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Article

Diverse Coordination Chemistry of the Whole Series Rare-Earth L-Lactates: Synthetic Features, Crystal Structure, and Application in Chemical Solution Deposition of Ln2O3 Thin Films

by
Ruslan Gashigullin
1,
Mikhail Kendin
1,2,
Irina Martynova
2 and
Dmitry Tsymbarenko
2,*
1
Department of Materials Science, Lomonosov Moscow State University, Moscow 119991, Russia
2
Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia
*
Author to whom correspondence should be addressed.
Molecules 2023, 28(15), 5896; https://doi.org/10.3390/molecules28155896
Submission received: 30 June 2023 / Revised: 25 July 2023 / Accepted: 4 August 2023 / Published: 5 August 2023
(This article belongs to the Section Inorganic Chemistry)
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Abstract

:
Rare-earth (RE, Ln) carboxylates are widely studied as precursors of RE oxide-based nanomaterials; however, no systematic studies of RE L-lactates (HLact = 2-hydroxypropanoic acid) have been reported to date. In the present work, a profound structural investigation of RE L-lactates is carried out. A family of RE lactate complexes of the general formula LnLact3∙nH2O (Ln = La, Ce–Nd, Sm–Lu, Y; n = 2–3) are synthesized and characterized by CHN, TGA, and FTIR as well as by powder and single-crystal XRD methods.The existence of four novel structural types (1-Ln–4-Ln) is revealed. Compounds of the 1-Ln type (Ln = La, Ce, Pr) exhibit a chain polymeric structure, whereas 2-Ln–4-Ln compounds are molecular crystals consisting of dimeric (2-Ln; Ln = La, Ce–Nd) or monomeric (3-Ln–Ln = Sm–Lu, Y; 4-Ln–Ln = Sm–Gd, Y) species. The crystal structures of 1-Ln–4-Ln compounds are discussed in terms of their coordination geometry and supramolecular arrangement. Solutions of yttrium and lanthanum lactates with diethylenetriamine are applied for the chemical deposition of Y2O3 and La2O3 thin films.

1. Introduction

Coordination compounds based on aliphatic metal carboxylates attract significant scientific interest as versatile precursors of inorganic nanomaterials [1,2,3]. In particular, rare-earth (RE, Ln) carboxylates are widely used in the preparation of functional thin films (high-temperature superconductors, colossal magnetoresistance materials, high-k dielectrics, and many others) through the metal–organic chemical solution deposition (MOCSD) process [4,5,6,7]. The latter implies the preparation of a precursor solution and its deposition onto a substrate with subsequent multi-stage annealing that eventually yields the required oxide thin film [4]. The composition of the precursor solution plays an important role, as it determines crucial characteristics of the latter, namely, viscosity, adhesion to the substrate, and decomposition mechanism [8].
Regarding the solution deposition of RE oxide films, RE carboxylates represent a set of advantages over other classes of RE compounds (e.g., alkoxides and β-diketonates) due to their moisture resistance and low volatility [4,9], although non-volatile RE carboxylates are generally inapplicable in the chemical vapor deposition process, where metal β-diketonates are widely used [10,11,12]. On the other hand, the majority of RE carboxylates exhibit polymeric structures [13,14,15,16,17,18], making them poorly soluble in common organic solvents. The solubility of RE carboxylates can be significantly enhanced by the addition of ancillary chelating ligands (e.g., polyamines) and formation of highly soluble mixed-ligand complexes, which decompose at relatively low (<700 °C) temperatures to yield their respective RE oxides [7,9,19]. Among the various RE monocarboxylates, acetates and propionates are often used in the fabrication of oxide materials [20,21,22,23,24]; however, there are very few reports on the use of RE lactates (2-hydroxypropanoates) for this purpose. In particular, Xue et al. reported the preparation of Pb0.98La0.02(Zr0.66Sn0.27Ti0.07)O3 ceramics from a solution of the respective metal lactates [25]; however, no experiments on the deposition of RE sesquioxide thin films using lactate-based precursors have been published to date.
Although L-lactic acid (henceforth HLact) is widely used in modern chemistry and chemical technology, simple metal salts of HLact remain poorly studied. There are few reports on the synthesis and characterization of Zn [26,27,28], Co [29], Mn [30], Zr [31], and UO22+ [32] lactates or the heterocationic and mixed-ligand compounds K2[{VO(O2)(Lact′)}2] [33], (NH4)2[Ti(Lact′)3] [34], (NEt4)2[VO2(Lact′)]2 and (Ph3P=N=PPh3)2[VO2(Lact′)]2 [35], (TMA)3[Mn2(Lact)(Lact′)4]∙H2O [36] (TMA = NMe4+), Zr(OH)Lact3 [31], (NH4)4[Ta2(Lact’)4(O2)2O]·3H2O [37], [Cu(Lact)Cl(dipyam)] (dipyam = 2,2′-dipyridylamine) [38], [Cu(Lact)(ClO4)(phen)]4 (phen = 1,10-phenanthroline) [39], [Ni6(Lact’)2(Lact)2Piv6(HPiv)8]·2HPiv (HPiv = pivalic acid) [40], [Cu(Lact)2(SS)]·4H2O, and [Cu2(Lact)4(SCS)3] (SS = 4,4′-dipyridyldisulfide; SCS = bis(4-pyridylthio)methane) [41] (here, Lact’ corresponds to the lactic acid dianion CH3CH(O–)COO–). Among RE lactates, only a few compounds have been synthesized and characterized to date. Namely, crystal structures of 2D-layered cationic {[Ln(H2O)2Lact2](ClO4)}∞ (Ln = Eu, Tb) [42,43] and molecular [Y(H2O)2Lact3] [44] compounds as well as mixed-ligand complexes of RE (L/D)-lactates with O- and N-donor ligands [45,46,47] have been reported. The main obstacle to the structural study of RE lactates lies in their tendency to form viscous supersaturated solutions or/and intergrown crystals rather than X-ray quality single crystals. Nevertheless, RE carboxylates are known to exhibit extreme structural diversity [13]; RE lactates seem to be an interesting system in this scope, as the presence of ancillary OH-groups near the carboxyl groups may yield unusual metal–ligand coordination modes, leading in turn to novel and unexpected supramolecular motifs. This feature can be illustrated on yttrium complexes with propionate and lactate ligands, which possess the same carbon chain structure while differing in the presence of an additional OH-group. Thus, yttrium propionate possesses a 2D-layered motif [18,48], whereas yttrium lactate exhibits a mononuclear structure, which is rather rare for RE carboxylates [44].
In the present work, we report a systematic X-ray diffraction study of RE lactates as well as their application in the chemical solution deposition of RE oxide thin films. A series of RE lactate complexes of the general formula LnLact3∙nH2O (Ln = La, Ce–Nd, Sm–Lu, Y; n = 2–3) have been synthesized and characterized by means of conventional chemical analyses (CHN, TGA, FTIR) as well as powder and single-crystal X-ray diffraction. Four structural types exhibiting different coordination environments of Ln3+ ions and different supramolecular arrangements have been revealed. Solutions of yttrium and lanthanum lactates with diethylenetriamine (DETA) were applied for the chemical deposition of Y2O3 and La2O3 thin films, respectively.

2. Results and Discussion

2.1. Synthesis of RE Lactates

In general, RE carboxylates are rather simple to synthesize; these compounds are commonly obtained via protolytic or ligand exchange reactions [49,50,51,52,53]. On the other hand, RE coordination compounds are known to exhibit structural flexibility; consequently, both the composition and structure of the synthesis product are highly sensitive to the preparation conditions. Regarding RE lactates, the hydrate number of the complex may easily vary depending on the synthesis temperature, concentration of water, and radius of the particular RE cation. An additional degree of freedom arises from the chirality of lactic acid and its anion; it is worth noting that the industrial HLact obtained by microbial fermentation consists of an almost pure L- (S, +) enantiomer. Thus, the presence of a racemic mixture of both enantiomers of the lactate ion or/and ancillary ions (even Na+ and ClO4–) in the initial solution can drastically change the reaction pathway, yielding heterocationic (e.g., {[LnNa(D-Lact)2(L-Lact)2]·2H2O}∞ − Ln = Sm, Eu [54]) or heteroanionic ({[Ln(H2O)2(L-Lact)2](ClO4)}∞ − Ln = Eu, Tb [42,43]) compounds. Nevertheless, the synthetic features of RE lactates have not been studied in detail yet, and the few papers dedicated to this issue represent only fragmentary and incomplete data. Therefore, we have carried out an extensive study on the preparation of RE lactates for the whole RE series (except for Sc and Pm) by means of different experimental procedures. According to the TGA (Figure 1 and Figures S1–S4) and FTIR data, all syntheses throughout Procedures I–III along with the room-temperature evaporation of mother liquors yielded the corresponding RE lactate complexes of the general formula LnLact3∙nH2O (Ln = La, Ce–Nd, Sm–Lu, Y; n = 2–3), which were divided into four types on the basis of powder and single-crystal XRD data (Figure 2): 1-Ln ([Ln(H2O)2Lact3]∞; Ln = La, Ce, Pr), 2-Ln ([Ln2(H2O)5Lact6]∙H2O; Ln = La, Ce, Pr, Nd), 3-Ln ([Ln(H2O)2Lact3]; Ln = Sm–Lu, Y), and 4-Ln ([Ln(H2O)2Lact3]∙H2O; Ln = Sm–Gd, Y). Regardless of the procedure (I–III) used, the phase composition of synthesis products is only affected by the crystallization and drying conditions.
In the case of light RE (La–Nd) lactates, the crystallization rate and temperature proved to be the major factors affecting the phase composition of the products. Indeed, fast evaporation of the solvent at room temperature (e.g., in air flow) yields the respective 1-Ln complexes; X-ray quality single crystals of these can be prepared via crystallization from hot supersaturated solutions. On the other hand, slow crystallization from RE lactate solutions at room temperature (from several weeks up to several months) yields crystalline precipitates of 2-Ln, which contain X-ray quality single crystals. The Nd compound is an exception to this rule, as it always crystallizes in the 2-Ln type. Presumably, this anomaly arises from the crystallographic instability of the 1-Ln structure in the case of smaller Nd3+ ions.
A different situation was observed for heavy RE lactates. These compounds can crystallize in the form of hydrates [Ln(H2O)2Lact3]∙H2O (4-Ln), which are, however, unstable and readily eliminate non-coordinated water molecules upon drying (this behavior is discussed further in Section 2.3). Thus, 4-Ln types were prepared upon the slow evaporation of the mother liquors at room temperature and stored in air to avoid water elimination. On the other hand, fast evaporation of RE lactate solutions with the subsequent drying of solid products in a desiccator yielded pure 3-Ln (Ln = Sm–Lu, Y) in all cases. X-ray quality single crystals of both 3-Ln and 4-Ln can be obtained via crystallization from the respective mother liquors.
In addition to the differences in their chemical composition, RE lactate complexes of the 1-Ln–4-Ln types exhibit major differences in their molecular and crystal structures, as discussed in the next section. It is worth noting that the starting reagent (HLact) was an enantiopure L-isomer. Therefore, all syntheses yielded chiral complexes, which in turn formed chiral crystals 1-Ln–4-Ln with no inversion centers or mirror/glide planes present.

