Next Article in Journal
Identification of Novel Natural Dual HDAC and Hsp90 Inhibitors for Metastatic TNBC Using e-Pharmacophore Modeling, Molecular Docking, and Molecular Dynamics Studies
Previous Article in Journal
NMR-Based Metabolomics: A New Paradigm to Unravel Defense-Related Metabolites in Insect-Resistant Cotton Variety through Different Multivariate Data Analysis Approaches
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Molecules
Volume 28
Issue 4
10.3390/molecules28041772
molecules-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO2 Capture Application

by
Qiyun Yu
1,
Jiali Bai
1,
Jiamei Huang
1,
Muslum Demir
2,3,
Ahmed A. Farghaly
4,5,6,
Parya Aghamohammadi
2,
Xin Hu
1,* and
Linlin Wang
7,*
1
Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China
2
Department of Chemical Engineering, Osmaniye Korkut Ata University, Osmaniye 80000, Turkey
3
TUBITAK Marmara Research Center, Material Institute, Gebze 41470, Turkey
4
Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL 60439, USA
5
Pritzker School of Molecular Engineering, The University of Chicago, Chicago, IL 60637, USA
6
Chemistry Department, Faculty of Science, Assiut University, Assiut 71516, Egypt
7
Key Laboratory of Urban Rail Transit Intelligent Operation and Maintenance Technology and Equipment of Zhejiang Province, College of Engineering, Zhejiang Normal University, Jinhua 321004, China
*
Authors to whom correspondence should be addressed.
Molecules 2023, 28(4), 1772; https://doi.org/10.3390/molecules28041772
Submission received: 24 January 2023 / Revised: 7 February 2023 / Accepted: 8 February 2023 / Published: 13 February 2023
(This article belongs to the Section Organic Chemistry)
Browse Figures
Versions Notes

Abstract

:
The design and synthesis of porous carbons for CO2 adsorption have attracted tremendous interest owing to the ever-soaring concerns regarding climate change and global warming. Herein, for the first time, nitrogen-rich porous carbon was prepared with chemical activation (KOH) of commercial melamine formaldehyde resin (MF) in a single step. It has been shown that the porosity parameters of the as-prepared carbons were successfully tuned by controlling the activating temperature and adjusting the amount of KOH. Thus, as-prepared N-rich porous carbon shows a large surface area of 1658 m2/g and a high N content of 16.07 wt%. Benefiting from the unique physical and textural features, the optimal sample depicted a CO2 uptake of up to 4.95 and 3.30 mmol/g at 0 and 25 °C under 1 bar of pressure. More importantly, as-prepared adsorbents show great CO2 selectivity over N2 and outstanding recyclability, which was prominently important for CO2 capture from the flue gases in practical application. An in-depth analysis illustrated that the synergetic effect of textural properties and surface nitrogen decoration mainly determined the CO2 capture performance. However, the textural properties of carbons play a more important role than surface functionalities in deciding CO2 uptake. In view of cost-effective synthesis, outstanding textural activity, and the high adsorption capacity together with good selectivity, this advanced approach becomes valid and convenient in fabricating a unique highly efficient N-rich carbon adsorbent for CO2 uptake and separation from flue gases.

1. Introduction

As of September 2022, the atmospheric carbon dioxide was recorded at 414.57 parts per million [1]. This colossal amount of CO2 has become a major threat to Earth’s environment and sustainable development. To combat this, many countries including the United States have set a goal to reduce greenhouse gas pollution by 50% from 2005 levels by 2030, and eventually achieve net zero emissions by 2050 [2]. With energy consumption and demands continuing to increase, the mitigation of carbon dioxide emissions has become a critical necessity in order to achieve these goals. Current strategies for large-scale mitigation are the capture of CO2 from the atmosphere through pressure or vacuum swing adsorption (P/VSA) processes [3], precombustion capture, post-combustion capture via amine solutions, and oxyfuel combustion [4,5]. Post-combustion capture uses amine absorption technology and involves the aqueous scrubbing of flue gas streams. These scrubbing systems absorb CO2 from flue gas, strip and release the CO2 in concentrated form, and allow the recovery of the original amine solvent [6]. All of these techniques represent great technological advances for CO2 capture. However, these methods come with drawbacks. For example, amine absorption requires a large amount of heat in order to regenerate the solvent, reducing the overall efficiency and increasing the capital cost of the system [7]. Due to the excessive cost, complicated set-up, and high energy consumption of the current methods, more mitigation strategies need to be explored. Gas–solid adsorption is a promising alternative due to its lower energy demands and less extreme operating conditions [8,9,10,11,12].
Over the past few decades, many high-surface-area materials such as metal–organic frameworks (MOFs) [13,14], zeolites [15], porous polymers [16,17,18], amine-modified materials [19,20], covalent–organic frameworks (COFs) [21], and different forms of porous carbons [22,23,24,25,26,27,28,29,30,31] have been explored as possible CO2 adsorbents. Among these, porous carbon adsorbents are considered to be the most promising based on their superb characteristics such as regulated porous structure, abundant precursors, robustness, high surface area, high hydrophobicity, and energy-efficient recovery where much less energy is required for regeneration compared to conventional capture techniques [32,33].
Two techniques have been explored to improve the selectivity and adsorption capacity of these carbonaceous materials. One of these techniques is to improve the pore structure of the material. It has been reported that microporous carbons with high surface areas have higher CO2 adsorption capacity [34]. Previous studies also confirm that the use of heteroatom dopants such as nitrogen, sulfur, and oxygen on the surfaces of porous carbon materials can improve their ability to capture CO2 [35,36,37]. Heteroatoms can improve the electrical properties of a porous material and increase carbon’s overall affinity for CO2 compared to non-doped carbons. When a carbon-based sample is functionalized with nitrogen, it favors the adsorption of carbon dioxide through acid–base interactions, quadrupolar interactions, and hydrogen-bond formation [38,39,40].
Multiple techniques have been explored in order to dope carbon materials with heteroatoms. These methods can be identified as either post-treatment or in situ doping. With post-treatment techniques, the carbon-based materials are treated with nitrogen-containing compounds such as urea [41], ammonia [42], and melamine [43] at high temperatures. This step incorporates nitrogen functional groups into the material, and it can be used to produce activated or porous carbon samples. With in situ methods, nitrogen-containing compounds are used as precursors to directly produce nitrogen-doped carbonaceous materials [44,45]. Successful functionalization of nitrogen to carbon samples can significantly enhance their abilities to adsorb and capture CO2. To the best of our knowledge, there is no direct utilization of commercial melamine formaldehyde resin (MF) via chemical activating agents for the application of CO2 capture. Thus, the present study fills this gap and this is the main novelty of the present research.
Herein, we, for the first time, prepared nitrogen-rich porous carbon adsorbents using a commercial melamine formaldehyde resin (MF) and KOH as the precursor and activating substance, respectively. The textural activity and nitrogen content of the carbons were regulated by adjusting the amount of the KOH and the activating temperature, which eventually affected the CO2 adsorption capacity and selectivity of CO2 over N2. Additionally, we fully investigated the relation between CO2 adsorption and porous properties for the as-prepared carbon-based adsorbents. Other parameters such as CO2/N2 selectivity, the heat of adsorption, CO2 adsorption kinetics behavior, stability, and dynamic CO2 capture performance were also examined.

