HPLC and ToF‒SIMS Analyses of Toxicodendron vernicifluum Tree Sap Mixed with Other Natural Lacquers
Abstract
1. Introduction
2. Results and Discussion
2.1. ToF–SIMS Compositional Analysis of Mixed Lacquers
2.2. HPLC Quantitative Analysis of Mixed Lacquers
3. Materials and Methods
3.1. Materials
3.2. Methods
3.2.1. Time-of-Flight Secondary Ion Mass Spectrometry
3.2.2. High-Performance Liquid Chromatography
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability: Not available. |
References
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Compound | Retention Time (Rt, min) | Response Factor (Rf*10−3) | LOD (μg/mL) | LOQ (μg/mL) |
---|---|---|---|---|
urushiol 15:3 | 8.92, 9.30 | 1.06 | 0.55 | 1.86 |
urushiol 15:2 | 11.95, 12.48 | 1.23 | 0.57 | 1.90 |
urushiol 15:1 | 17.63, 18.38 | 1.77 | 0.52 | 1.73 |
laccol 17:0 | 25.76 | 2.78 | 0.08 | 0.26 |
cardol 15:3 | 8.30 | 2.62 | 0.08 | 0.25 |
Korean‒CNSL | CNSL Composition (wt%) [±SD] | ||
Urushiol 15:3 | Urushiol 15:1 | Used Contents (wt%) | |
Unknown A0 | 93.3 (±1.4) | 93.9 (±1.0) | 90.0 |
Unknown B0 | 8.8 (±1.3) | 10.0 (±1.0) | 10.0 |
ChineseII‒Myanmarese | Myanmarese Composition (wt%) [±SD] | ||
Urushiol 15:3 | Urushiol 15:2 | Used Contents (wt%) | |
Unknown A1 | 89.9 (±0.8) | 86.2 (±4.8) | 90.0 |
Unknown B1 | 33.0 (±0.4) | 31.7 (±2.2) | 30.0 |
Blend | Korean (wt%) | Vietnamese (wt%) | Blend | Korean (wt%) | CNSL (wt%) | Blend | Chinese II (wt%) | Myanmarese (wt%) |
---|---|---|---|---|---|---|---|---|
KV01 | 0 | 100 | KC01 | 0 | 100 | CM01 | 0 | 100 |
KV02 | 25 | 75 | KC02 | 20 | 80 | CM02 | 20 | 80 |
KV03 | 50 | 50 | KC03 | 50 | 50 | CM03 | 50 | 50 |
KV04 | 75 | 25 | KC04 | 80 | 20 | CM04 | 80 | 20 |
KV05 | 100 | 0 | KC05 | 100 | 0 | CM05 | 100 | 0 |
urushiol 15:3 | 3-[(8ZE,11Z,14E)-pentadeca-8,11,14-trienyl])- 1,2-benzenediol C21H30O2 M.W. 314.47 | |
urushiol 15:2 | 3-(8Z,11Z-Pentadecadienyl)-1,2-benzenediol C21H32O2 M.W. 316.49 | |
urushiol 15:1 | 3-(8Z-Pentadecenyl)- 1,2-benzenediol C21H34O2 M.W. 318.49 | |
laccol 17:0 | 3-heptadecylbenzene-1,2-diol C23H40O2 M.W. 348.57 | |
cardol 15:3 | 5-(8Z,11Z)-8,11,14-Pentadecatrien-1-yl-1,3-benzenediol C21H30O2 M.W. 314.47 |
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Yu, H.H.; Ham, S.W.; Lee, Y. HPLC and ToF‒SIMS Analyses of Toxicodendron vernicifluum Tree Sap Mixed with Other Natural Lacquers. Molecules 2021, 26, 434. https://doi.org/10.3390/molecules26020434
Yu HH, Ham SW, Lee Y. HPLC and ToF‒SIMS Analyses of Toxicodendron vernicifluum Tree Sap Mixed with Other Natural Lacquers. Molecules. 2021; 26(2):434. https://doi.org/10.3390/molecules26020434
Chicago/Turabian StyleYu, Hye Hyun, Seung Wook Ham, and Yeonhee Lee. 2021. "HPLC and ToF‒SIMS Analyses of Toxicodendron vernicifluum Tree Sap Mixed with Other Natural Lacquers" Molecules 26, no. 2: 434. https://doi.org/10.3390/molecules26020434
APA StyleYu, H. H., Ham, S. W., & Lee, Y. (2021). HPLC and ToF‒SIMS Analyses of Toxicodendron vernicifluum Tree Sap Mixed with Other Natural Lacquers. Molecules, 26(2), 434. https://doi.org/10.3390/molecules26020434