2.2. Crystal Structures of RE Lactates

Single-crystal XRD revealed the existence of four structural types among RE lactate complexes: 1D-polymeric [Ln(H2O)2Lact3]∞ (1-Ln), dimeric [Ln2(H2O)5Lact6]∙H2O (2-Ln), and monomeric ([Ln(H2O)2Lact3] (3-Ln) and [Ln(H2O)2Lact3]∙H2O (4-Ln)). Full details on the unit cell parameters and Ln–O bond lengths for all crystal structures determined are summarized in Tables S1–S3. For crystal structures refined from PXRD data, the corresponding PXRD patterns with Rietveld fits are provided in Figures S5 and S6. Data on the Continuous Shape Measures (CShM [55]) analysis of RE coordination polyhedra are summarized in Table S4.

2.2.1. Crystal Structures of Type 1-Ln (Ln = La, Pr)

As revealed from single-crystal XRD data, 1-La exhibits a 1D-polymeric structure. 1-La crystallizes in an orthorhombic lattice (space group P212121). The asymmetric part of the unit cell contains one lanthanum atom (La1), three Lact-anions, and two water molecules. La1 coordinates carboxyl and hydroxyl oxygen atoms from two chelating (O1∙∙∙O3, O7∙∙∙O9) and one chelating-bridging (O4∙∙∙O6) lactate ligands, two water molecules (O10, O11), and additionally one carboxyl oxygen atom of a chelating-bridging lactate anion (O5i) from the symmetry-related part (Figure 3a); thus, the CN of La1 is 9, and the coordination polyhedron is best described as a spherical tricapped trigonal prism (TCTPR-9, Table S4). It is worth noting that Ln–O bond lengths depend on the type of ligand atoms, being longer for α-hydroxyl groups (O3, O6, O9) and shorter for water molecules (O10, O11), chelating carboxyl atoms (O1, O4, O7), and bridging carboxyl atoms (O5i) in descending order (Table S2).
Adjacent lanthanum atoms are interlinked through chelating-bridging lactate ligands (O4∙∙∙O5∙∙∙O6) to form corrugated [La(H2O)2Lact3]∞ chains propagating along the [010] direction (Figure 3b). Neighboring [La(H2O)2Lact3]∞ chains are packed in a “herringbone” manner and are translated one into another by 21(x) and 21(z) screw axes as well as by crystallographic translations. Multiple intra- and interchain hydrogen bonds (d(O∙∙∙O)~2.64–2.85 Å) are present in the crystal. 1-Pr possesses the same structural motif except for minor differences in the Ln–O coordination bond lengths, which are on average ~0.04 Å shorter than those of 1-La (Table S2).
The main feature of the 1-Ln structural type is the chelating-bridging coordination mode observed for some of the lactate ligands. Specifically, the latter not only form chelate cycles, they interconnect adjacent RE centers through an additional carboxyl oxygen atom. Analogous coordination behavior of lactate ligands was reported for the polymeric {[Ln(H2O)2Lact2](ClO4)}∞ (Ln = Eu, Tb) complexes [42,43].

2.2.2. Crystal Structures of Type 2-Ln (Ln = La, Ce, Pr)

Unlike the polymeric 1-Ln compounds, crystal structures of [Ln2(H2O)5Lact6]∙H2O (2-Ln; Ln = La, Ce, Pr) consist of discrete dimeric molecules. All compounds in the 2-Ln family exhibit triclinic symmetry (space group P1). The asymmetric part of the unit cell contains two Ln atoms (Ln1 an Ln2), six lactate ligands, and six water molecules. Ln1 coordinates carboxyl and hydroxyl oxygen atoms from three Lact-anions (O1∙∙∙O3, O4∙∙∙O6, O7∙∙∙O9) in a chelating mode. Additionally, Ln1 attaches two water molecules (O19, O20) and one carboxyl oxygen atom (O10) from a chelating-bridging lactate ion; therefore, the CN of Ln1 is 9, and the best fitting reference polyhedron is a spherical tricapped trigonal prism (TCTPR-9, Table S4). Ln–O bond lengths exhibit the same dependence on the type of ligand atoms as observed for 1-Ln (Table S2). Similarly, Ln2 exhibits a nine-fold coordination environment; however, the arrangement of the ligands is different from that of Ln1. Specifically, Ln2 coordinates carboxyl and hydroxyl oxygen atoms from two chelating (O13∙∙∙O15, O16∙∙∙O18) and one chelating-bridging (O11∙∙∙O12) lactate anions, along with an additional three water molecules (O21, O22, O23). In contrast to the coordination environment of Ln1, Ln2 exhibits the longest Ln–O bonds for water ligands rather than α-hydroxyl groups (Table S2). The coordination polyhedron of Ln2 is best described as a “muffin” (MFF-9, Table S4).
As described for 1-Ln, some of the lactate ions not only chelate RE ions through carboxyl and hydroxyl oxygen atoms, they bridge them through another carboxyl oxygen atom. Thus, Ln1–Ln2 pairs are linked with each other through chelating-bridging (O10∙∙∙O11∙∙∙O12) lactate ligands to form non-centrosymmetric dimers [Ln2(H2O)5Lact6] that are additionally stabilized by intramolecular hydrogen bonds (d(O∙∙∙O)~2.75–2.87 Å for 2-La, Figure 4a). Additionally, neighboring [Ln2(H2O)5Lact6] species form multiple O–H∙∙∙O contacts with each other as well as with non-coordinated water molecules, yielding a three-dimensional hydrogen-bonded framework (Figure 4b).

2.2.3. Crystal Structures of Types 3-Ln and 4-Ln (Ln = Sm–Lu, Y)

The decrease of the Ln3+ ionic radius in the lanthanide series reduces the preferable CN of the metal center and favors the formation of monomeric lactate complexes beginning from Sm3+. Thus, Ln lactates (Ln = Sm–Lu, Y) of both 3-Ln and 4-Ln types possess mononuclear structural motifs with virtually identical configurations of the Ln coordination environment while exhibiting differences at the supramolecular level.
All 3-Ln compounds crystallize with orthorhombic unit cells (space group P212121). The asymmetric part of the unit cell contains one [Ln(H2O)Lact3] molecule. Ln1 coordinates carboxyl and hydroxyl oxygen atoms from three chelating lactate ligands (O1∙∙∙O3, O4∙∙∙O6, O7∙∙∙O9) and additional oxygen atoms from two water molecules (O10, O11) to form an eight-vertex coordination polyhedron (Figure 5a). The latter is well described by multiple reference shapes; the best fitting polyhedron with the minimal CShM parameter varies among the 3-Ln group, being either a triangular dodecahedron TDD-8 or a square antiprism SAPR-8 (Table S4).
A detailed analysis of the crystal packing for 3-Ln reveals the presence of hydrogen-bonded layers; their structure can be represented as follows. First, neighboring [Ln(H2O)Lact3] molecules form intermolecular ROH∙∙∙OOCR and HOH∙∙∙OOCR hydrogen bonds (d(O∙∙∙O)~2.62–2.71 Å for 3-Gd) to yield infinite chain-like species [Ln(H2O)Lact3]∞ propagating along the [100] direction, with the shortest Ln∙∙∙Ln separation being 5.7542(2) Å for 3-Gd. In turn, [Ln(H2O)Lact3]∞ species link with each other through additional HOH∙∙∙OOCR hydrogen bonds (d(O∙∙∙O)~2.67–2.80 Å for 3-Gd) into extended corrugated layers parallel to the (001) plane (Figure 5b), which interact primarily via weak van der Waals forces.
It is worth noting that the monoclinic crystal structure of [Y(H2O)2Lact3] (henceforth 5-Y) reported by Yapryntsev et al. [44] exhibits a similar structural motif that differs from 3-Ln in the crystallographic symmetry and arrangement of hydrogen-bonded species. To be more precise, the crystal of 5-Y consists of mononuclear [Y(H2O)2Lact3] molecules interlinked by hydrogen bonds into chain-like species [Y(H2O)2Lact3]∞, which in turn form corrugated layers. Despite possessing a virtually identical topology of an isolated hydrogen-bonded layer, 3-Ln and 5-Y differ in the packing of those. In the former case, neighboring layers are translated one into another through 21(y) and 21(z) screw axes and adjacent layers are rotated by 180° along the [001] direction relative to each other. Therefore, the layer orientations alternate, and an ABAB packing motif is observed (Figure S7a). In the case of 5-Y, adjacent layers are simply transformed into each other through the c crystallographic translation, which has a small in-layer shift because the β angle slightly deviates from 90°. In other words, the arrangement of the layers in 5-Y can be described as a distorted AAA motif (Figure S7b). Thus, 3-Ln and 5-Y are polytypes. Variable layer arrangements (i.e., polytypism) for RE lactates are possible due to the weak non-specific interlayer interactions, as all hydrogen bonds are intralayer. A similar case of polytypism was previously reported for yttrium and heavy lanthanide (Ho–Lu) propionates [18].
As described for 3-Ln, the crystal structures of 4-Ln consist of discrete [Ln(H2O)2Lact3] molecules (Figure 6a) interlinked into hydrogen-bonded species [Ln(H2O)2Lact3]∞ (d(O∙∙∙O)~2.66–2.77 Å, shortest d(Ln∙∙∙Ln) 5.8257(5) Å for 4-Sm), and the overall arrangement of molecules in the unit cell is very similar to that of 3-Ln. However, unlike 3-Ln, neighboring [Ln(H2O)2Lact3]∞ species in 4-Ln are linked through hydrogen bonds (d(O∙∙∙O)~2.70 Å for 4-Sm) into double chains {[Ln(H2O)2Lact3]∞}2 rather than extended layers. The b unit cell parameter, which is primarily responsible for the interchain Ln∙∙∙Ln separation, turns out to be significantly elongated with respect to that of 3-Ln (13.3765(12) and 10.7147(3) Å for 4-Sm and 3-Gd, respectively). Packing cavities between {[Ln(H2O)2Lact3]∞}2 double chains are occupied by non-coordinated water molecules, which form three hydrogen bonds each with adjacent {[Ln(H2O)2Lact3]∞}2 chains (d(O∙∙∙O)~2.69–2.85 Å for 4-Sm) to yield a hydrogen-bonded 3D-framework (Figure 6b).
As mentioned in Section 2.1, RE carboxylates are structurally flexible, and addition/elimination of solvent molecules often leads to the drastic changes in the molecular structure or/and crystal packing [56]. Thus, compounds 3-Ln and 4-Ln represent a peculiar example of RE carboxylates where the introduction of ancillary water molecules retains the coordination environment of Ln centers as well as certain features at the supramolecular level (i.e., [Ln(H2O)2Lact3]∞ chain-like species).
To summarize the data on RE lactate structures, a number of conclusions should be pointed out. First of all, Lact-anions are prone to forming stable five-membered chelate rings with RE cations through COO- and OH-groups rather than the four-membered chelate rings abundant among non-substituted RE carboxylates [13,18,56,57]. In the case of medium- and small-radius Ln3+ cations (Sm–Lu, Y), formation of three chelating cycles along with coordination of two water molecules is enough to fulfill the coordination preferences of the metal center without any ancillary chemical interactions. Furthermore, lactate ligands can form additional COO–Ln bonds (i.e., exhibit a chelating-bridging mode) if the coordination sphere of Ln centers cannot be fully saturated by chelate cycles. This occurs, for instance, for larger RE (La, Ce–Nd) lactates where the nine-fold coordination polyhedron of Ln is completed through the additional Ln–O bonding with neighboring structural units, yielding polymeric (1-Ln) or binuclear (2-Ln) structures depending on the amount of coordinated water molecules. Formation of coordination polymers is possible for medium-radius Eu3+ and Tb3+ cations if lactate ligands are partially substituted with non-coordinating anions (e.g., in the structures of {[Ln(H2O)2Lact2](ClO4)}∞ [42,43]). In this case, two chelating cycles cannot provide the desired eight-fold coordination environment of RE cations; consequently, the coordination mode for all lactate ligands switches to chelating-bridging to yield a 2D-polymeric network.