2. Results and Discussion

2.1. Morphological, Phase Structural, and Surface Chemical Properties

Scanning electron microscopy (SEM) images were used to perceive the morphology and microscopic structures of carbons. The surface morphology of the representative MFC-700-0.2 sample is presented at different magnifications in Figure 1a,b. Notably, the surface of the MFC-700-0.2 sample looks rough and an obvious porous structure (eroded cavities) is prominent, which is critically beneficial for holding a vast amount of CO2 gas. The transmission electron microscopy (TEM) image of the same sample is shown in Figure 1c, which displays a nanoscale rich honeycomb structure. X-ray diffraction (XRD) was applied to assess the crystal framework of the selected MFC-700-0.2 porous carbon, as depicted in Figure 1d. The XRD spectra of the MFC-700-0.2 present one intense and one broad peak placed at 2θ values of 23 and 43°, which were assigned to (002) and (100) reflections of graphitic structure [46].
The elemental content of C, N, and H of the MF-derived porous carbon samples was obtained by elemental analysis (Table 1). It was noticed that up to 16.07 wt% N was held in the as-prepared carbon adsorbents when annealed between 600 and 750 °C, which is an outstanding amount of nitrogen functionality compared to similar materials. X-ray photoelectron spectroscopy (XPS) was conducted to assess the chemical environment in as-prepared adsorbents. As indicated in Figure 2a, the survey scan spectra of the MFC-700-0.1, MFC-700-0.2, and MFC-750-0.2 samples presented peaks located at around 284.5, 398.3, and 531.2 eV, signifying the main presence of C, N, and O atoms. The C1s spectrum can be deconvoluted into signals for C–C (284.5 eV), C–N (285.2 eV), C–O (286.2 eV), and C=O (288.6 eV) [47] (Figure S1, Supplementary Materials). The N 1s core-level XPS spectra of the MFC-700-0.1, MFC-700-0.2, and MFC-750-0.2 samples depicted three prominent peaks placed at 398.4, 400.3, and 401.4 eV, which refer to pyridinic (N-6), pyrrolic (N-5), and graphitic N, respectively [48,49,50]. The fully N functional group contents for these adsorbents are provided in Table S1 (Supplementary Materials). Previous studies reported that pyridinic and pyrrolic nitrogen functional groups integrated into a carbon framework led to strong Lewis basicity, in other words, enhanced electron donor activities, which are favorable to the CO2 adsorption capacity [51,52,53].

2.2. Porous Textual Properties

The textural properties of the MFC-T-m samples were analyzed by N2 sorption, and isotherms are presented in Figure 3, with complete parameters provided in Table 1. The semi-logarithmic N2 sorption isotherms of all the samples are included in Figure S2. It is shown in Figure 3 that the adsorption branches of all samples in N2 isotherms are mostly overlapped with desorption branches, and sorption trends tend to be a horizontal plateau at a very low pressure of 0.1, signifying a typical type I isotherm with a high amount of micropore formation in the carbon framework. Furthermore, in the case of the MFC-650-0.2, MFC-700-0.2, and MFC-750-0.2 samples, isotherms depict a wide knee with adsorbed amounts significantly rising as the P/P0 value reaches 0.3, indicated the existence of small-sized mesopores and certain large-sized micropores [54]. Additionally, these samples slightly present typical type IV isotherms with a small hysteresis loop at a pressure of 0.9–1.0, indicating the presence of some macropore structure. [55,56].
The pore size distributions (PSDs) of the MFC-T-m samples are shown in Figure 4. As observed, almost all porous carbons depict highly concentrated micropores in the range of 0.4 to 0.6 nm. On the other hand, the MFC-650-0.2, MFC-700-0.2, and MFC-750-0.2 samples present a mesopore distribution in the 2.2 to 4.0 nm range. Thus, the carbons have a hierarchical pore structure, i.e., abundant micropore structure together with a certain amount of meso- and macroporosity. Different porous characteristics such as the specific BET surface area (SBET), total pore volume (V0), and micropore volume (Vt) values of the adsorbents are provided in Table 1. It has been found that as the activating temperature increases from the 600 to 700 °C, these porous parameters significantly rise; however, upon further increasing the activating temperature to 750 °C, these values slightly decrease, most probably owing to the destructive effect of the chemical activating agent (KOH) at elevated temperatures, which results in destruction of existing pores and then leads to a shrinkage of microporosity. This is consistent with previous literature studies [57,58]. Furthermore, we investigated the effect of the amount of activating agents on the pore formation and concluded that as the KOH/MF mass ratio increased from 0.1 to 0.2, the textural properties of the carbons notably enhanced thanks to a certain amount of KOH reaching the large-area boundary and opening more and more porosity within the carbon structure.
Since the narrow micropores (<1 nm) were well-recognized as the key factor that determines the CO2 uptake of porous carbons under 1 bar and 25 °C conditions [59,60], herein, the volume of narrow micropores (Vn) in the MFC-T-m samples was calculated using the Dubinin−Radushkevich (D−R) equation based on their CO2 adsorption data at 0 °C. As shown in Table 1, the changing trend of Vn with respect to activation temperature and KOH/MF mass ratio is the same as with the other porous parameters, with a maximum Vn of 0.62 cm3/g for MFC-700-0.2.

