Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis of the Coordination Compounds
2.2. Crystal Structure of the Coordination Compounds
2.3. X-ray Powder Diffraction, IR Spectroscopy and Thermogravimetric Analysys
2.4. Luminescent Properties of the Ligand and the Coordinaion Compounds
3. Materials and Methods
3.1. Starting Materials and Synthetic Procedures
3.1.1. Synthesis of Compound [Tb(H4.5L)2(H2O)5]∙6H2O (1)
3.1.2. Synthesis of Compound {[Eu2(H3L)2(H2O)6]∙8H2O}n (2)
3.2. Physical Methods of Analysis
3.3. Single-Crystal X-ray Diffraction
3.4. Computational Chemistry Details
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
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Parameter | Compound 1 | Compound 2 |
---|---|---|
Molecular formula | C60H43O35Tb | C30H29EuO22 |
Formula weight, g∙mol−1 | 1481.85 | 893.49 |
Temperature, K | 150(2) | 150.00 |
Crystal system | Monoclinic | Triclinic |
Space group | C2/c | P-1 |
a, Å | 38.585(2) | 8.66180(10) |
b, Å | 13.1992(7) | 10.0305(2) |
c, Å | 11.9356(7) | 19.2763(3) |
α/° | 90 | 87.9920(10) |
β, ° | 106.289(2) | 80.1830(10) |
γ/° | 90 | 87.1930(10) |
Cell volume, Å | 5834.6(6) | 1647.66(5) |
Z | 4 | 2 |
ρcalc, g/cm3 | 1.687 | 1.801 |
μ, mm−1 | 1.320 | 2.000 |
F(000) | 2988.0 | 896.0 |
Independent reflections | 9710 [Rint = 0.0508, Rsigma = 0.0445] | 5809 [Rint = 0.0405, Rsigma = 0.0402] |
Goodness-of-fit on F2 | 1.061 | 1.036 |
Final R indexes [I ≥ 2σ(I)] | R1 = 0.0353, wR2 = 0.0756 | R1 = 0.0263, wR2 = 0.0547 |
Final R indexes [all data] | R1 = 0.0458, wR2 = 0.0786 | R1 = 0.0295, wR2 = 0.0565 |
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Yu, X.; Pavlov, D.I.; Ryadun, A.A.; Potapov, A.S.; Fedin, V.P. Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand. Molecules 2022, 27, 7849. https://doi.org/10.3390/molecules27227849
Yu X, Pavlov DI, Ryadun AA, Potapov AS, Fedin VP. Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand. Molecules. 2022; 27(22):7849. https://doi.org/10.3390/molecules27227849
Chicago/Turabian StyleYu, Xiaolin, Dmitry I. Pavlov, Alexey A. Ryadun, Andrei S. Potapov, and Vladimir P. Fedin. 2022. "Variable Dimensionality of Europium(III) and Terbium(III) Coordination Compounds with a Flexible Hexacarboxylate Ligand" Molecules 27, no. 22: 7849. https://doi.org/10.3390/molecules27227849