2.3. Thermal Decomposition of RE Lactates

According to the TGA data, all RE lactates undergo multi-step thermal decomposition. The first stage corresponds to the desolvation, and its characteristic temperature significantly differs for the 1-Ln–4-Ln structural types. In general, compounds with non-coordinated water molecules (2-Ln and 4-Ln) undergo desolvation at lower temperatures than those with only coordinated water molecules (1-Ln, 3-Ln). Indeed, [Ln(H2O)2Lact3]∞ (1-Ln; Ln = La, Ce, Pr) begin to decompose at ca. 110–120 °C (Figure S1). An analogous process for [Ln(H2O)2Lact3] (3-Ln; Ln = Sm–Lu, Y) generally starts at 100–120 °C (Figures S2 and S3). On the other hand, hydrated complexes [Ln2(H2O)5Lact6]∙H2O (2-Ln; Ln = La, Ce–Nd) decompose at temperatures higher than ~80 °C; furthermore, both coordinated and non-coordinated water molecules are removed in a single stage with no intermediate products, e.g., 1-Ln, being formed (Figure 7a and Figure S1).
For the hydrated compounds [Ln(H2O)2Lact3]∙H2O (4-Ln; Ln = Sm–Gd, Y), TG-curves reveal a two-step desolvation process. Namely, these partially decompose upon minor heating (30–60 °C) to form the respective [Ln(H2O)2Lact3] (3-Ln) complexes, which remain stable up to 100–120 °C and then undergo complete desolvation (Figure 7b and Figure S4).
Upon further heating, the products of desolvation (anhydrous RE lactates) decompose through multiple overlapping stages that presumably refer to the competing processes of the pyrolysis and combustion of organic ligands. As follows from the TGA data, the thermal stability of anhydrous RE lactates slightly decreases in the Ln series, with a pronounced anomaly in the case of Ce lactate. The latter decomposes at significantly lower temperatures (above ~125 °C, as observed for 2-Ce—Figure S1) than the neighboring La and Pr compounds, presumably due to the oxidation of CeIII. The final step on TG-curves (except for 1-Ce and 2-Ce, which immediately yield CeO2 after the decomposition of ligands) corresponds to the decomposition of RE carbonates or/and oxocarbonates.
The differences in the desolvation processes for 2-Ln and 4-Ln have additionally been proven by means of variable-temperature PXRD (VT-PXRD) using the example of the 2-Pr and 4-Gd compounds (Figure 8 and Figure S8). In the former case, the PXRD pattern remains virtually unchanged up to 100 °C, i.e., the native [Pr2(H2O)5Lact6]∙H2O (2-Pr) phase remains stable in this temperature region (Figure 8a). Upon further heating, the initial hydrated complex undergoes gradual decomposition, eventually yielding an amorphous product (presumably, anhydrous Pr lactate) at 140 °C that exhibits only a diffuse X-ray scattering halo rather than sharp X-ray diffraction peaks. It is worth noting that no intermediate phases (e.g., 1-Pr—[Pr(H2O)2Lact3]∞) were observed during the desolvation process; therefore, 2-Pr indeed eliminates all water molecules in a single stage.
A different behavior was observed for 4-Gd. As follows from the VT-PXRD data, the initial [Gd(H2O)2Lact3]∙H2O phase retains up to 60 °C. At higher temperatures the PXRD pattern changes rapidly, indicating the formation of the pure 3-Gd phase upon the removal of non-coordinated water molecules (Figure 8b and Figure S8). In other words, the desolvation of [Gd(H2O)2Lact3]∙H2O (4-Gd) is actually a two-step process involving an intermediate [Gd(H2O)2Lact3] (3-Gd) product, as observed in the TGA experiments (Figure 7b). The product of total desolvation, which is formed above 160–170 °C, is amorphous.
The observed differences in the thermal behavior of RE lactate hydrates can be explained on the basis of their crystal structures. Indeed, the transition from 4-Ln to 3-Ln only involves the removal of non-coordinated water molecules and slight lattice distortions. On the other hand, 2-Ln and 1-Ln exhibit major structural differences, and the former cannot be simply transformed into the latter through a solid-state process at relatively low (ca. 100 °C) temperatures.

2.4. Ln2O3 Thin Films

Thin films of RE sesquioxides have been previously used as planarization sublayers for second-generation HTS tapes [58,59,60]; the major characteristic of such films is their root-mean-square roughness (henceforth Sq), which is expected to be lower than that of the original substrate. Highly smooth coatings are usually fabricated from amorphous or nanocrystalline oxides, which are formed upon the low-temperature (500–600 °C) heat treatment of the respective metal–organic precursors [60].
A Y2O3 thin film (Y-F1) was deposited onto an as-rolled hastelloy HC276 tape with a native surface possessing an Sq value of 8.2 nm (Figure S9a). As estimated from AFM data, the Y-F1 coating has a significantly enhanced smoothness (Sq = 4.9 nm for a 5 × 5 μm2 scan area, Figure 9a), i.e., a planarization effect is achieved even through only one deposition cycle. The θ–θ XRD scan of Y-F1 reveals no Bragg reflections except those of the substrate material (Figure S10); therefore, the Y-F1 film exhibits no crystallinity, similarly to the Y2O3 film obtained from the yttrium acetate precursor [60]. One-cycle deposition of a La2O3 film onto an as-rolled HC276 substrate (La-F1) reduces its mean roughness, yielding an Sq value of 5.1 nm (5 × 5 μm2 scan area; Figure 9b), which is close to that of the Y-F1 coating. In other words, both Y-F1 and La-F1 make a comparable planarization effect. The smoothness of the surface can be further enhanced via multiple cycles of deposition that makes it possible to produce planar buffer layers for the fabrication of second-generation HTS tapes. To highlight this effect, preliminarily electropolished HC276 tape with a residual Sq of 1.1 nm (Figure S9b) was coated with a La-based thin film (La-F2) deposited from a twice-diluted solution of lanthanum lactate-based precursor (La-S2) through seven cycles of deposition. As a result, a highly smooth (Sq = 0.45 nm, Figure S11) surface was obtained.

3. Materials and Methods

Ln(NO3)3∙nH2O (“Reakhim, Moscow, Russia”, reagent grade), Ln2(CO3)3∙mH2O (“Reakhim”, reagent grade), aqueous ammonia (CNH3 = 16 mol/l, “Reakhim”, reagent grade), aqueous lactic acid (HLact, 80%wt, “Reakhim”, analytical grade), isopropanol (iPrOH, “NPP ‘Gamma’, Moscow, Russia”, reagent grade), and diethylenetriamine (DETA, “Sigma-Aldrich, Darmstadt, Germany”, 99%) were purchased from local suppliers and used without further purification. Polycrystalline hastelloy HC276 tapes were purchased from SuperOx LLC (Moscow, Russia).
TG-DTA data (air atmosphere, temperature range 25–1000 °C, heating rate 10 °C/min, sample mass ca. 50 mg) were recorded on a Derivatograph Q-1500 D instrument (MOM, Budapest,). Measurements of C and H contents were carried out using an Elementar Vario MICRO cube instrument (Elementar Analysensysteme GmbH, Langenselbold, Germany). Ln content was determined by complexometric titration (acetate buffer, Xylenol orange) as well as from the TGA data at 1000 °C.
FTIR spectra were recorded on a Perkin-Elmer Spectrum One FTIR spectrometer (PerkinElmer Inc., Waltham, USA) in the attenuated total reflectance (ATR) geometry in the wavenumber range of 650−4000 cm−1.
PXRD data of powder samples at 300 K were collected using a Rigaku MINIFLEX (600 W X-ray tube, Cu Kα radiation, Kβ-filter, symmetrical reflection θ−2θ mode, D/teX Ultra 1D-linear detector, Rigaku, Tokyo, Japan) laboratory diffractometer.
Variable-temperature PXRD (VT-PXRD) experiments were performed in a temperature range of 30–180 °C in the Debye–Scherrer geometry (2θ range 2.6–41.2°) on a Bruker D8 QUEST diffractometer (Photon III CMOS area detector, Mo Kα radiation, Montel optics, Bruker AXS Inc., Madison, USA) equipped with a hot air blower. Samples were placed into opened Kapton® capillaries of 0.5 mm diameter. The in situ heating experiment was performed in a stepwise heating mode (10 °C/step) with an average heating rate of 3 °C/min. As described recently, 2D diffraction patterns were processed using FormagiX v.0.9.5. software and calibrated with an NIST SRM660c LaB6 reference sample [61].
The phase composition of thin films was studied by means of XRD using a Rigaku SmartLab diffractometer (Cu Kα1 radiation, incident beam Ge (220)×2 monochromator, symmetrical reflection θ–θ mode). The surface morphology and roughness of films were examined by atomic force microscopy (AFM) on an NT-MDT NTegra Aura instrument (NT-MDT, Moscow, Russia) in semi-contact mode.