2.3. CO2 Adsorption Performance of the N-Doped Porous Carbons

Having confirmed the existence of high nitrogen content along with advanced textural properties, the CO2 adsorption performances of N-rich porous carbon were investigated in depth. The CO2 adsorption isotherms of MFC-T-m samples are depicted in Figure 5 and corresponding CO2 uptake capacities are given in Table 1. It is obvious that the CO2 adsorption isotherms tend to continue increasing even above 1 bar, signifying that higher adsorption capacities can be achieved at elevated adsorption pressure. Another critical conclusion of the CO2 adsorption isotherm plot is that the adsorption capacity of all N-doped porous carbons decreased as the adsorption temperature increased from 0 to 25 °C, indicating that the adsorption mechanism predominantly occurred via an exothermic physical process [61]. To define the optimal CO2 adsorbent, different experimental conditions were investigated in terms of the activation temperature and the KOH/MF mass ratio. The results of the optimization parameters are as follows: Firstly, as the activating temperature rose from 600 to 650 °C, the CO2 capture capacity was significantly increased at both 0 and 25 °C. Further increasing the activation temperature to 700 °C, the CO2 capture capacity was increased again. However, a further increase in the activating temperature from 700 to 750 °C resulted in a notable decrease in the CO2 capture capacity due to the low textural properties since the potential porosity collapse occurred at the elevated activating temperature. We further investigated how the KOH/MF mass ratio affects CO2 capture performance. It was found that a mass ratio of 0.2 is the optimal amount for CO2 capture activity. In short, 700 °C and 0.2 were found to be optimal activating temperature and KOH/MF mass ratio. It should be pointed out that MFC-700-0.2, the optimal sample in this study, has an CO2 adsorption performance comparable to many classic sorbents such as porous carbons [62,63], MOFs [13], COFs [64], porous aromatic frameworks (PAFs) [65], and porous polymers [16].
The adsorption performances of the MFC-T-m samples were further examined to understand the factors affecting CO2 capture activity. The correlations between SBET, V0, Vt, Vn, and nitrogen content versus CO2 uptake are depicted in Figure 6. Notably, certain correlations between CO2 adsorption capacity and SBET, V0, Vt, Vn, and nitrogen content were observed. For instance, there is a good linear relationship between the CO2 capacity and SBET, V0, Vt, and Vn. This claims that as the textural properties enhance, the CO2 capture performance of the adsorbents is significantly increased. This is owing to the fact that the narrow micropore feature plays a paramount role in the CO2 adsorption process. Moreover, there is no apparent linear correlation between N content and CO2 uptake capacity; however, this does not reflect the fact that the nitrogen functionality is a non-defining parameter for carbon capture applications. When we compared the CO2 uptake among MFC-600-0.2, MFC-700-0.1, and MFC-750-0.2, it was found that MFC-750-0.2 had the lowest CO2 uptake of these three samples, even though it has the most advanced porous textural properties. The higher CO2 uptake in MFC-600-0.2 and MFC-700-0.1 can be ascribed to their higher N content compared to MFC-750-0.2. To sum up, both the textural properties and nitrogen functionalities are responsible for the CO2 capture capacity of the as-prepared adsorbents. Considering the fact that this series of samples has a high nitrogen content (up to 16 wt%), but their CO2 adsorption capacity is lower than 4 mmol/g at 25 °C and 1 bar, we think that between narrow porosity and N content, the narrow porosity is the more important factor that determines CO2 uptake of carbonaceous sorbents.
To assess the CO2 separation activity of the representative MFC-700-0.2 sample, the CO2 and N2 isotherms at 25 °C are presented in Figure 7a. Notably, the adsorption capacity of CO2 is much higher than N2 gas, signifying a better selectivity of the MFC-700-0.2 sample for CO2 than for N2. The ideal adsorbed solution theory (IAST) technique [66] was used to quantitatively assess the selectivity for CO2 over N2 and the IAST selectivity was calculated as 17, which is assigned to the strengthened attraction of CO2 molecules on N-doped carbon.
To evaluate the kinetic activity of the optimal MFC-700-0.2 sample, the CO2 adsorption amount versus the adsorption time is depicted in Figure 7b and it was found that within 4.5 min, 90% adsorption saturation is obtained, demonstrating fast adsorption kinetics.
To depict the combination interaction strength between the N-doped carbon adsorbents and the CO2 molecules, the isosteric heats of adsorption (Qst) of selected adsorbents were calculated by the Clausius–Clapeyron equation based on the CO2 sorption isotherm at 0 and 25 °C. The results show that the Qst steadily declines at a relatively low CO2 capture, and then reaches a near plateau as the constant occupation of adsorption active sites increases with the rising CO2 capture, indicating the heterogeneity of interactions between the surfaces of adsorbents and CO2 molecules, which is possibly owing to the heterogeneity of the surface chemistry [67]. The initial Qst values were found to range from 35–48 kJ/mol, which is higher than that of pure carbon-derived adsorbents (around 18 kJ/mol), signifying the strong interaction between the CO2 and N-doped porous carbons. It should be noted that even though the initial Qst for these N-doped carbons is higher than 40 kJ/mol, the CO2 adsorption on these MFC-T-m carbons is still a physisorption process.
To further confirm the practical usability of the as-prepared adsorbent, a breakthrough experiment was conducted for the MFC-700-0.2 sample and it was found that the CO2 dynamic capture capacity was calculated as 0.70 mmol/g at a gas pressure of 1 bar and temperature of 25 °C along with a gas flow rate of 10 mL/min (CO2 concentration: 10 vol.%). It needs to be acknowledged here that a certain amount of water vapor is contained in flue gas, which could deteriorate the CO2 capture capacity of these N-doped carbons due to the competitive adsorption between CO2 and H2O.
In addition to the ideal separation activity, the recyclability performance of adsorbents is another key metric for practical CO2 capture. The regeneration analysis of the selected MFC-700-0.2 sample was conducted for five repeated cycles at 25 °C and 1 bar. Before each test, the sample was heated at 200 °C for 6 h in a vacuum. As depicted in Figure 8, without noticeable loss, 94% of the original CO2 uptake is maintained, demonstrating the excellent recyclability of as-prepared adsorbent along with the low energy requirement for the regeneration process.

3. Synthesis and Characterization

Commercial melamine formaldehyde resin (MF) was selected as the starting material and N-rich porous carbons were produced through a single-step reaction using direct KOH activation. Four activation temperatures (600, 650, 700, and 750 °C) and two KOH/MF ratios (0.1 and 0.2) were used for the optimization process. The resulting sorbents were labeled as MFC-T-m, where T represents the activation temperature and m represents the KOH/MF ratio. The yield of the carbon materials varied from 15.96 to 2.07 wt%.

3.1. KOH Activation

In a typical preparation, 2 g melamine formaldehyde resin (MF) was combined with a solution that contained 0.4 g KOH. After stirring vigorously for 8 h, the mixture was left overnight to dry at 120 °C in an oven. Afterwards, the sample was heated to 200 °C and then held at this temperature for 1 h, then the temperature was elevated to 700 °C and maintained at this temperature for 2 h. The activation was performed at a heating rate of 5 °C/min and a nitrogen flow rate of 400 mL/min. After activation, the sorbent was washed with distilled water until the pH of the filtrate was close to 7. The wet sample was dried under vacuum at 150 °C for 24 h. The final product was named MFC-700-0.2.

