, Suqin Sun, Xiangna Han, and Hong Guo. 2023. "Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components" Molecules 28, no. 4: 1946. https://doi.org/10.3390/molecules28041946

APA Style

Han, L., Xi, G., Dai, W., Zhou, Q., Sun, S., Han, X., & Guo, H. (2023). Influence of Natural Aging on the Moisture Sorption Behaviour of Wooden Structural Components. Molecules, 28(4), 1946. https://doi.org/10.3390/molecules28041946

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