3.1. Synthesis and Crystal Growth of RE Lactates

RE lactate complexes LnLact3∙nH2O (Ln = Y, La, Ce–Nd, Sm–Lu; n = 2–3) of four structural types (1-Ln–4-Ln) were obtained from aqueous solutions by three different synthetic routes, as described below. The chemical and phase composition of all obtained products were confirmed by means of CHN, TG-DTA, FTIR, and XRD analyses.
Procedure I. A 10 mmol amount of Ln(NO3)3∙6H2O was dissolved in 40 mL of distilled water. After that, 2.2 mL of aqueous ammonia (CNH3 = 16 M, ca. 35 mmol NH3) was added upon stirring. The resulting precipitate was centrifuged and washed with distilled water three times, then suspended in 10 mL of H2O; next, 30 mmol of HLact was added to the reaction mixture. The latter was stirred at elevated temperatures (ca. 75 °C) to obtain a clear solution. The resulting solution for Ln = La–Nd was slowly cooled to room temperature and stored in air for evaporation and crystallization within 3–8 weeks, which yielded crystals of 2-Ln. Alternatively, the same solution was evaporated upon heating until the crystallization began (to ca. 50% of its initial volume) and then cooled to room temperature. Precipitates of the 1-Ln phase for Ln = La–Pr, as well as 3-Ln or 4-Ln for Ln = Sm–Lu and Y, were obtained in this manner.
The resulting precipitate was filtered off, washed with several milliliters of H2O and EtOH, and stored in a desiccator over NaOH (1-Ln, 2-Ln, and 3-Ln) or in air (4-Ln). The yields were 65–85%.
Procedure II. A 5 mmol amount of Ln2(CO3)3∙nH2O was dispersed in 60 mL of water and 40 mmol of HLact was added to the reaction mixture. The latter was refluxed at 100 °C for 2 h and cooled to the room temperature, which yielded a fine crystalline precipitate. The latter was treated in the same manner as described above. The yield was ca. 85%.
Procedure III. A 10 mmol amount of Ln(NO3)3∙6H2O was dissolved in 40 mL of distilled water. An aqueous solution of NH4Lact was prepared separately by mixing 1.9 mL of aqueous ammonia (CNH3 = 16 M, ca. 30 mmol NH3) and 31 mmol of HLact in 40 mL of water. The prepared solutions were mixed upon vigorous stirring and evaporated to ca. 50% of the initial volume. Crystallization occurred within 0.5–24 h after the synthesis, and the resulting precipitate was treated in the same manner as described above. The yield was ca. 60%.
In all procedures, the mother liquors left after filtration were slowly evaporated in ambient conditions for several days; X-ray quality single crystals of 3-Gd and 4-Sm were obtained in this manner. Crystals of 1-La and 1-Pr were grown from hot supersaturated solutions of the respective RE lactates. Single crystals of 2-La, 2-Ce, and 2-Pr were harvested directly from the respective bulk products prepared via slow (3–8 weeks) crystallization in ambient conditions.
  • [La(H2O)2Lact3]∞ (1-La). Calc. for C9H19LaO11 (%): La, 31.42; C, 24.45; H, 4.33. Found (%): La, 31.3; C, 24.8; H, 4.5. FTIR (ATR, ν, cm−1): 3338sh, 3264, 2992w, 2935vw, 2876vw (νOH, νCH); 1705w; 1698w; 1668w (δH2O); 1590sh, 1557s (νasCOO); 1486sh, 1477sh, 1465 (δasCH3); 1439vw; 1425w, 1391 (νsCOO, δCOH); 1375w; 1365, 1359sh, 1351sh (δsCH3); 1319; 1284; 1242s; 1130s; 1117s; 1093; 1055; 1037; 937; 864; 815; 773, 765 (δCOO); 660.
  • [Ce(H2O)2Lact3]∞ (1-Ce). Calc. for C9H19CeO11 (%): Ce, 31.60; C, 24.38; H, 4.32. Found (%): Ce, 31.5; C, 24.3; H, 4.3. FTIR (ATR, ν, cm−1): 3335sh, 3256, 2993w, 2936vw, 2877vw (νOH, νCH); 1705w; 1695sh; 1664w (δH2O); 1588sh, 1557s (νasCOO); 1485sh, 1478sh, 1464 (δasCH3); 1439w; 1425w, 1388 (νsCOO, δCOH); 1364, 1359, 1351 (δsCH3); 1318; 1283; 1243s; 1126s; 1117s; 1093; 1055; 1036; 937; 864; 815; 774, 764 (δCOO); 660.
  • [Pr(H2O)2Lact3]∞ (1-Pr). Calc. for C9H19O11Pr (%): Pr, 31.73. Found (%): Pr, 31.6. FTIR (ATR, ν, cm−1): 3338sh, 3255, 2995w, 2939vw, 2879vw (νOH, νCH); 1704vw; 1694vw; 1662w (δH2O); 1591sh, 1558 (νasCOO); 1480, 1466 (δasCH3); 1440w; 1426w, 1391 (νsCOO, δCOH); 1375w; 1365, 1358, 1352sh (δsCH3); 1330; 1319; 1284; 1245s; 1130s; 1118s; 1094; 1056; 1037; 938; 865; 817; 774, 764 (δCOO); 660.
  • [La2(H2O)5Lact6]∙H2O (2-La). Calc. for C18H42La2O24 (%): La, 30.19; C, 23.49; H, 4.60. Found (%): La, 30.4; C, 23.6; H, 4.5. FTIR (ATR, ν, cm−1): 3562sh, 3303sh, 3170, 2985vw, 2941vw (νOH, νCH); 1665w, 1653sh, 1645sh (δH2O); 1568s (νasCOO); 1475 (δasCH3); 1424sh, 1395 (νsCOO, δCOH); 1378sh; 1363 (δsCH3); 1320, 1277sh, 1268; 1232w; 1127; 1116s; 1089; 1041s; 932; 865; 845w; 774 (δCOO); 663.
  • [Ce2(H2O)5Lact6]∙H2O (2-Ce). Calc. for C18H42Ce2O24 (%): Ce, 30.37; C, 23.43; H, 4.59. Found (%): Ce, 31.2; C, 23.0; H, 4.6. FTIR (ATR, ν, cm−1): 3319sh, 3203, 2986w, 2941vw (νOH, νCH); 1662vw, 1645sh (δH2O); 1564s (νasCOO); 1471vw, 1465sh, 1456sh (δasCH3); 1423sh, 1395 (νsCOO, δCOH); 1387sh; 1377sh; 1362 (δsCH3); 1319; 1280sh; 1266w; 1230sh; 1124sh; 1116s; 1089; 1041s; 932; 865; 845w; 819w; 774 (δCOO); 707sh; 660.
  • [Pr2(H2O)5Lact6]∙H2O (2-Pr). Calc. for C18H42O24Pr2 (%): Pr, 30.49. Found (%): Pr, 30.6. FTIR (ATR, ν, cm−1): 3569vw, 3328sh, 3199, 2985vw, 2941vw (νOH, νCH); 1660, 1650sh (δH2O); 1567s, 1556sh (νasCOO); 1475 (δasCH3); 1426sh, 1398 (νsCOO, δCOH); 1389sh; 1384sh; 1376sh; 1363 (δsCH3); 1320; 1306sh; 1279w; 1266; 1126; 1116s; 1090; 1042s; 933w; 866; 848w; 816wv; 774 (δCOO); 711sh; 663.
  • [Nd2(H2O)5Lact6]∙H2O (2-Nd). Calc. for C18H42Nd2O24 (%): Nd, 30.99. Found (%): Nd, 32.0. FTIR (ATR, ν, cm−1): 3319sh, 3195, 2980sh, 2975sh, 2967sh, 2942vw, 2936sh, 2897w, 2880w (νOH, νCH); 1659w, 1651sh (δH2O); 1570s, 1559sh (νasCOO); 1471, 1450vw (δasCH3); 1423sh, 1399 (νsCOO, δCOH); 1385sh; 1363 (δsCH3); 1320; 1280; 1266; 1223; 1126; 1116s; 1092; 1042s; 933; 866; 849; 812sh; 775 (δCOO); 710sh; 672; 663.
  • [Sm(H2O)2Lact3] (3-Sm). Calc. for C9H19O11Sm (%): Sm, 33.15; C, 23.83; H, 4.22. Found (%): Sm, 33.2; C, 23.6; H, 4.3. FTIR (ATR, ν, cm−1): 3399, 3159sh, 3054, 2997, 2989, 2980sh, 2957w, 2943sh, 2883vw (νOH, νCH); 1668sh (δH2O); 1577s (νasCOO); 1481, 1470, 1456sh (δasCH3); 1427sh, 1407sh, 1404sh, 1391s (νsCOO, δCOH); 1365, 1358 (δsCH3); 1320sh; 1314s; 1281; 1270sh; 1263; 1111s; 1094; 1045s; 932; 863; 782, 776sh (δCOO); 759; 709; 665sh.
  • [Eu(H2O)2Lact3] (3-Eu). Calc. for C9H19EuO11 (%): Eu, 33.38. Found (%): Eu, 33.7. FTIR (ATR, ν, cm−1): 3403, 3158sh, 3058, 2997, 2989, 2980sh, 2958w, 2938w, 2885sh (νOH, νCH); 1663sh (δH2O); 1583s (νasCOO); 1482, 1469, 1457sh (δasCH3); 1427sh, 1408sh, 1393s (νsCOO, δCOH); 1365, 1359 (δsCH3); 1321sh; 1314s; 1282; 1272; 1265; 1112s; 1095; 1046s; 932; 863; 783, 776sh (δCOO); 758; 712; 651.
  • [Gd(H2O)2Lact3] (3-Gd). Calc. for C9H19GdO11 (%): Gd, 34.15. Found (%): Gd, 34.1. FTIR (ATR, ν, cm−1): 3403, 3161sh, 3074, 3013vw, 2998w, 2978vw, 2960w, 2946w, 2845vw (νOH, νCH); 1668sh (δH2O); 1585s (νasCOO); 1480, 1465 (δasCH3); 1409sh, 1394s (νsCOO, δCOH); 1372, 1358 (δsCH3); 1314s; 1278sh; 1263; 1115s; 1092sh; 1045s; 933; 864; 787, 768, 753sh (δCOO); 710; 651.
  • [Tb(H2O)2Lact3] (3-Tb). Calc. for C9H19O11Tb (%): Tb, 34.39. Found (%): Tb, 34.1. FTIR (ATR, ν, cm−1): 3403, 3151sh, 3061, 2997, 2989, 2981sh, 2955w, 2938w, 2883sh (νOH, νCH); 1661sh (δH2O); 1580s (νasCOO); 1483, 1468, 1456sh (δasCH3); 1428sh, 1409sh, 1393s (νsCOO, δCOH); 1365, 1359 (δsCH3); 1321sh; 1315s; 1281sh; 1271sh; 1264; 1112s; 1096; 1046s; 933; 864; 783, 776sh (δCOO); 759sh; 715; 666sh; 651.
  • [Dy(H2O)2Lact3] (3-Dy). Calc. for C9H19DyO11 (%): Dy, 34.89. Found (%): Dy, 35.3. FTIR (ATR, ν, cm−1): 3405, 3161sh, 3061, 2997w, 2990w, 2959sh, 2941sh, 2881vw (νOH, νCH); 1581s (νasCOO); 1485, 1468 (δasCH3); 1413sh, 1394s (νsCOO, δCOH); 1366w, 1359 (δsCH3); 1315s; 1282sh; 1273sh; 1265; 1123sh; 1112s; 1096; 1047s; 934; 864; 784, 775sh, 760sh (δCOO); 716; 651.
  • [Ho(H2O)2Lact3] (3-Ho). Calc. for C9H19HoO11 (%): Ho, 35.23; C, 23.09; H, 4.09. Found (%): Ho, 35.9; C, 22.8; H, 4.2. FTIR (ATR, ν, cm−1): 3405, 3158sh, 3064, 2981, 2967, 2942sh, 2880vw (νOH, νCH); 1666sh (δH2O); 1583s (νasCOO); 1485, 1469 (δasCH3); 1415sh, 1395s (νsCOO, δCOH); 1366, 1359 (δsCH3); 1323sh; 1315; 1283sh; 1273sh; 1266; 1124sh; 1113s; 1096; 1047s; 934; 865; 785, 775sh (δCOO); 719; 651.
  • [Er(H2O)2Lact3] (3-Er). Calc. for C9H19ErO11 (%): Er, 35.55. Found (%): Er, 35.6. FTIR (ATR, ν, cm−1): 3406, 3157sh, 3059, 3019vw, 2997sh, 2990, 2981sh, 2961w, 2940vw, 2878sh (νOH, νCH); 1666sh (δH2O); 1584s (νasCOO); 1487, 1469 (δasCH3); 1434sh, 1416sh, 1397s (νsCOO, δCOH); 1378sh; 1366, 1359 (δsCH3); 1324sh; 1316; 1283; 1273sh; 1267; 1125w; 1113s; 1096; 1047s; 935; 865; 786, 776sh (δCOO); 722; 673vw; 654.
  • [Tm(H2O)2Lact3] (3-Tm). Calc. for C9H19O11Tm (%): Tm, 35.78. Found (%): Tm, 37.2. FTIR (ATR, ν, cm−1): 3408, 3158sh, 3062, 2996sh, 2989, 2983sh, 2966w, 2950vw 2931vw, 2879vw (νOH, νCH); 1663sh (δH2O); 1583s (νasCOO); 1487, 1469 (δasCH3); 1434sh, 1413sh, 1396s (νsCOO, δCOH); 1380; 1366, 1359 (δsCH3); 1322sh; 1316s; 1282sh; 1272sh; 1266; 1113s; 1097; 1048s; 935; 865; 785, 777sh (δCOO); 723.
  • [Yb(H2O)2Lact3] (3-Yb). Calc. for C9H19O11Yb (%): Yb, 36.33. Found (%): Yb, 35.6. FTIR (ATR, ν, cm−1): 3419, 3167sh, 3062, 3001, 2983, 2941, 2892w (νOH, νCH); 1663sh (δH2O); 1583s (νasCOO); 1487, 1471 (δasCH3); 1434sh, 1414sh, 1398s (νsCOO, δCOH); 1379; 1364 (δsCH3); 1318s; 1284; 1267; 1126; 1114s; 1102sh; 1098sh; 1048s; 935; 866; 786, 777sh (δCOO); 722; 651.
  • [Lu(H2O)2Lact3] (3-Lu). Calc. for C9H19LuO11 (%): Lu, 36.59. Found (%): Lu, 37.8. FTIR (ATR, ν, cm−1): 3408, 3146sh, 3066, 2996sh, 2990, 2983sh, 2941sh, 2879vw (νOH, νCH); 1667sh (δH2O); 1584s (νasCOO); 1485, 1470 (δasCH3); 1434sh, 1414sh, 1399s (νsCOO, δCOH); 1380; 1366, 1360 (δsCH3); 1323sh; 1316s; 1282sh, 1273sh, 1268; 1113s; 1098; 1049s; 936; 866; 786, 776sh (δCOO); 727.
  • [Y(H2O)2Lact3] (3-Y). Calc. for C9H19O11Y (%): Y, 22.67; C, 27.57; H, 4.88. Found (%): Y, 23.4; C, 27.3; H, 4.9. FTIR (ATR, ν, cm−1): 3407, 3159sh, 3062, 2996sh, 2990, 2980sh, 2941sh, 2881vw (νsCOO, δCOH); 1583 (νasCOO); 1484, 1469 (δasCH3); 1416sh, 1396s (νsCOO, δCOH); 1377sh, 1365, 1359 (δsCH3); 1323sh; 1315s; 1283sh; 1275sh; 1266; 1124sh; 1113s; 1096; 1047s; 934; 865; 785, 775sh (δCOO); 719; 652.
  • [Sm(H2O)2Lact3]∙H2O (4-Sm). Calc. for C9H21O12Sm (%): Sm, 31.88. Found (%): Sm, 31.8. FTIR (ATR, ν, cm–1): 3492vw, 3399w, 3157sh, 3068, 2997w, 2989w, 2979sh, 2959vw, 2941sh. 2883vw (νOH, νCH); 1634sh (δH2O); 1582s (νasCOO); 1480, 1467 (δasCH3); 1407sh, 1391s (νsCOO, δCOH); 1367, 1358 (δsCH3); 1322sh; 1314s; 1280sh; 1271sh; 1264; 1114s; 1094; 1045s; 932; 863; 782, 774sh (δCOO); 707; 650.
  • [Eu(H2O)2Lact3]∙H2O (4-Eu). Calc. for C9H21EuO12 (%): Eu, 32.11. Found (%): Eu, 32.2. FTIR (ATR, ν, cm–1): 3492vw, 3402vw, 3157sh, 3084, 3014w, 2999w, 2978w, 2960vw, 2949vw (νOH, νCH); 1636 (δH2O); 1588s (νasCOO); 1479, 1465 (δasCH3); 1409s, 1396sh (νsCOO, δCOH); 1372, 1358 (δsCH3); 1315s; 1278; 1264; 1116s; 1092sh; 1045s; 931; 864; 788, 768 (δCOO); 705.
  • [Y(H2O)2Lact3]∙H2O (4-Y). Calc. for C9H21O12Y (%): Y, 21.68. Found (%): Y, 21.5. FTIR (ATR, ν, cm–1): 3492vw, 3405sh, 3170sh, 3086, 3014w. 2999w, 2979w, 2963w, 2946w (νOH, νCH); 1639 (δH2O); 1591s (νasCOO); 1482sh, 1466 (δasCH3); 1412, 1401 (νsCOO, δCOH); 1373, 1359 (δsCH3); 1316s; 1279; 1265; 1115s; 1092w; 1051sh; 1045s; 934; 866; 790, 769 (δCOO); 708w; 677w.