3.2. Characterization

Powdered X-ray diffraction (XRD) patterns were carried out on a PHILIPS PW3040/60 powder diffractometer (PHILIPS, Amsterdam, Netherland) using CuKα radiation (λ = 0.15406 nm). Scanning electron microscopy (SEM Hitachi S-4800, Hitachi, Tokyo, Japan) was used to observe the morphology of the samples of carbon materials. Further details of the pore structure were determined by transmission electron microscopy (TEM, JEOL-2100F, JEOL, Kyoto, Japan) operated at 200 kV. The CHN elements were analyzed using a VarioEL III Elemental Analyzer (Elementar, Hanau, Germany). Nitrogen adsorption and desorption isotherms were measured on a 3H-2000PS2 sorption analyzer (Beishide, Beijing, China) at −196 °C. Ultrahigh-purity N2 (99.999%, Shanghai Pujiang Gas Co., Ltd., Shanghai, China) was used for measurements. The samples were degassed under vacuum at 200 °C for at least 12 h prior to measurement. The specific surface area (SBET) was determined using the multipoint Brunauer–Emmett–Teller (BET) method based on the adsorption data in the relative pressure range between 0.001 and 0.09. The total micropore volume (Vt) was derived from the N2 adsorption data using the t-plot method, and the total pore volume (V0) was estimated from the amount of liquid nitrogen adsorbed at a relative pressure of 0.99. The pore size distribution was calculated through the density functional theory (DFT) method (slit pore, equilibrium model). Additionally, X-ray photoelectron (XPS) measurements were conducted using an AXIS Nova spectrometer from Kratos Inc. (Kratos, Manchester, UK) equipped with a monochromatic Al Kα X-ray source (1486.6 eV). The XPS survey spectra were obtained with a pass energy of 160 eV, and high-resolution spectra were recorded with a pass energy of 40 eV. The XPS sub-peaks were deconvolved using a non-linear least squares curve-fitting program (Peak-Fit version 4) that utilized a Gaussian–Lorentzian mix function and Shirley background subtraction.
The CO2 adsorption isotherms were measured using a Beshide 3H-2000PS2 sorption analyzer at 0 °C and 25 °C. Pure CO2 (99.99%, Shanghai Pujiang Gas Co., Ltd., Shanghai, China) was used for adsorption. Prior to each adsorption experiment, the sample was degassed for 12 h at 200 °C to remove the guest molecules from the pores. The volume of narrow micropores (with sizes < 1 nm), Vn, was calculated from CO2 adsorption at 0 °C using the Dubinin–Radushkevich (D-R) equation. The measurements were repeated for each sample, until the values fell within ±2% of each other.

3.3. Measurement of Dynamic CO2 Uptake of the Sorbents

The dynamic CO2 uptake of the sorbents was evaluated in a fixed-bed reactor, as shown in Scheme S1, at 1 bar and 25 °C. The sample was first heated to 100 °C under N2 flow (20 mL/min) for 1 h. After the temperature was reduced to 25 °C, the gas flow was switched from nitrogen to a 10% CO2/N2 mixture (10 mL/min). The effluent gases were monitored in real time using an Agilent 7820A gas chromatograph equipped with a thermal conductivity detector (TCD). The dynamic CO2 capture capacity of each sorbent was calculated from the breakthrough curves.

3.4. Measurement of CO2 Adsorption Kinetics

The CO2 adsorption kinetics was measured using a NETZSCH STA 449C thermogravimetric analyzer (NETZSCH, Selb, Germany). The sample (approximately 5 mg) was purged with a He stream at 200 °C for 1 h, then cooled to the experimental temperature of 25 °C. CO2 gas was then introduced into the test chamber at a flow rate of 50 mL/min, and the change in weight over time was saved.

4. Conclusions

In this work, N-rich porous carbon with good porosity was successfully fabricated by a one-step chemical activation method using commercial melamine formaldehyde resin (MF) as both a carbon and nitrogen source. As-prepared N-doped porous carbons present great textural properties and enhanced nitrogen functionality on their surfaces. As expected, the resultant N-doped carbon adsorbent exhibit a CO2 uptake of up to 4.95 and 3.30 mmol/g at 0 and 25 °C (under 1 bar of pressure), respectively, which are equal to or even higher than those of similar reported CO2 adsorbents. The full CO2 capture analysis results show that a combination of textural activity and functional surface chemistry predominantly determines the carbon capture performance. However, the textural property of carbons is a more important factor than surface functionalities in determining CO2 uptake under ambient conditions. Furthermore, the N-doped carbon adsorbent exhibited excellent CO2 selectivity, moderate isosteric heat of adsorption, and satisfactory recyclability. Considering these confident outcomes such as the low-cost preparation as well as the aspect of environmental friendliness, as-prepared N-rich porous carbons are believed to be promising adsorbents for separating CO2 from flue gas. Regarding future direction, the practical application of the present material will be conducted.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/molecules28041772/s1, Scheme S1. Schematic of the fixed-bed reactor system. Figure S1: XPS C1s of (a) MFC-700-0.1, (b) MFC-700-0.2, and (c) MFC-750-0.2; Figure S2. Semi-logarithmic N2 sorption isotherms of the samples prepared at different conditions. Table S1: N-species contribution in total N obtained from fitting of the N 1s XPS spectra.

Author Contributions

Conceptualization, Q.Y. and X.H.; formal analysis, J.B., J.H. and A.A.F.; investigation, Q.Y. and J.B.; resources, L.W. and X.H.; data curation, J.B., J.H., P.A. and M.D.; writing—original draft preparation, Q.Y.; writing—review and editing, X.H., L.W. and Q.Y.; supervision, L.W. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Zhejiang Provincial Natural Science Foundation, grant number LY21B070005, the National Undergraduate Training Program for Innovation and Entrepreneurship of China and Self designed scientific research project of Zhejiang Normal University, grant number 2021ZS06, TUBITAK 2247, grant number 121C217, and Gaziantep KOSGEB.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data presented in this study are available on request from the corresponding author.

Conflicts of Interest

The authors declare no conflict of interest.

Sample Availability

Samples of the compounds are not available from the authors.

