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Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents

by Janine Richter 1 and Michael Ruck 1,2,*
1
Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany
2
Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Strasse 40, 01187 Dresden, Germany
*
Author to whom correspondence should be addressed.
Academic Editors: Johan Jacquemin and Fouad Ghamouss
Molecules 2020, 25(1), 78; https://doi.org/10.3390/molecules25010078
Received: 28 November 2019 / Revised: 18 December 2019 / Accepted: 19 December 2019 / Published: 24 December 2019
(This article belongs to the Special Issue Ionic Liquids, from Their Synthesis to Their Applications)
Ionic liquids (ILs) and deep eutectic solvents (DESs) have proven to be suitable solvents and reactants for low-temperature reactions. To date, several attempts were made to apply this promising class of materials to metal oxide chemistry, which, conventionally, is performed at high temperatures. This review gives an overview about the scientific approaches of the synthesis as well as the dissolution of metal oxides in ILs and DESs. A wide range of metal oxides along with numerous ILs and DESs are covered by this research. With ILs and DESs being involved, many metal oxide phases as well as different particle morphologies were obtained by means of relatively simple reactions paths. By the development of acidic task-specific ILs and DESs, even difficultly soluble metal oxides were dissolved and, hence, made accessible for downstream chemistry. Especially the role of ILs in these reactions is in the focus of discussion. View Full-Text
Keywords: ionic liquid; deep eutectic solvent; metal oxide; dissolution ionic liquid; deep eutectic solvent; metal oxide; dissolution
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Richter, J.; Ruck, M. Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents. Molecules 2020, 25, 78.

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