3.2. Preparation of Precursor Solutions and Deposition of Ln2O3 Thin Films

Thin films of Y2O3 and La2O3 oxides were deposited onto metallic polycrystalline cold-rolled hastelloy HC276 substrates (length 100 mm, width 12 mm, thickness 110 μm) by the MOCSD method.
A Y-based precursor solution (Y-S1) with Y3+ concentration of 0.1 M was prepared as follows. First, 3.14 g (8 mmol) of [Y(H2O)2Lact3] (3-Y) was dispersed in several milliliters of iPrOH. DETA (13 mL, 120 mmol) was added and the reaction mixture was diluted with iPrOH to reach a total volume of 80 mL. The reaction mixture was stirred upon heating to ca. 90 °C until the solid reagent completely dissolved. Residual insoluble admixtures were filtered off, and the resulting clear solution was used for the deposition of thin films. La-based precursor solutions (La-S1 and La-S2) were prepared in an analogous manner. The concentrations of La3+ ions were 0.1 M and 0.05 M for La-S1 and La-S2, respectively. Additionally, the La:DETA ratio was different for these solutions, at 15:1 for La-S1 and 13:1 for La-S2.
The tape substrate was submerged into the bath with the precursor solution and pulled out in the vertical direction at a rate of 1 mm/s and then passed through two tube furnaces for drying (100 °C, air atmosphere) and combustion (500 °C, ozonized air atmosphere, gas flow 5 L/min, ozone concentration 0.6 mg/L) to yield the required thin films. Y-F1 and La-F1 films were produced from the Y-S1 and La-S1 solutions, respectively, through a single deposition cycle onto as-rolled hastelloy substrates, while La-F2 was deposited from the La-S2 solution through seven cycles onto an electropolished hastelloy substrate. The detailed scheme of the laboratory-made MOCSD apparatus used here was reported by us earlier in [62,63].

3.3. X-ray Crystallography

Single-crystal XRD data were collected on three laboratory diffractometers (Bruker AXS Inc., Madison, USA): a Bruker D8 QUEST (Photon III CMOS area detector, Mo Kα radiation, Montel optics), Bruker Smart APEX II (CCD area detector, Mo Kα radiation, graphite monochromator), and Bruker Smart APEX DUO (CCD area detector, Mo Kα radiation, graphite monochromator), as well as on the XRD1 beamline (λ = 0.70000 Å, Dectris Pilatus 2M detector, DECTRIS AG, Baden, Switzerland) of the Elettra synchrotron facility (Trieste, Italy). Diffraction datasets obtained with the laboratory diffractometers were indexed and integrated using SAINT from the SHELXTL PLUS package [64,65,66], whereas the synchrotron diffraction data were processed using CrysAlisPRO v.40.67a [67] software. Crystal structures were solved by direct methods (SHELXS) and refined anisotropically for all non-H atoms with the full-matrix F2 least-squares technique (SHELXL). Hydrogen atoms of water molecules and hydroxyl groups were located from the difference Fourier maps and refined with soft restraints on O–H distances and H–O–H angles. All other H atoms were placed in geometrically calculated positions and refined in a riding model. Absorption correction was applied using SADABS v. 2016/2 [68] and SCALE3 ABSPACK v.1.0.4 [69]. Further details on the data collection and refinement parameters are summarized in Table S1.
The crystal structures of 3-Sm and 3-Y were determined from powder XRD data by Rietveld refinement. PXRD data were collected on a Rigaku SmartLab (Rigaku, Tokyo, Japan) diffractometer (9 kW rotating anode, Cu Kα radiation, secondary graphite monochromator) operated in symmetrical reflection θ–θ mode. The powder sample was placed into a side-loaded sample holder, which was rotated along the φ-axis during the measurements in order to avoid texturing effects and to improve the statistics. Structures were solved using the initial model prepared from the 4-Sm homologue by omitting free water molecules and distorting the unit cell, followed by the full-profile Rietveld method in JANA2006 [70] with soft restraints on bond distances and valence angles within Lact-anions as well as on Ln–O bond distances. Positions of the H-atoms of water molecules were determined geometrically based on the analysis of H-bonds, while other H atoms were placed in idealized positions. All atoms were refined isotropically with Uiso(Ln), a common Uiso(C) for all C-atoms, the Uiso(OLact) of all O-atoms of Lact-anions, and Uiso(OW) for the O atoms of H2O molecules. All H-atoms were refined in a riding model with fixed isotropic thermal parameters. PXRD patterns were fitted with a nine-term Legendre polynomial background and a five-term pseudo-Voigt peak shape function, with asymmetry corrected by axial divergence.
Continuous Shape Measures (CShM) analysis of RE coordination polyhedra in the crystal structures of 1-Ln–4-Ln was carried out using Shape v.2.1 software [55].
CCDC 2277672–2277680 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html (accessed on 30 June 2023) or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44 1223 336033; E-mail: [email protected].

4. Conclusions

In general, rare-earth carboxylates exhibit an extreme structural diversity; introduction of ancillary functional groups into the structure of anionic ligands (e.g., OH-groups) may lead to novel metal–ligand binding modes, yielding unusual molecular and supramolecular motifs. In the present work, this feature has been demonstrated for rare-earth lactates with crystal structures of four different types; these have been systematically studied throughout the whole rare-earth series. The main feature of all structures revealed here is the presence of five-membered chelate rings formed by rare-earth cations and lactate ligands. Unlike non-substituted rare-earth carboxylates (e.g., acetates), which are prone to forming oligonuclear and polymeric complexes through bridging and chelating-bridging coordination, metal–lactate chelate rings favor the formation of mononuclear complexes for medium- and small-radius rare-earth cations (Sm–Lu, Y). Nevertheless, additional chelating-bridging coordination of lactate ligands, which yields binuclear or polymeric species, is possible if the coordination environment of the metal center is not fully saturated by chelate rings (e.g., for La and Ce–Nd lactates). Interestingly, mononuclear Sm–Lu and Y lactate hydrates have been found to exhibit polytypism, i.e., polymorphism implying different arrangements of hydrogen-bonded layers with the virtually identical configuration of a single layer. Regarding the practical application of rare-earth lactates, these have been proven to be efficient precursors for the chemical solution deposition of rare-earth oxide thin films, as demonstrated for the example of Y2O3 and La2O3 coatings. In addition to their high smoothness, thin films of La2O3 are also prospective high-k materials (κ~27) for semiconductor electronics. Furthermore, molecular lactate complexes exist for many transition metals, solutions of which are expected to be compatible with those of rare-earth lactates. This makes it possible to use metal lactates for the fabrication of 3d–4f heterometallic oxide nanomaterials (rare-earth nickelates, ferrites, manganites, etc.), which is the primary goal of our further research.