References

  1. Available online: https://gml.noaa.gov/ccgg/trends/global.html (accessed on 2 January 2023).
  2. Wu, Z.; Huang, X.; Chen, R.; Mao, X.; Qi, X. The United States and China on the paths and policies to carbon neutrality. J. Environ. Manag. 2022, 320, 115785. [Google Scholar] [CrossRef] [PubMed]
  3. To, J.W.; He, J.; Mei, J.; Haghpanah, R.; Chen, Z.; Kurosawa, T.; Chen, S.; Bae, W.-G.; Pan, L.; Tok, J.B.-H. Hierarchical N-doped carbon as CO2 adsorbent with high CO2 selectivity from rationally designed polypyrrole precursor. J. Am. Chem. Soc. 2016, 138, 1001–1009. [Google Scholar] [CrossRef] [PubMed]
  4. Chen, S.; Liu, J.; Zhang, Q.; Teng, F.; McLellan, B.C. A critical review on deployment planning and risk analysis of carbon capture, utilization, and storage (CCUS) toward carbon neutrality. Renew. Sustain. Energy Rev. 2022, 167, 112537. [Google Scholar] [CrossRef]
  5. Zhao, B.; Tao, W.; Zhong, M.; Su, Y.; Cui, G. Process, performance and modeling of CO2 capture by chemical absorption using high gravity: A review. Renew. Sustain. Energy Rev. 2016, 65, 44–56. [Google Scholar] [CrossRef]
  6. Rochelle, G.T. Amine Scrubbing for CO2 Capture. Science 2009, 325, 1652–1654. [Google Scholar] [CrossRef] [PubMed]
  7. Aghel, B.; Janati, S.; Wongwises, S.; Shadloo, M.S. Review on CO2 capture by blended amine solutions. Int. J. Greenh. Gas Control 2022, 119, 103715. [Google Scholar] [CrossRef]
  8. Liu, F.; Huang, K.; Jiang, L. Promoted adsorption of CO2 on amine-impregnated adsorbents by functionalized ionic liquids. AIChE J. 2018, 64, 3671–3680. [Google Scholar] [CrossRef]
  9. Lou, Y.-C.; Qi, S.-C.; Xue, D.-M.; Gu, C.; Zhou, R.; Liu, X.-Q.; Sun, L.-B. Solvent-free synthesis of N-containing polymers with high cross-linking degree to generate N-doped porous carbons for high-efficiency CO2 capture. Chem. Eng. J. 2020, 399, 125845. [Google Scholar] [CrossRef]
  10. Shi, J.; Cui, H.; Xu, J.; Yan, N.; Liu, Y. Design and fabrication of hierarchically porous carbon frameworks with Fe2O3 cubes as hard template for CO2 adsorption. Chem. Eng. J. 2020, 389, 124459. [Google Scholar] [CrossRef]
  11. Shi, S.; Liu, Y. Nitrogen-doped activated carbons derived from microalgae pyrolysis by-products by microwave/KOH activation for CO2 adsorption. Fuel 2021, 306, 121762. [Google Scholar] [CrossRef]
  12. Comroe, M.L.; Kolasinski, K.W.; Saha, D. Direct Ink 3D Printing of Porous Carbon Monoliths for Gas Separations. Molecules 2022, 27, 5653. [Google Scholar] [CrossRef]
  13. Millward, A.R.; Yaghi, O.M. Metal-Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature. J. Am. Chem. Soc. 2005, 127, 17998–17999. [Google Scholar] [CrossRef]
  14. Wang, Q.; Chen, Y.; Liu, P.; Wang, Y.; Yang, J.; Li, J.; Li, L. CO2 Capture from High-Humidity Flue Gas Using a Stable Metal-Organic Framework. Molecules 2022, 27, 5608. [Google Scholar] [CrossRef]
  15. Chatterjee, S.; Jeevanandham, S.; Mukherjee, M.; Vo, D.-V.N.; Mishra, V. Significance of re-engineered zeolites in climate mitigation–A review for carbon capture and separation. J. Environ. Chem. Eng. 2021, 9, 105957. [Google Scholar] [CrossRef]
  16. Sun, L.-B.; Kang, Y.-H.; Shi, Y.-Q.; Jiang, Y.; Liu, X.-Q. Highly Selective Capture of the Greenhouse Gas CO2 in Polymers. ACS Sustain. Chem. Eng. 2015, 3, 3077–3085. [Google Scholar] [CrossRef]
  17. Shao, L.; Li, Y.; Huang, J.; Liu, Y.-N. Synthesis of Triazine-Based Porous Organic Polymers Derived N-Enriched Porous Carbons for CO2 Capture. Ind. Eng. Chem. Res. 2018, 57, 2856–2865. [Google Scholar] [CrossRef]
  18. Sang, Y.; Cao, Y.; Wang, L.; Yan, W.; Chen, T.; Huang, J.; Liu, Y.-N. N-rich porous organic polymers based on Schiff base reaction for CO2 capture and mercury(II) adsorption. J. Colloid Interface Sci. 2021, 587, 121–130. [Google Scholar] [CrossRef] [PubMed]
  19. Yan, H.Y.; Zhang, G.J.; Xu, Y.; Zhang, Q.Q.; Liu, J.; Li, G.Q.; Zhao, Y.Q.; Wang, Y.; Zhang, Y.F. High CO2 adsorption on amine-functionalized improved macro-/mesoporous multimodal pore silica. Fuel 2022, 315, 123195. [Google Scholar] [CrossRef]
  20. Zhang, G.; Zhao, P.; Hao, L.; Xu, Y.; Cheng, H. A novel amine double functionalized adsorbent for carbon dioxide capture using original mesoporous silica molecular sieves as support. Sep. Purif. Technol. 2019, 209, 516–527. [Google Scholar] [CrossRef]
  21. Wang, Y.; Kang, C.; Zhang, Z.; Usadi, A.K.; Calabro, D.C.; Baugh, L.S.; Di Yuan, Y.; Zhao, D. Evaluation of Schif-Base Covalent Organic Frameworks for CO2 Capture: Structure-Performance Relationships, Stability, and Performance under Wet Conditions. ACS Sustain. Chem. Eng. 2021, 10, 332–341. [Google Scholar] [CrossRef]
  22. Wang, J.; Zhang, P.; Liu, L.; Zhang, Y.; Yang, J.; Zeng, Z.; Deng, S. Controllable synthesis of bifunctional porous carbon for efficient gas-mixture separation and high-performance supercapacitor. Chem. Eng. J. 2018, 348, 57–66. [Google Scholar] [CrossRef]
  23. Peng, H.-L.; Zhang, J.-B.; Zhang, J.-Y.; Zhong, F.-Y.; Wu, P.-K.; Huang, K.; Fan, J.-P.; Liu, F. Chitosan-derived mesoporous carbon with ultrahigh pore volume for amine impregnation and highly efficient CO2 capture. Chem. Eng. J. 2019, 359, 1159–1165. [Google Scholar] [CrossRef]
  24. Benzigar, M.R.; Talapaneni, S.N.; Joseph, S.; Ramadass, K.; Singh, G.; Scaranto, J.; Ravon, U.; Al-Bahily, K.; Vinu, A. Recent advances in functionalized micro and mesoporous carbon materials: Synthesis and applications. Chem. Soc. Rev. 2018, 47, 2680–2721. [Google Scholar] [CrossRef] [PubMed]
  25. Guo, Y.F.; Tan, C.; Sun, J.; Li, W.L.; Zhang, J.B.; Zhao, C.W. Porous activated carbons derived from waste sugarcane bagasse for CO2 adsorption. Chem. Eng. J. 2020, 381, 122736. [Google Scholar] [CrossRef]
  26. Shao, J.; Ma, C.; Zhao, J.; Wang, L.; Hu, X. Effective nitrogen and sulfur co-doped porous carbonaceous CO2 adsorbents derived from amino acid. Colloids Surf. Physicochem. Eng. Asp. 2022, 632, 127750. [Google Scholar] [CrossRef]
  27. Nazir, G.; Rehman, A.; Park, S.-J. Role of heteroatoms (nitrogen and sulfur)-dual doped corn-starch based porous carbons for selective CO2 adsorption and separation. J. CO2 Util. 2021, 51, 101641. [Google Scholar] [CrossRef]
  28. Yu, Q.Y.; Bai, J.L.; Huang, J.M.; Demir, M.; Altay, B.N.; Hu, X.; Wang, L.L. One-Pot Synthesis of N-Rich Porous Carbon for Efficient CO2 Adsorption Performance. Molecules 2022, 27, 6816. [Google Scholar] [CrossRef]
  29. Nazir, G.; Rehman, A.; Park, S.J. Valorization of shrimp shell biowaste for environmental remediation: Efficient contender for CO2 adsorption and separation. J. Environ. Manag. 2021, 299, 113661. [Google Scholar] [CrossRef]
  30. Nazir, G.; Rehman, A.; Park, S.J. Self-activated, urea modified microporous carbon cryogels for high-performance CO2 capture and separation. Carbon 2022, 192, 14–29. [Google Scholar] [CrossRef]
  31. Rehman, A.; Nazir, G.; Rhee, K.Y.; Park, S.-J. Valorization of orange peel waste to tunable heteroatom-doped hydrochar-derived microporous carbons for selective CO2 adsorption and separation. Sci. Total Environ. 2022, 849, 157805. [Google Scholar] [CrossRef]
  32. Choudhury, F.A.; Norouzi, N.; Amir, K.; Demir, M.; El-Kaderi, H.M. Iron-based sulfur and nitrogen dual doped porous carbon as durable electrocatalysts for oxygen reduction reaction. Int. J. Hydrog. Energy 2022, 47, 6078–6088. [Google Scholar] [CrossRef]
  33. Guo, L.P.; Li, W.C.; Qiu, B.; Ren, Z.X.; Du, J.; Lu, A.H. Interfacial assembled preparation of porous carbon composites for selective CO2 capture at elevated temperatures. J. Mater. Chem. 2019, 7, 5402–5408. [Google Scholar] [CrossRef]
  34. Liu, Z.; Du, Z.; Song, H.; Wang, C.; Subhan, F.; Xing, W.; Yan, Z. The fabrication of porous N-doped carbon from widely available urea formaldehyde resin for carbon dioxide adsorption. J. Colloid Interface Sci. 2014, 416, 124–132. [Google Scholar] [CrossRef] [PubMed]
  35. Sang, Y.F.; Chen, G.; Huang, J.H. Oxygen-rich porous carbons from carbonyl modified hyper-cross-linked polymers for efficient CO2 capture. J. Polymer Res. 2020, 27, 36. [Google Scholar] [CrossRef]
  36. Ma, C.; Bai, J.; Demir, M.; Hu, X.; Liu, S.; Wang, L. Water chestnut shell-derived N/S-doped porous carbons and their applications in CO2 adsorption and supercapacitor. Fuel 2022, 326, 125119. [Google Scholar] [CrossRef]
  37. Ma, C.; Lu, T.; Shao, J.; Huang, J.; Hu, X.; Wang, L. Biomass derived nitrogen and sulfur co-doped porous carbons for efficient CO2 adsorption. Sep. Purif. Technol. 2022, 281, 119899. [Google Scholar] [CrossRef]
  38. Ma, C.D.; Lu, T.Y.; Demir, M.; Yu, Q.Y.; Hu, X.; Jiang, W.H.; Wang, L.L. Polyacrylonitrile-Derived N-Doped Nanoporous Carbon Fibers for CO2 Adsorption. ACS Appl. Nano Mater. 2022, 5, 13473–13481. [Google Scholar] [CrossRef]
  39. Hao, G.-P.; Li, W.-C.; Qian, D.; Lu, A.-H. Rapid Synthesis of Nitrogen-Doped Porous Carbon Monolith for CO2 Capture. Adv. Mater. 2010, 22, 853–857. [Google Scholar] [CrossRef]
  40. Xing, W.; Liu, C.; Zhou, Z.; Zhang, L.; Zhou, J.; Zhuo, S.; Yan, Z.; Gao, H.; Wang, G.; Qiao, S.Z. Superior CO2 uptake of N-doped activated carbon through hydrogen-bonding interaction. Energy Environ. Sci. 2012, 5, 7323–7327. [Google Scholar] [CrossRef]
  41. Rehman, A.; Park, S.-J. From chitosan to urea-modified carbons: Tailoring the ultra-microporosity for enhanced CO2 adsorption. Carbon 2020, 159, 625–637. [Google Scholar] [CrossRef]
  42. Mochizuki, Y.; Bud, J.; Byambajav, E.; Tsubouchi, N. Influence of ammonia treatment on the CO2 adsorption of activated carbon. J. Environ. Chem. Eng. 2022, 10, 107273. [Google Scholar] [CrossRef]
  43. Li, Q.; Liu, S.; Wang, L.; Chen, F.; Shao, J.; Hu, X. Efficient nitrogen doped porous carbonaceous CO2 adsorbents based on lotus leaf. J. Environ. Sci. 2021, 103, 268–278. [Google Scholar] [CrossRef] [PubMed]
  44. Huang, J.; Bai, J.; Demir, M.; Hu, X.; Jiang, Z.; Wang, L. Efficient N-Doped Porous Carbonaceous CO2 Adsorbents Derived from Commercial Urea-Formaldehyde Resin. Energy Fuels 2022, 36, 5825–5832. [Google Scholar] [CrossRef]
  45. Ma, C.; Bai, J.; Hu, X.; Jiang, Z.; Wang, L. Nitrogen-doped porous carbons from polyacrylonitrile fiber as effective CO2 adsorbents. J. Environ. Sci. 2023, 125, 533–543. [Google Scholar] [CrossRef]
  46. Liu, Y.Z.; Wang, H.; Li, C.C.; Wang, S.H.; Li, L.; Song, C.W.; Wang, T.H. Hierarchical flaky porous carbon derived from waste polyimide film for high-performance aqueous supercapacitor electrodes. Int. J. Energy Res. 2021, 46, 370–382. [Google Scholar] [CrossRef]