Supplementary Materials

The following supporting information can be downloaded at: https://www.mdpi.com/article/10.3390/molecules28155896/s1, Figure S1: TG-DTG curves for [Ln(H2O)2Lact3]∞ (1-Ln; Ln = La, Ce, Pr) and [Ln2(H2O)5Lact6]∙H2O (2-Ln; Ln = La, Ce, Pr, Nd); Figure S2: TG-DTG curves for [Ln(H2O)2Lact3] (3-Ln; Ln = Sm–Ho; part 1); Figure S3: TG-DTG curves for [Ln(H2O)2Lact3] (3-Ln; Ln = Er–Lu, Y; part 2); Figure S4: TG-DTG curves for [Ln(H2O)2Lact3]∙H2O (4-Ln; Ln = Sm–Gd, Y); Table S1: Crystal and refinement data for 1-Ln–4-Ln; Table S2: Selected interatomic distances for the crystal structures of 1-Ln and 2-Ln estimated from single-crystal and powder XRD data; Table S3: Selected interatomic distances for the crystal structures of 3-Ln and 4-Ln estimated from single-crystal and powder XRD data; Table S4: Continuous Shape Measures (CShM) analysis of RE coordination polyhedra in the crystal structures of 1-Ln–4-Ln; Figure S5: Room-temperature PXRD data for 3-Sm: the experimental pattern, Rietveld refinement fit, difference profile, and positions of Bragg peaks; Figure S6: Room-temperature PXRD data for 3-Y: the experimental pattern, Rietveld refinement fit, difference profile, and positions of Bragg peaks; Figure S7: Comparison of the layer arrangement for 3-Gd and 5-Y; Figure S8: Sections of VT-PXRD color maps (Mo Kα radiation) for 2-Pr and 4-Gd lactates in comparison with the respective theoretical PXRD patterns; Figure S9: AFM topography (5 × 5 μm2 scans) of the Hastelloy substrates (as-rolled and electropolished tapes); Figure S10: θ–θ XRD scan for the Y-F1 thin film; Figure S11: AFM topography (5 × 5 μm2 scan) of the La-F2 film on the electropolished Hastelloy HC276 substrate.

Author Contributions

Conceptualization, I.M. and D.T.; methodology, I.M. and D.T.; investigation, R.G., I.M. and D.T.; formal analysis, M.K., R.G. and D.T.; validation, M.K. and D.T.; visualization, M.K., R.G. and D.T.; writing—original draft preparation, M.K. and D.T.; writing—review and editing, M.K., R.G. and D.T.; supervision, D.T.; project administration, D.T.; funding acquisition, D.T. All authors have read and agreed to the published version of the manuscript.

Funding

D.T., R.G., and M.K. acknowledge the Russian Science Foundation (RSF project 22-73-10089) for funding the determination of the crystal structures of Sm and Y lactates, for the analysis of the supramolecular arrangement of layered compounds and for VT-PXRD experiments. D.T., I.M., R.G., and M.K. acknowledge support from the Russian Foundation for Basic Research (project 20-33-70096) for synthesis, determination of the crystal structures of Ln-Pr and Gd lactates, and thin film deposition experiments. Diffraction data collection for Gd lactate at Elettra synchrotron was partially funded by the CALIPSOplus project from the EU Framework Programme for Research and Innovation HORIZON 2020 (Grant Agreement 730872).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The primary data presented in this study are available on request from the corresponding author.

Acknowledgments

The authors acknowledge support from the M.V. Lomonosov Moscow State University Program of Development. D.T. thanks Maurizio Polentarutti and Giorgio Bais (Elettra synchrotron) for their valuable support in the single-crystal X-ray diffraction experiment.

Conflicts of Interest

The authors declare no conflict of interest.

Sample Availability

Samples of compounds 1-Ln–4-Ln are available from the authors.