  47. Prasankumar, T.; Salpekar, D.; Bhattacharyya, S.; Manoharan, K.; Yadav, R.M.; Campos Mata, M.A.; Miller, K.A.; Vajtai, R.; Jose, S.; Roy, S.; et al. Biomass derived hierarchical porous carbon for supercapacitor application and dilute stream CO2 capture. Carbon 2022, 199, 249–257. [Google Scholar] [CrossRef]
  48. Zhu, C.; Liu, Y.; Zhang, H.N.; Yang, H.; Yin, X.T.; Li, Z.G.; Ma, X.G. Synergistic effect of porous structure and heteroatoms in carbon materials to boost high-performance supercapacitor. Int. J. Energy Res. 2021, 45, 10963–10973. [Google Scholar] [CrossRef]
  49. Rehman, A.; Nazir, G.; Rhee, K.Y.; Park, S.-J. A rational design of cellulose-based heteroatom-doped porous carbons: Promising contenders for CO2 adsorption and separation. Chem. Eng. J. 2021, 420, 130421. [Google Scholar] [CrossRef]
  50. Yadav, R.M.; Li, Z.; Zhang, T.; Sahin, O.; Roy, S.; Gao, G.; Guo, H.; Vajtai, R.; Wang, L.; Ajayan, P.M.; et al. Amine-Functionalized Carbon Nanodot Electrocatalysts Converting Carbon Dioxide to Methane. Adv. Mater. 2022, 34, 2105690. [Google Scholar] [CrossRef]
  51. Li, H.M.; Li, J.H.; Thomas, A.; Liao, Y.Z. Ultra-High Surface Area Nitrogen-Doped Carbon Aerogels Derived From a Schiff-Base Porous Organic Polymer Aerogel for CO2 Storage and Supercapacitors. Adv. Funct. Mater. 2019, 29, 1904785. [Google Scholar] [CrossRef]
  52. Sánchez-Sánchez, Á.; Suárez-García, F.; Martínez-Alonso, A.; Tascón, J.M.D. Influence of Porous Texture and Surface Chemistry on the CO2 Adsorption Capacity of Porous Carbons: Acidic and Basic Site Interactions. ACS Appl. Mater. Interface 2014, 6, 21237–21247. [Google Scholar] [CrossRef]
  53. Ma, X.; Cao, M.; Hu, C. Bifunctional HNO3 catalytic synthesis of N-doped porous carbons for CO2 capture. J. Mater. Chem. 2013, 1, 913–918. [Google Scholar] [CrossRef]
  54. Huang, G.G.; Wu, X.X.; Hou, Y.R.; Cai, J.J. Sustainable porous carbons from garlic peel biowaste and KOH activation with an excellent CO2 adsorption performance. Biomass Convers. Biorefin. 2020, 10, 267–276. [Google Scholar] [CrossRef]
  55. Lu, T.Y.; Bai, J.L.; Demir, M.; Hu, X.; Huang, J.M.; Wang, L.L. Synthesis of potassium Bitartrate-derived porous carbon via a facile and Self-Activating strategy for CO2 adsorption application. Sep. Purif. Technol. 2022, 296, 121368. [Google Scholar] [CrossRef]
  56. Lu, T.; Ma, C.; Demir, M.; Yu, Q.; Aghamohammadi, P.; Wang, L.; Hu, X. One-pot synthesis of potassium benzoate-derived porous carbon for CO2 capture and supercapacitor application. Sep. Purif. Technol. 2022, 301, 122053. [Google Scholar] [CrossRef]
  57. Li, H.Q.; Xiao, N.; Hao, M.Y.; Song, X.D.; Wang, Y.W.; Ji, Y.Q.; Liu, C.; Li, C.; Guo, Z.; Zhang, F.; et al. Efficient CO(2) electroreduction over pyridinic-N active sites highly exposed on wrinkled porous carbon nanosheets. Chem. Eng. J. 2018, 351, 613–621. [Google Scholar] [CrossRef]
  58. Kou, J.H.; Sun, L.B. Nitrogen-Doped Porous Carbons Derived from Carbonization of a Nitrogen-Containing Polymer: Efficient Adsorbents for Selective CO2 Capture. Ind. Eng. Chem. Res. 2016, 55, 10916–10925. [Google Scholar] [CrossRef]
  59. Presser, V.; McDonough, J.; Yeon, S.-H.; Gogotsi, Y. Effect of pore size on carbon dioxide sorption by carbide derived carbon. Energy Environ. Sci. 2011, 4, 3059–3066. [Google Scholar] [CrossRef]
  60. Sevilla, M.; Fuertes, A.B. Sustainable porous carbons with a superior performance for CO2 capture. Energy Environ. Sci. 2011, 4, 1765–1771. [Google Scholar] [CrossRef]
  61. Xie, W.H.; Yao, X.Y.; Li, H.; Li, H.R.; He, L.N.A. Biomass-Based N-Rich Porous Carbon Materials for CO2 Capture and in-situ Conversion. ChemSusChem 2022, 15, e202201004. [Google Scholar] [CrossRef]
  62. Balahmar, N.; Mitchell, A.C.; Mokaya, R. Generalized Mechanochemical Synthesis of Biomass-Derived Sustainable Carbons for High Performance CO2 Storage. Adv. Energy Mater. 2015, 5, 1500867. [Google Scholar] [CrossRef]
  63. Sui, Z.-Y.; Cui, Y.; Zhu, J.-H.; Han, B.-H. Preparation of Three-Dimensional Graphene Oxide–Polyethylenimine Porous Materials as Dye and Gas Adsorbents. ACS Appl. Mater. Interfaces 2013, 5, 9172–9179. [Google Scholar] [CrossRef]
  64. Furukawa, H.; Yaghi, O.M. Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications. J. Am. Chem. Soc. 2009, 131, 8875–8883. [Google Scholar] [CrossRef] [PubMed]
  65. Ben, T.; Li, Y.; Zhu, L.; Zhang, D.; Cao, D.; Xiang, Z.; Yao, X.; Qiu, S. Selective adsorption of carbon dioxide by carbonized porous aromatic framework (PAF). Energy Environ. Sci. 2012, 5, 8370–8376. [Google Scholar] [CrossRef]
  66. Myers, A.L.; Prausnitz, J.M. Thermodynamics of mixed-gas adsorption. AIChE J. 1965, 11, 121–127. [Google Scholar] [CrossRef]
  67. Shi, W.W.; Wang, R.Z.; Liu, H.L.; Chang, B.B.; Yang, B.C.; Zhang, Z.L. Biowaste-derived 3D honeycomb-like N and S dual-doped hierarchically porous carbons for high-efficient CO2 capture. RSC Adv. 2019, 9, 23241–23253. [Google Scholar] [CrossRef]
Molecules 28 01772 g001 550
Figure 1. SEM images (a,b); TEM image (c); and XRD pattern (d) of MFC-700-0.2.
Figure 1. SEM images (a,b); TEM image (c); and XRD pattern (d) of MFC-700-0.2.
Molecules 28 01772 g001
Molecules 28 01772 g002 550