References

  1. Mishra, S.; Daniele, S. Metal–Organic Derivatives with Fluorinated Ligands as Precursors for Inorganic Nanomaterials. Chem. Rev. 2015, 115, 8379–8448. [Google Scholar] [CrossRef]
  2. ten Elshof, J.E. Chemical Solution Deposition of Oxide Thin Films. In Epitaxial Growth of Complex Metal Oxides; Elsevier: Amsterdam, The Netherlands, 2022; pp. 75–100. [Google Scholar]
  3. Kessler, V.G. Aqueous Route to TiO2-Based Nanomaterials Using pH-Neutral Carboxylate Precursors. J. Sol-Gel Sci. Technol. 2013, 68, 464–470. [Google Scholar] [CrossRef]
  4. Schneller, T.; Waser, R.; Kosec, M.; Payne, D. Chemical Solution Deposition of Functional Oxide Thin Films; Schneller, T., Waser, R., Kosec, M., Payne, D., Eds.; Springer: Vienna, Austria, 2013; Volume 9783211993, ISBN 978-3-211-99310-1. [Google Scholar]
  5. Lee, H.Y.; Kim, S.I.; Lee, Y.C.; Hong, Y.P.; Park, Y.H.; Ko, K.H. New Chemical Route for YBCO Thin Films. IEEE Trans. Appl. Supercond. 2003, 13, 2743–2746. [Google Scholar] [CrossRef]
  6. Hasenkox, U.; Mitze, C.; Waser, R.; Arons, R.R.; Pommer, J.; Güntherodt, G. Chemical Solution Deposition of Epitaxial La1−x(Ca, Sr)XMnO3 Thin Films. J. Electroceram. 1999, 3, 255–260. [Google Scholar] [CrossRef]
  7. Kendin, M.; Tsymbarenko, D. Synthesis and Thermal Decomposition of Rare Earth Isovalerates and Their Solutions with Amines as an Effective Pathway to Obtain Oxide Nanomaterials. J. Anal. Appl. Pyrolysis 2019, 140, 367–375. [Google Scholar] [CrossRef]
  8. Schwartz, R.W. Chemical Solution Deposition of Perovskite Thin Films. Chem. Mater. 1997, 9, 2325–2340. [Google Scholar] [CrossRef]
  9. Tsymbarenko, D.M.; Martynova, I.A.; Malkerova, I.P.; Alikhanyan, A.S.; Kuzmina, N.P. Mixed Ligand Acetate, Propionate, and Pivalate Complexes of Rare Earth Metals with Monoethanolamine: A New Approach to the Synthesis, Composition, Structure, and Use for the Preparation of Oxide Materials. Russ. J. Coord. Chem. 2016, 42, 662–678. [Google Scholar] [CrossRef]
  10. Aspinall, H.C. Requirements of Precursors for MOCVD and ALD of Rare Earth Oxides. In Rare Earth Oxide Thin Films. Topics in Applied Physics; Fanciulli, M., Scarel, G., Eds.; Springer: Berlin/Heidelberg, Germany, 2006; Volume 106, pp. 53–72. ISBN 3540357963. [Google Scholar]
  11. Jones, A.C.; Aspinall, H.C.; Chalker, P.R. Chapter 8. Chemical Vapour Deposition of Metal Oxides for Microelectronics Applications. In Chemical Vapour Deposition: Precursors, Processes and Applications; Jones, A.C., Hitchman, M.L., Eds.; Royal Society of Chemistry: Cambridge, UK, 2008; pp. 357–412. [Google Scholar]
  12. Jones, A.C.; Aspinall, H.C.; Chalker, P.R. Molecular Design of Improved Precursors for the MOCVD of Oxides Used in Microelectronics. Surf. Coat. Technol. 2007, 201, 9046–9054. [Google Scholar] [CrossRef]
  13. Janicki, R.; Mondry, A.; Starynowicz, P. Carboxylates of Rare Earth Elements. Coord. Chem. Rev. 2017, 340, 98–133. [Google Scholar] [CrossRef]
  14. Ouchi, A.; Suzuki, Y.; Ohki, Y.; Koizumi, Y. Structure of Rare Earth Carboxylates in Dimeric and Polymeric Forms. Coord. Chem. Rev. 1988, 92, 29–43. [Google Scholar] [CrossRef]
  15. Gomez Torres, S.; Meyer, G. Anhydrous Neodymium(III) Acetate. Z. Anorg. Allg. Chem. 2008, 634, 231–233. [Google Scholar] [CrossRef]
  16. Malaestean, I.L.; Kutluca-Alıcı, M.; Ellern, A.; van Leusen, J.; Schilder, H.; Speldrich, M.; Baca, S.G.; Kögerler, P. Linear, Zigzag, and Helical Cerium(III) Coordination Polymers. Cryst. Growth Des. 2012, 12, 1593–1602. [Google Scholar] [CrossRef]
  17. Tsymbarenko, D.; Martynova, I.; Grebenyuk, D.; Shegolev, V.; Kuzmina, N. One-Dimensional Coordination Polymers of Whole Row Rare Earth Tris-Pivalates. J. Solid State Chem. 2018, 258, 876–884. [Google Scholar] [CrossRef]
  18. Kendin, M.; Tsymbarenko, D. 2D-Coordination Polymers Based on Rare-Earth Propionates of Layered Topology Demonstrate Polytypism and Controllable Single-Crystal-to-Single-Crystal Phase Transitions. Cryst. Growth Des. 2020, 20, 3316–3324. [Google Scholar] [CrossRef]
  19. Grebenyuk, D.; Ryzhkov, N.; Tsymbarenko, D. Novel Mononuclear Mixed Ligand Complexes of Heavy Lanthanide Trifluoroacetates with Diethylenetriamine. J. Fluor. Chem. 2017, 202, 82–90. [Google Scholar] [CrossRef]
  20. Vermeir, P.; Cardinael, I.; Bäcker, M.; Schaubroeck, J.; Schacht, E.; Hoste, S.; Van Driessche, I. Fluorine-Free Water-Based Sol–Gel Deposition of Highly Epitaxial YBa2Cu3O7−δ Films. Supercond. Sci. Technol. 2009, 22, 075009. [Google Scholar] [CrossRef]
  21. Vermeir, P.; Cardinael, I.; Schaubroeck, J.; Verbeken, K.; Bäcker, M.; Lommens, P.; Knaepen, W.; D’haen, J.; De Buysser, K.; Van Driessche, I. Elucidation of the Mechanism in Fluorine-Free Prepared YBa2Cu3O7−δ Coatings. Inorg. Chem. 2010, 49, 4471–4477. [Google Scholar] [CrossRef]
  22. Queraltó, A.; Banchewski, J.; Pacheco, A.; Gupta, K.; Saltarelli, L.; Garcia, D.; Alcalde, N.; Mocuta, C.; Ricart, S.; Pino, F.; et al. Combinatorial Screening of Cuprate Superconductors by Drop-On-Demand Inkjet Printing. ACS Appl. Mater. Interfaces 2021, 13, 9101–9112. [Google Scholar] [CrossRef]
  23. Rasi, S.; Ricart, S.; Obradors, X.; Puig, T.; Roura-Grabulosa, P.; Farjas, J. Effect of Triethanolamine on the Pyrolysis of Metal-Propionate-Based Solutions. J. Anal. Appl. Pyrolysis 2019, 143, 104685. [Google Scholar] [CrossRef] [Green Version]
  24. Zhao, Y.; Torres, P.; Tang, X.; Norby, P.; Grivel, J.-C. Growth of Highly Epitaxial YBa2Cu3O7−δ Films from a Simple Propionate-Based Solution. Inorg. Chem. 2015, 54, 10232–10238. [Google Scholar] [CrossRef]
  25. Xue, L.; Li, Q.; Zhang, Y.; Liu, R.; Zhen, X. Synthesis, Sintering and Characterization of PLZST Perovskite Prepared by a Lactate Precursor Route. J. Eur. Ceram. Soc. 2006, 26, 323–329. [Google Scholar] [CrossRef]
  26. Gromilov, S.A.; Piryazev, D.A.; Tatarchuk, V.V. Crystal Structure of Zinc Lactate Dihydrate—A By-Product of the Micellar Synthesis of ZnO2 Nanoparticles from Zinc Acetate and Hydroperite. J. Struct. Chem. 2021, 62, 571–576. [Google Scholar] [CrossRef]
  27. Ke, Z.; Fan, X.; You-ying, D.; Chen, F.; Zhang, L.; Yang, K.; Li, B.; Kong, Y. Crystal Structure and Solution Thermodynamics of the Lactate Complex Zn[(C3H5O3)2(H2O)2]·H2O(S). Chem. Thermodyn. Therm. Anal. 2022, 5, 100024. [Google Scholar] [CrossRef]
  28. Singh, K.D.; Jain, S.C.; Sakore, T.D.; Biswas, A.B. The Crystal and Molecular Structure of Zinc Lactate Trihydrate. Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 1975, 31, 990–993. [Google Scholar] [CrossRef]
  29. Carballo, R.; Covelo, B.; Vázquez-López, E.M.; Castiñeiras, A.; Niclós, J. The Interaction of α-Hydroxycarboxylic Acids with Metal Ions: Lactic Acid (H2L1) and 2-Methyllactic Acid (H2L2) with Cobalt(II) Crystal and Molecular Structures of [Co(HL1)2(H2O)2]·H2O and [Co(HL2)2(H2O)2]. Z. Anorg. Allg. Chem. 2002, 628, 468–472. [Google Scholar] [CrossRef]
  30. Lis, T. Structure of Manganese(II) L-Lactate Dihydrate. Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 1982, 38, 937–939. [Google Scholar] [CrossRef]
  31. Larsen, E.M.; Homeier, E.H. Zirconium(IV) and Hafnium(IV) Complexes of α-Hydroxy Carboxylates, Lactates, Mandelates, and Isopropylmandelates. Stereospecificity in Eight-Coordinate Complexes. Inorg. Chem. 1972, 11, 2687–2692. [Google Scholar] [CrossRef]
  32. Xie, Y.; Zhao, H.; Wang, X.; Qu, Z.; Xiong, R.; Xue, X.; Xue, Z.; You, X. 2D Chiral Uranyl(VI) Coordination Polymers with Second-Harmonic Generation Response and Ferroelectric Properties. Eur. J. Inorg. Chem. 2003, 2003, 3712–3715. [Google Scholar] [CrossRef]
  33. Demartin, F.; Biagioli, M.; Strinna-Erre, L.; Panzanelli, A.; Micera, G. Molecular Structure of a Mono-Peroxo Vanadium(V) Complex Formed by d,l-Lactic Acid. Inorganica Chim. Acta 2000, 299, 123–127. [Google Scholar] [CrossRef]
  34. Kakihana, M.; Tomita, K.; Petrykin, V.; Tada, M.; Sasaki, S.; Nakamura, Y. Chelating of Titanium by Lactic Acid in the Water-Soluble Diammonium Tris(2-Hydroxypropionato)Titanate(IV). Inorg. Chem. 2004, 43, 4546–4548. [Google Scholar] [CrossRef]
  35. Hati, S.; Batchelor, R.J.; Einstein, F.W.B.; Tracey, A.S. Vanadium(V) Complexes of α-Hydroxycarboxylic Acids in Aqueous Solution. Inorg. Chem. 2001, 40, 6258–6265. [Google Scholar] [CrossRef] [PubMed]
  36. Saadeh, S.M.; Lah, M.S.; Pecoraro, V.L. Manganese Complexes of α-Hydroxy Acids. Inorg. Chem. 1991, 30, 8–15. [Google Scholar] [CrossRef]
  37. Petrykin, V.; Kakihana, M.; Yoshioka, K.; Sasaki, S.; Ueda, Y.; Tomita, K.; Nakamura, Y.; Shiro, M.; Kudo, A. Synthesis and Structure of New Water-Soluble and Stable Tantalum Compound: Ammonium Tetralactatodiperoxo-μ-Oxo-Ditantalate(V). Inorg. Chem. 2006, 45, 9251–9256. [Google Scholar] [CrossRef] [PubMed]
  38. Carballo, R.; Covelo, B.; Fernández-Hermida, N.; Lago, A.B.; Vázquez-López, E.M. Synthesis of Mixed-Ligand Complexes of Copper(II) with Lactate and 2,2′-Dipyridylamine: Study of the Effect of Weak Interactions on Their Crystal Packing. Z. Anorg. Allg. Chem. 2007, 633, 1791–1795. [Google Scholar] [CrossRef]
  39. Balboa, S.; Borrás, J.; Brandi, P.; Carballo, R.; Castiñeiras, A.; Lago, A.B.; Niclós-Gutiérrez, J.; Real, J.A. Three-Dimensional Mixed-Ligand Coordination Polymers with Ferromagnetically Coupled Cyclic Tetranuclear Copper(II) Units Bonded by Weak Interactions. Cryst. Growth Des. 2011, 11, 4344–4352. [Google Scholar] [CrossRef]
  40. Fursova, E.; Romanenko, G.; Ovcharenko, V. Unpredictable Polynuclear Ni(II) Lactate Formation. Polyhedron 2013, 62, 274–277. [Google Scholar] [CrossRef]
  41. Carballo, R.; Covelo, B.; Fernández-Hermida, N.; García-Martínez, E.; Lago, A.B.; Vázquez-López, E.M. Solid State Coordination Chemistry of Copper(II) Lactate Complexes with the Twisted Ligands 4,4′-Dipyridyldisulfide and Bis(4-Pyridylthio)Methane. J. Mol. Struct. 2008, 892, 427–432. [Google Scholar] [CrossRef]
  42. Qu, Z.-R.; Ye, Q.; Zhao, H.; Fu, D.-W.; Ye, H.-Y.; Xiong, R.-G.; Akutagawa, T.; Nakamura, T. Homochiral Laminar Europium Metal–Organic Framework with Unprecedented Giant Dielectric Anisotropy. Chem.-A Eur. J. 2008, 14, 3452–3456. [Google Scholar] [CrossRef]
  43. Ye, Q.; Fu, D.-W.; Tian, H.; Xiong, R.-G.; Chan, P.W.H.; Huang, S.D. Multiferroic Homochiral Metal−Organic Framework. Inorg. Chem. 2008, 47, 772–774. [Google Scholar] [CrossRef]
  44. Yapryntsev, A.D.; Baranchikov, A.E.; Churakov, A.V.; Kopitsa, G.P.; Silvestrova, A.A.; Golikova, M.V.; Ivanova, O.S.; Gorshkova, Y.E.; Ivanov, V.K. The First Amorphous and Crystalline Yttrium Lactate: Synthesis and Structural Features. RSC Adv. 2021, 11, 30195–30205. [Google Scholar] [CrossRef]
  45. Chen, H.-J.; Chen, L.-Q.; Lin, L.-R.; Long, L.-S.; Zheng, L.-S. Doped Luminescent Lanthanide Coordination Polymers Exhibiting Both White-Light Emission and Thermal Sensitivity. Inorg. Chem. 2021, 60, 6986–6990. [Google Scholar] [CrossRef] [PubMed]
  46. Wang, K.; Zheng, T.-F.; Chen, J.-L.; Wen, H.-R.; Liu, S.-J.; Hu, T.-L. A pH-Stable TbIII -Based Metal–Organic Framework as a Turn-On and Blue-Shift Fluorescence Sensor toward Benzaldehyde and Salicylaldehyde in Aqueous Solution. Inorg. Chem. 2022, 61, 16177–16184. [Google Scholar] [CrossRef] [PubMed]
  47. Dickins, R.S.; Love, C.S.; Puschmann, H. Bidentate Lactate Binding in Aqueous Solution in a Cationic, Heptadentate Lanthanide Complex: An Effective Chiral Derivatising Agent. Chem. Commun. 2001, 1, 2308–2309. [Google Scholar] [CrossRef]
  48. Martynova, I.A.; Tsymbarenko, D.M.; Kuz’mina, N.P. Yttrium Tris-Propionate Monohydrate: Synthesis, Crystal Structure, and Thermal Stability. Russ. J. Coord. Chem. Khimiya 2014, 40, 565–570. [Google Scholar] [CrossRef]