Figure 2. XPS survey (a) of selected adsorbents; XPS N 1s of (b) MFC-700-0.1, (c) MFC-700-0.2, and (d) MFC-750-0.2. In (b,c), the black line is the original data and the red line is the fitting curve, the green line is the background.
Figure 2. XPS survey (a) of selected adsorbents; XPS N 1s of (b) MFC-700-0.1, (c) MFC-700-0.2, and (d) MFC-750-0.2. In (b,c), the black line is the original data and the red line is the fitting curve, the green line is the background.
Molecules 28 01772 g002
Molecules 28 01772 g003 550
Figure 3. N2 sorption isotherms of the samples prepared at KOH/MF ratio of (a) 0.1 and (b) 0.2. Filled and empty symbols represent adsorption and desorption branches, respectively. STP: standard temperature and pressure.
Figure 3. N2 sorption isotherms of the samples prepared at KOH/MF ratio of (a) 0.1 and (b) 0.2. Filled and empty symbols represent adsorption and desorption branches, respectively. STP: standard temperature and pressure.
Molecules 28 01772 g003
Molecules 28 01772 g004 550
Figure 4. Pore size distribution of the samples prepared at KOH/MF ratio of (a) 0.1 and (b) 0.2. Dv(d) = dV/dD.
Figure 4. Pore size distribution of the samples prepared at KOH/MF ratio of (a) 0.1 and (b) 0.2. Dv(d) = dV/dD.
Molecules 28 01772 g004
Molecules 28 01772 g005 550
Figure 5. CO2 adsorption isotherms at 25 °C (a,c) and 0 °C (b,d) for melamine formaldehyde resin-derived N-doped carbons prepared under different conditions.
Figure 5. CO2 adsorption isotherms at 25 °C (a,c) and 0 °C (b,d) for melamine formaldehyde resin-derived N-doped carbons prepared under different conditions.
Molecules 28 01772 g005
Molecules 28 01772 g006 550
Figure 6. Plot of each porous properties characteristic: (a) SBET, (b) V0, (c) Vt, (d) Vn, and (e) nitrogen content versus CO2 uptake.
Figure 6. Plot of each porous properties characteristic: (a) SBET, (b) V0, (c) Vt, (d) Vn, and (e) nitrogen content versus CO2 uptake.
Molecules 28 01772 g006
Molecules 28 01772 g007 550
Figure 7. (a) CO2 and N2 adsorption isotherms of MFC-700-0.2 at 25 °C and 1 bar, the black line is CO2 isotherm and the red line is N2 isotherm (b) CO2 adsorption kinetics at 25 °C for MFC-700-0.2, (c) Qst (isosteric heats of adsorption) on selected sorbents and (d) breakthrough curves of MFC-700-0.2. Adsorption conditions: gas pressure = 1 bar, adsorption temperature = 25 °C, gas flow rate = 10 mL/min, inlet CO2 concentration = 10 vol.%.
Figure 7. (a) CO2 and N2 adsorption isotherms of MFC-700-0.2 at 25 °C and 1 bar, the black line is CO2 isotherm and the red line is N2 isotherm (b) CO2 adsorption kinetics at 25 °C for MFC-700-0.2, (c) Qst (isosteric heats of adsorption) on selected sorbents and (d) breakthrough curves of MFC-700-0.2. Adsorption conditions: gas pressure = 1 bar, adsorption temperature = 25 °C, gas flow rate = 10 mL/min, inlet CO2 concentration = 10 vol.%.
Molecules 28 01772 g007
Molecules 28 01772 g008 550
Figure 8. Cyclic study of CO2 adsorption for MFC-700-0.2.
Figure 8. Cyclic study of CO2 adsorption for MFC-700-0.2.
Molecules 28 01772 g008
Table
Table 1. Porous textural, elemental compositions, and CO2 uptakes of adsorbents derived from melamine formaldehyde resin under different conditions.
Table 1. Porous textural, elemental compositions, and CO2 uptakes of adsorbents derived from melamine formaldehyde resin under different conditions.
SampleSBET a
(m2/g)		V0 b
(cm3/g)		Vt c
(cm3/g)		Vn d
(cm3/g)		N
(wt%)		C
(wt%)		H
(wt%)		CO2 Uptake
(mmol/g)
25 °C0 °C
MFC-600-0.12780.150.090.2216.0758.183.862.022.55
MFC-600-0.28950.430.350.4014.5157.943.592.743.76
MFC-650-0.14350.220.160.2315.2359.643.122.062.72
MFC-650-0.210700.570.440.5813.9759.113.822.864.28
MFC-700-0.17680.370.290.3914.7260.653.412.884.25
MFC-700-0.216580.960.660.6213.3864.134.043.304.95
MFC-750-0.15540.280.210.3611.6458.262.602.543.26
MFC-750-0.213730.870.600.519.6760.342.982.473.79
a Surface area was calculated using the BET method at P/P0 = 0.005–0.05. b Total pore volume at P/P0 = 0.99. c Evaluated by the t-plot method. d Pore volume of narrow micropores (<1 nm) obtained from the CO2 adsorption data at 0 °C.
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Yu, Q.; Bai, J.; Huang, J.; Demir, M.; Farghaly, A.A.; Aghamohammadi, P.; Hu, X.; Wang, L. One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO2 Capture Application. Molecules 2023, 28, 1772. https://doi.org/10.3390/molecules28041772

AMA Style

Yu Q, Bai J, Huang J, Demir M, Farghaly AA, Aghamohammadi P, Hu X, Wang L. One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO2 Capture Application. Molecules. 2023; 28(4):1772. https://doi.org/10.3390/molecules28041772

Chicago/Turabian Style

Yu, Qiyun, Jiali Bai, Jiamei Huang, Muslum Demir, Ahmed A. Farghaly, Parya Aghamohammadi, Xin Hu, and Linlin Wang. 2023. "One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO2 Capture Application" Molecules 28, no. 4: 1772. https://doi.org/10.3390/molecules28041772

APA Style

Yu, Q., Bai, J., Huang, J., Demir, M., Farghaly, A. A., Aghamohammadi, P., Hu, X., & Wang, L. (2023). One-Pot Synthesis of Melamine Formaldehyde Resin-Derived N-Doped Porous Carbon for CO2 Capture Application. Molecules, 28(4), 1772. https://doi.org/10.3390/molecules28041772

Article Metrics

Back to TopTop