  49. Wang, R.; Zheng, Z. Rare Earth Complexes with Carboxylic Acids. In Rare Earth Coordination Chemistry; John Wiley & Sons, Ltd.: Chichester, UK, 2010; pp. 91–136. ISBN 9780470824856. [Google Scholar]
  50. Scales, N.; Zhang, Y.; Bhadbhade, M.; Karatchevtseva, I.; Kong, L.; Lumpkin, G.R.; Li, F. Neodymium Coordination Polymers with Propionate, Succinate and Mixed Succinate–Oxalate Ligands: Synthesis, Structures and Spectroscopic Characterization. Polyhedron 2015, 102, 130–136. [Google Scholar] [CrossRef]
  51. Grivel, J.-C.; Zhao, Y.; Tang, X.; Pallewatta, P.G.P.A.; Watenphul, A.; Zimmermann, M.V. Thermal Decomposition of Yttrium(III) Valerate in Argon. J. Anal. Appl. Pyrolysis 2014, 106, 125–131. [Google Scholar] [CrossRef]
  52. Bußkamp, H.; Deacon, G.B.; Hilder, M.; Junk, P.C.; Kynast, U.H.; Lee, W.W.; Turner, D.R. Structural Variations in Rare Earth Benzoate Complexes: Part I. Lanthanum. CrystEngComm 2007, 9, 394–411. [Google Scholar] [CrossRef]
  53. Grebenyuk, D.; Zobel, M.; Polentarutti, M.; Ungur, L.; Kendin, M.; Zakharov, K.; Degtyarenko, P.; Vasiliev, A.; Tsymbarenko, D. A Family of Lanthanide Hydroxo Carboxylates with 1D Polymeric Topology and Ln4 Butterfly Core Exhibits Switchable Supramolecular Arrangement. Inorg. Chem. 2021, 60, 8049–8061. [Google Scholar] [CrossRef]
  54. Li, Y.; Yan, P.; Hou, G.; Li, H.; Chen, P.; Li, G. Luminescence of Unique 1D Tube-like Lactate Lanthanide Coordination Polymers. J. Organomet. Chem. 2013, 723, 176–180. [Google Scholar] [CrossRef]
  55. Casanova, D.; Llunell, M.; Alemany, P.; Alvarez, S. The Rich Stereochemistry of Eight-Vertex Polyhedra: A Continuous Shape Measures Study. Chem.-A Eur. J. 2005, 11, 1479–1494. [Google Scholar] [CrossRef]
  56. Gomez Torres, S.; Pantenburg, I.; Meyer, G. Direct Oxidation of Europium Metal with Acetic Acid: Anhydrous Europium(III) Acetate, Eu(OAc)3, Its Sesqui-Hydrate, Eu(OAc)3(H2O)1.5, and the “Hydrogendiacetate”, [Eu(H(OAc)2)3](H2O). Z. Anorg. Allg. Chem. 2006, 632, 1989–1994. [Google Scholar] [CrossRef]
  57. Kepert, C.J.; Wei-Min, L.; Junk, P.C.; Skelton, B.W.; White, A.H. Structural Systematics of Rare Earth Complexes. X (‘Maximally’) Hydrated Rare Earth Acetates. Aust. J. Chem. 1999, 52, 437. [Google Scholar] [CrossRef]
  58. Chu, J.; Zhao, Y.; Zhen, S.; Jiang, G.; Chen, Y.; Wu, W.; Zhang, Z.; Hong, Z.; Jin, Z. Influence of Seed Layer Materials on the Texture of IBAD-MgO Layer. IEEE Trans. Appl. Supercond. 2018, 28, 1–5. [Google Scholar] [CrossRef]
  59. Lee, S.; Petrykin, V.; Molodyk, A.; Samoilenkov, S.; Kaul, A.; Vavilov, A.; Vysotsky, V.; Fetisov, S. Development and Production of Second Generation High Tc Superconducting Tapes at SuperOx and First Tests of Model Cables. Supercond. Sci. Technol. 2014, 27, 044022. [Google Scholar] [CrossRef] [Green Version]
  60. Martynova, I.A.; Tsymbarenko, D.M.; Kamenev, A.A.; Mudretsova, S.N.; Streletsky, A.N.; Vasiliev, A.L.; Kuzmina, N.P.; Kaul, A.R. Chemical Deposition of Smooth Nanocrystalline Y2O3 Films from Solutions of Metal-Organic Precursors. Russ. Chem. Bull. 2013, 62, 1454–1458. [Google Scholar] [CrossRef]
  61. Tsymbarenko, D.; Grebenyuk, D.; Burlakova, M.; Zobel, M. Quick and Robust PDF Data Acquisition Using a Laboratory Single-Crystal X-Ray Diffractometer for Study of Polynuclear Lanthanide Complexes in Solid Form and in Solution. J. Appl. Crystallogr. 2022, 55, 890–900. [Google Scholar] [CrossRef]
  62. Martynova, I.; Tsymbarenko, D.; Kamenev, A.; Kuzmina, N.; Kaul, A. Synthesis and Characterization of Amorphous Yttrium Oxide Layers by Metal Organic Chemical Solution Deposition. Phys. E Low-Dimens. Syst. Nanostruct. 2014, 56, 447–451. [Google Scholar] [CrossRef]
  63. Tsymbarenko, D.M.; Martynova, I.A.; Ryzhkov, N.V.; Kuz’mina, N.P. Aluminum Hydroxocarboxylates in Solution Deposition of Planarization Alumina Films. Russ. J. Gen. Chem. 2017, 87, 1209–1216. [Google Scholar] [CrossRef]
  64. Sheldrick, G.M. SHELXTL, Version 5.10, Structure Determination Software Suite; Bruker AXS: Madison, WI, USA, 1998. [Google Scholar]
  65. Sheldrick, G.M. A Short History of SHELX. Acta Crystallogr. Sect. A Found. Crystallogr. 2008, 64, 112–122. [Google Scholar] [CrossRef] [Green Version]
  66. Sheldrick, G.M. Crystal Structure Refinement with SHELXL. Acta Crystallogr. Sect. C Struct. Chem. 2015, 71, 3–8. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  67. CrysAlisPRO Softwave System, Version 1.171.40.67a; Rigaku Oxford Diffraction, Rigaku Corporation: Wroclaw, Poland, 2019.
  68. Krause, L.; Herbst-Irmer, R.; Sheldrick, G.M.; Stalke, D. Comparison of Silver and Molybdenum Microfocus X-Ray Sources for Single-Crystal Structure Determination. J. Appl. Crystallogr. 2015, 48, 3–10. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  69. SCALE3 ABSPACK; Version 1.0.4, GUI 1.03; An Oxford Diffraction Program; Oxford Diffraction Ltd.: Abingdon, UK, 2005.
  70. Petříček, V.; Dušek, M.; Palatinus, L. Crystallographic Computing System JANA2006: General Features. Z. Krist.-Cryst. Mater. 2014, 229, 345–352. [Google Scholar] [CrossRef]
Molecules 28 05896 g001
Figure 1. TG-DTG data for 1-La. A full set of TG-DTG curves for RE lactates is provided in Figures S1–S4.
Figure 1. TG-DTG data for 1-La. A full set of TG-DTG curves for RE lactates is provided in Figures S1–S4.
Molecules 28 05896 g001
Molecules 28 05896 g002
Figure 2. PXRD patterns for the samples of: (a) 1-Ln; (b) 2-Ln; (c) 3-Ln; and (d) 4-Ln. Experimental PXRD patterns are shown in comparison with the respective theoretical profiles calculated from the structure models at low (100–120 K) temperatures with room-temperature unit cell parameters (in the case of 2-La, peak intensities estimated from the le Bail refinement were used to generate the theoretical profile).
Figure 2. PXRD patterns for the samples of: (a) 1-Ln; (b) 2-Ln; (c) 3-Ln; and (d) 4-Ln. Experimental PXRD patterns are shown in comparison with the respective theoretical profiles calculated from the structure models at low (100–120 K) temperatures with room-temperature unit cell parameters (in the case of 2-La, peak intensities estimated from the le Bail refinement were used to generate the theoretical profile).
Molecules 28 05896 g002
Molecules 28 05896 g003
Figure 3. Crystal structure of 1-La: (a) the selected fragment (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity); (b) polymeric chains [La(H2O)2Lact3]∞. Symmetry code: (i) 1 − x, −0.5 + y, 1.5 − z.
Figure 3. Crystal structure of 1-La: (a) the selected fragment (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity); (b) polymeric chains [La(H2O)2Lact3]∞. Symmetry code: (i) 1 − x, −0.5 + y, 1.5 − z.
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Figure 4. Crystal structure of 2-La: (a) the asymmetric unit (one [La2(H2O)5Lact6] dimer and one non-coordinated water molecule); thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, and “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units. (b) Crystal packing (view along the [001] direction).
Figure 4. Crystal structure of 2-La: (a) the asymmetric unit (one [La2(H2O)5Lact6] dimer and one non-coordinated water molecule); thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, and “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units. (b) Crystal packing (view along the [001] direction).
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Figure 5. Crystal structure of 3-Gd: (a) asymmetric unit (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units); (b) projection of hydrogen-bonded layers (view along the [100] direction; dashed blue lines correspond to the O–H∙∙∙O hydrogen bonds; all hydrogen atoms are omitted for clarity).
Figure 5. Crystal structure of 3-Gd: (a) asymmetric unit (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units); (b) projection of hydrogen-bonded layers (view along the [100] direction; dashed blue lines correspond to the O–H∙∙∙O hydrogen bonds; all hydrogen atoms are omitted for clarity).
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Figure 6. Crystal structure of 4-Sm: (a) asymmetric unit (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units); (b) projection of the hydrogen-bonded framework (view along the [100] direction; dashed blue lines correspond to the O–H∙∙∙O hydrogen bonds; isolated spheres in the packing cavities correspond to the non-coordinated water molecules; all hydrogen atoms are omitted for clarity).
Figure 6. Crystal structure of 4-Sm: (a) asymmetric unit (thermal ellipsoids are depicted at the 50% probability level, C–H hydrogen atoms are omitted for clarity, “broken-off” dashed lines correspond to the intermolecular hydrogen bonds with adjacent structural units); (b) projection of the hydrogen-bonded framework (view along the [100] direction; dashed blue lines correspond to the O–H∙∙∙O hydrogen bonds; isolated spheres in the packing cavities correspond to the non-coordinated water molecules; all hydrogen atoms are omitted for clarity).
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Figure 7. TG-DTG curves recorded for: (a) 2-Pr and (b) 4-Gd. A full set of TG-DTG curves for RE lactates is shown in Figures S1–S4.
Figure 7. TG-DTG curves recorded for: (a) 2-Pr and (b) 4-Gd. A full set of TG-DTG curves for RE lactates is shown in Figures S1–S4.
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Figure 8. VT-PXRD data (Mo Kα radiation) in the form of color maps for: (a) 2-Pr and (b) 4-Gd. Q refers to the modulus of a scattering vector transfer: Q = 4π∙sinθ/λ. Sections of the color maps at selected temperatures are shown in Figure S8.
Figure 8. VT-PXRD data (Mo Kα radiation) in the form of color maps for: (a) 2-Pr and (b) 4-Gd. Q refers to the modulus of a scattering vector transfer: Q = 4π∙sinθ/λ. Sections of the color maps at selected temperatures are shown in Figure S8.
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Figure 9. AFM topography (5 × 5 μm2 scans) of Ln2O3/HC276 thin films: (a) Y-F1 and (b) La-F1.
Figure 9. AFM topography (5 × 5 μm2 scans) of Ln2O3/HC276 thin films: (a) Y-F1 and (b) La-F1.
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Gashigullin, R.; Kendin, M.; Martynova, I.; Tsymbarenko, D. Diverse Coordination Chemistry of the Whole Series Rare-Earth L-Lactates: Synthetic Features, Crystal Structure, and Application in Chemical Solution Deposition of Ln2O3 Thin Films. Molecules 2023, 28, 5896. https://doi.org/10.3390/molecules28155896

AMA Style

Gashigullin R, Kendin M, Martynova I, Tsymbarenko D. Diverse Coordination Chemistry of the Whole Series Rare-Earth L-Lactates: Synthetic Features, Crystal Structure, and Application in Chemical Solution Deposition of Ln2O3 Thin Films. Molecules. 2023; 28(15):5896. https://doi.org/10.3390/molecules28155896

Chicago/Turabian Style

Gashigullin, Ruslan, Mikhail Kendin, Irina Martynova, and Dmitry Tsymbarenko. 2023. "Diverse Coordination Chemistry of the Whole Series Rare-Earth L-Lactates: Synthetic Features, Crystal Structure, and Application in Chemical Solution Deposition of Ln2O3 Thin Films" Molecules 28, no. 15: 5896. https://doi.org/10.3390/molecules28155896

APA Style

Gashigullin, R., Kendin, M., Martynova, I., & Tsymbarenko, D. (2023). Diverse Coordination Chemistry of the Whole Series Rare-Earth L-Lactates: Synthetic Features, Crystal Structure, and Application in Chemical Solution Deposition of Ln2O3 Thin Films. Molecules, 28(15), 5896. https://doi.org/10.3390/molecules28155896

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